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Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman


Comparison of laboratory and semi-field tests for the estimation of leaching rates from treated wood
2010 - IRG/WP 10-50274
The authorization of wood preservative formulations in the European Union according to the Biocidal Products Directive (BPD) includes the assessment of environmental risks by the emission of active ingredients. This risk assessment includes scenarios for preserved wood (e.g. house scenario, noise barrier), in which the predicted environmental concentration (PEC) for soil and water is calculated, u...
N Morsing, M Klamer, B Seidel, J Wittenzellner, M Maier, J Habicht


Sample Origin Influencing the Leachability of Wood Preservatives
2011 - IRG/WP 11-20474
The aim of this study is to see if the raw material influences fixation and leachability of wood preservatives. Moving towards more eco-friendly and –concious society, the wood industries must adjust itself to new rules and regulations. Greener solutions in wood protection are being tested and introduced, older systems are being improved, but questions still arise concerning some elements curren...
K Kängsepp. E Larnøy, P Meier


A Method for Studying Boron Redistribution and Leaching in Timber Framing
2011 - IRG/WP 11-20476
In typical New Zealand timber framed house construction, the timber framing has a vapour permeable building wrap applied to the exterior and a cladding applied over 20 mm battens. An interior lining usually of gypsum plasterboard is then fixed once the timber framing has a moisture content of < 20%. Timber framing within the building envelope is not expected to be wet in-service or exposed to a le...
J A Drysdale, N Marston, M E Hedley


Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives
2011 - IRG/WP 11-30556
Copper ethanolamine based preservatives are currently the most important solutions for impregnation of wood in ground contact in Europe. One of the issues related to those and similar water based solutions is insufficient penetration to refractory wood species like Norway spruce. In order to elucidate this issue, commercial copper ethanolamine based solution was supplemented with five different wo...
M Humar, N Thaler, B Lesar


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Effect of Biodiesel on the Efficacy of Pentachlorophenol Treated Wood
2012 - IRG/WP 12-30584
Pentachlorophenol (PCP) is widely used as a wood preservative for utility poles and other wood products. Recently, it has been proposed that a modified PCP carrier system based on a diesel/biodiesel mixture should be used in place of the conventional diesel/KB3 carrier, but there is some question as to whether or not this modified carrier system can provide the same service life for wood products ...
S Keshani Langroodi, H Borazjani, D Nicholas, L Prewitt, S V Diehl


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


KERUING and APITONG: A Timely Review of the Perfect Choice Wood Species for Crossarms and Brace Arms, Including Data on Copper Naphthenate Treatments
2012 - IRG/WP 12-40603
Apitong or the wood species more commonly known as Keruing is an important tropical hardwood known for its high strength to weight ratio and its reasonable durability and preservative treatability. This wood has been exported from managed permanent forest estates in Malaysia into the United States for over 4 decades for its widespread use in wooden utility industry brace arms and crossarms, yet cu...
A Wong, M Freeman


Fixation and leaching characteristics of Malaysian tropical hardwoods treated with CCA-C
2012 - IRG/WP 12-50289
The fixation and leaching characteristics of 8 Malaysian tropical hardwood (MTH) species treated with chromated copper arsenate (CCA-C) wood preservative were examined. The species evaluated were Acacia (Acacia mangium), Bintangor (Calophyllum sp.), Geronggang (Cratoxylon arborescens), Medang (Litsea sp.), Meranti rambai daun (Shorea acuminata), Putat (Planchonia sp.), Ramin (Gonystylus sp.) and S...
S Salim, S Shahomlail, Z Ashaari, Yong-Seok Choi, Gyu-Hyeok Kim


Copper naphthenate treatment for wood pols - a review and update
2012 - IRG/WP 12-30600
This paper reviews copper naphthenate (CuNap) and its utility as a treatment for wooden utility poles. One of the principal reasons that CuNap has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity. CuNap is a well-proven non-restricted use preservative, used extensively and specified for environmental reasons by ut...
J A Brient, M H Freeman


Product efficacy against Fusarium circinatum, a quarantine organism in Europe
2013 - IRG/WP 13-10807
Fusarium circinatum Nirenberg et O'Donnell (telemorph: Gibberella circinata Nirenberg et O'Donnell) is a quarantine organism in Europe producing the disease known as pitch canker of pines. For a decade, the European Union has taken steps to locate and eradicate the pathogen with the aim of eliminating the risk of spread. So far, research has focused on forest stands, however, the movemen...
M T Troya, R Raposo, F Llinares, M Conde


Determination of the natural durability of solid wood against wood-destroying fungi - a European round-robin test
2013 - IRG/WP 13-20511
In Europe the durability of wood against wood-destroying basidiomycetes is tested according to CEN/TS 15083-1 (2005). Hitherto existing experience with this standard is quite heterogeneous and results from previous round-robin tests have stayed unreported or have been reported incompletely. In particular the need for natural pre-weathering of the test specimens to allow potential detoxification of...
C Brischke, C R Welzbacher, A Gellerich, S Bollmus, M Humar, K Plaschkies, W Scheiding, G Alfredsen, J Van Acker, I De Windt


Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


The Effect of Water Repellent on Semi-Field Leaching of Active Substances from Metal Free Wood Preservative Formulation
2013 - IRG/WP 13-30615
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. A comparison of the leaching of active substances from wood treated with a metal free preservative formulation with and wit...
D G Cantrell


Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


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