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Fixation of CCA preservatives in cocos-, oil- and rattan-palm
1986 - IRG/WP 3371
In previous tests with jubaea-palm almost no fixation of a CCA-preservative Type B could be achieved, consequently, further leaching tests were carried out with samples of 1 cocos-, 1 oil- and 2 rattan-palms from Malaysia. A good fixation of chromium and copper took place in cocos-palm after 4 weeks storage at 28°C. Nevertheless the fixation was slower than in pine-wood and demanded an elevated t...
H Willeitner, K Brandt


The efficacy of polymer/preservative treatments in soil-bed exposure
1992 - IRG/WP 92-3729
Southern pine was treated with CCA, CCB, sodium borax/boric acid, or disodiumoctaborate, alone or in combination with an acrylic polymer system containing a water repellent. Treated samples were subjected to an unsterile soil burial test. The addition of polymer reduced the weight loss in borontreated samples at the lower retentions but not at the higher retention. Results with borates indicate th...
R J Murphy, H M Barnes, S M Gray


Leaching of Boron - more than 3 years of field exposure
1997 - IRG/WP 97-30143
The diffusibility of Boron in wood and thus the ability of its leaching is known since long. Nevertheless quantitative data on this process are only rarely available. To overcome this lack of information field exposure tests were started with beam-segments treated with pure boric acid and poles treated with CCB. In addition some of the beam-segments were surface-treated with a varnish to investiga...
A Peylo, H Willeitner


Sediment toxicity study of marine piles treated with CCA-C
1995 - IRG/WP 95-50040-35
A study was undertaken to demonstrate the effects of 10-day exposure to sediments mixed with leachate from chromated copper arsenate Type-C (CCA-C) southern pine marine piles treated to a retention of 40 kg/m³ (2.5 pcf) and untreated southern pine piles on the benthic amphipod, Ampelisca abdita. The biological endpoint used to establish effects was organism survival. Leachate obtained during a 28...
W J Baldwin, E A Pasek, P D Osborne


Field studies investigating the efficacy of biological treatments in preventing decay of freshly-felled pine
1993 - IRG/WP 93-10022
Four species of fungi (Trichoderma viride, Ascocoryne sarcoides, Potebniamyces conifererum and Cryptosporiopsis terraconensis) and sterile distilled water were applied separately to unpeeled, freshly-felled pine billets. The fungi were all in the form of concentrated aqueous spore suspensions, and were spread onto the end-grains of the logs by brush. Destructive sampling of the billets was carried...
M W Schoeman, D J Dickinson


Microwave treatment to Accelerated fixation of copper-ethanolamine (Cu-EA) treated wood
2004 - IRG/WP 04-40271
This study evaluated the use of microwave post-treatment to accelerate fixation of copper-ethanolamine (Cu-EA) treated 19 mm southern yellow pine sapwood cubes. Cubes were pressure treated at 3.2 and 6.4 kg/m3 Cu retention target, after which they were microwave post treated during different duration periods. An accelerated AWPA leaching test was conducted during 300 hours to determine the amount...
Jinzhen Cao, D P Kamdem


Moderate temperature fixation of CCA-C
1989 - IRG/WP 3522
Several Canadian treating plants are using moderate temperature (40-60C°) fixation chambers to reduce drippage and leaching from fresh CCA treated wood. In this study, chromium reduction and surface leaching properties of CCA-C treated red pine (Pinus resinosa) pole sections were monitored during exposure to temperatures of 50-60C° and 90-100% RH conditions. Chromium-VI concentration in the abso...
P A Cooper, Y T Ung


Effect of species, retention and conditioning temperature on copper stabilization and leaching for ACQ-D
2004 - IRG/WP 04-30342
The time to stabilization or equalization of the copper component of ACQ-D was highly dependent on treating solution concentration (preservative retention) and post treatment temperature. Stabilization was rapid for low preservative retentions but extended times were needed for wood treated with higher concentration solutions. The extent of stabilization was also concentration dependent with a h...
Y T Ung, P A Cooper


Chromated copper arsenate preservative treatment of hardwoods. Part 2: leaching performance of seven North American hardwoods
1997 - IRG/WP 97-30132
Seven North American hardwood species were treated with 2% CCA-C solution and fixed at temperatures of 21°C and 50°C and conditions of high relative humidity (95%) as described in Part 1 of this presentation. Red pine (Pinus resinosa) was included as a softwood for comparison. Adequately fixed wood blocks (99.9% chromium fixation) were exposed to leaching tests according to AWPA E11-87 test. Par...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Silicic acid-Boric acid complexes as wood preservatives
2001 - IRG/WP 01-30273
A silicic acid monomer aqueous solution (SAMS) or colloidal silicic acid solution (CSAS) was combined with various metal compounds or boric acid. Agents where SAMS or CSAS was combined with boric acid gave good protection against decay caused by the brown-rot fungus Fomitopsis palustris, the treated wood (Cryptomera japonica D. Don) specimens after the leaching test maintained a high resistance to...
H Yamaguchi


Report on the efficacy and performance of the insecticide candidate termiticide in H2 field trials
2004 - IRG/WP 04-10516
This paper explains the field results of phenol pyrazole treated timber against in an above ground mound colonies of Coptotermes acinaciformis (Froggatt). C. acinaciformis (‘termites’) are the major pest of human structures throughout tropical and sub tropical regions, causing billions of dollars in damage to timber-in-service worldwide. The result of this field test have shown that candidate ...
B M Ahmed, P Vinden, J Hann, J R J French


The influence of staining fungi on the decay resistance of wood treated with alkylammonium compounds
1984 - IRG/WP 3308
Although found to be very effective in laboratory tests, alkylammonium compounds (AAC's) have failed to perform as well in field stake tests. Examination of leachability showed that this was not the cause. The present study investigated the possibility that staining fungi, (which have been observed to rapidly infect the field stakes), degrade the AAC wood preservative. Soil-blocks were tr...
J N R Ruddick


Stability, performance and distribution of propiconazole (R 49362) in acceleratedly aged wood
1991 - IRG/WP 3647
The permanency of propiconazole (R 49362 - WOCOSENÔ technical - Janssen Pharmaceutica) in wood was examined in an 18 month storage test, an evaporative ageing study (EN 73), a volatilization stress experiment, and water-leaching studies (EN 84). The biological efficacy against two brown rot fungi: Coniophora puteana BAM Ebw. 15 and Gloeophyllum trabeum BAM Ebw. 109 was assessed according to the E...
A R Valcke, M Stevens


Accelerated weathering test for the evaluation of wood preservative efficacy
2003 - IRG/WP 03-20262
Wood samples treated with ammonium copper quat (ACQ-1900 and ACQ-2200), Chromated copper arsenate (CCA), Tanalith E 3491 and Wolmanit CX-8 have been studied in accelerated weathering experiments. The weathering experiment was performed by cycles of 2 hours UV-light irradiation followed by water spray for 18 minutes. The changes on the surface of the weathered samples were characterized by FTIR Sp...
A Temiz, M Eikenes, Ü C Yildiz, F G Evans, B Jacobsen


Development of a mini-block test method for the rapid evaluation of preservative performance against Basidiomycte fungi
1991 - IRG/WP 2379
Screening procedures for new biocides used as wood preservatives can be a time consuming process using conventional Basidiomycete assay procedures. This is due mainly to the long exposure periods required to achieve adequate levels of decay (weight loss) in the test blocks. A number of alternative methods have been developed but most utilise artificial substrates such as filter paper or agar in wh...
J Brown, S Caswell, G R Williams


Differences and their causes of CCA and CCB efficacay among some softwoods and hardwoods
1991 - IRG/WP 3656
Wood blocks from two softwoods and two tropical hardwoods species treated with different concentrations of CCA, CCB, and combinations of CrO3, CuS04, H3BO3 were subjected to the decay by brown rot fungus, Tyromyces palustris. CCA maintained good effect both in softwoods and hardwoods, while CCB and the other combinations lost their effectiveness after leaching. Chemicals leached from CCA treated w...
K Yamamoto, M Rokova


The efficacy of preservatives into the glue-line of plywood
1993 - IRG/WP 93-30002
This research is anti-termite/decay preservatives mixed with resin to produce the plywood. Thereafter, anti-decay/termite plywood were produced by the ordinary methods. To produce suitable plywood in the utilization and certified performance, the preservatives should be 0.3 to 0.4 kg/m³ of Chlorpyrifos; 0.88 and 1.10 kg/m³ of mix preservatives of Chlorpyrifos + IF-1000. Laboratories decay test (...
S Fushiki, T Saito, Y Katuzawa, Y Imamura, S Yusuf, B Subiyanto


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Leaching from field test stakes. Part 2: The distribution in and leaching from different parts of test stakes
1994 - IRG/WP 94-50026
Field test stakes treated with Boliden K33 (copper, chromium and arsenic) and Cuprinol Tryck (CT86) (copper and N-alkylbenzyldimethylammoniumchloride) respectively were exposed in ground contact at two different test fields in Sweden and rejected due to decay after 2 to 28 years. Stakes treated with the same preservatives were also exposed during 7 years above ground. The test stakes have been ana...
F G Evans, B Nossen, M-L Edlund


Chemical Analysis of Southern Pine Pole Stubs Thirteen Months Following Treatment with Three Methylisothiocyanate Based Commercial Fumigants
2002 - IRG/WP 02-30294
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC based fumigants, liquid metham sodi...
R J Ziobro, T C Anderson, D J Herdman, J Guzzetta, T Pope


A report of the Technical Recommendations documents for the Canadian Wood Protection and Preservation Facilities and an environmental study of storm water runoff from anti-sapstain treatment plants
1988 - IRG/WP 3478
With the completion of the Final draft of the Technical Recommendations (TR) documents for the Wood Preservation and Wood Protection Industry, there are naturally questions on what is expected from these documents and how Environment Canada and Provincial regulatory agencies may interact with the wood preservation industry. In general, it is expected that the Canadian Wood Preservation and Protect...
G Das, V N P Mathur


Comments on leaching in view of accelerated testing
1977 - IRG/WP 294
We developed an accelerated test for leaching at elevated temperatures (75-85°C). This test was used for the examination of 11 preservative formulations containing Cu, Zn and As. The data obtained from these experiments were compared with data on some formulations tested by ASTM standard leaching test. The method consists in making a large surface to volume ratio of wood from a treated block by c...
J Rak


Comparison of the anti-fungal efficacy of Cobra with drill perforation on oscillating pressure treated spruce transmission poles -Laboratory test
1988 - IRG/WP 3469
A laboratory method for measuring the depth of penetration of the fungicidal concentrations effective against basidiomycetes (brown rot) was developed. The tests on CCB oscillating pressure treated spruce transmission poles have shown that the depth of salt penetration can be increased by about 10 mm by a drill perforation before the impregnation. An even better penetration is reached, however, if...
E Graf, B Zgraggen


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