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Microwave treatment to Accelerated fixation of copper-ethanolamine (Cu-EA) treated wood
2004 - IRG/WP 04-40271
This study evaluated the use of microwave post-treatment to accelerate fixation of copper-ethanolamine (Cu-EA) treated 19 mm southern yellow pine sapwood cubes. Cubes were pressure treated at 3.2 and 6.4 kg/m3 Cu retention target, after which they were microwave post treated during different duration periods. An accelerated AWPA leaching test was conducted during 300 hours to determine the amount...
Jinzhen Cao, D P Kamdem


Some practical implications from recent research on the fixation of CCA preservatives
1975 - IRG/WP 358
The mechanism of fixation of CCA preservatives is briefly described. If the temperature is increased during the primary fixation period, the formation of intermediate fixation compounds is less extensive. The length of the primary fixation period is of practical interest. It is determined by preservative composition and concentration, temperature and wood species. Diagrams are given for Pinus sylv...
S-E Dahlgren


Sterilization to limit pretreatment decay: Internal temperature during kiln drying of Douglas-fir poles
2001 - IRG/WP 01-40206
Sterilization to limit pretreatment decay: Internal temperature during kiln drying of Douglas-fir poles. Fungal colonization of poles following peeling has been the subject of considerable concern among electric utilities. While the presence of fungi does not, in itself constitute a risk, the survival of these fungi through the conventional treating processes could allow them to continue to degrad...
J J Morrell, P G Forsyth, K L Levien


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


Standardization of CCA treated 45 hardwood species grown in Bangladesh for REB crossarms
1995 - IRG/WP 95-20059
Researches on 45 hardwood species grown in Bangladesh regarding density, moduli of rupture (MOR), colour and treatability of sapwood and heartwood, seasoning property and natural durability of heartwood revealed that both sapwood and heartwood of 17 species could be full cell pressure treated with CCA at impregnation pressure of 14-18 kg/cm² and only sapwood of rest 28 species could be pressure t...
A K Lahiry


Industrial fixation systems: key factors, limitations and optimisation through the use of computer simulation modelling. Discussion paper
1994 - IRG/WP 94-40026
This paper briefly describes four fixation operative in the Netherlands, namely: circulating and non-circulating steam fixation cylinders, steam fixation chambers and controlled climate rooms. The general limitations of industrial practice are reviewed against the background of established fixation theory. The controlling variables, both material and process-related, for fixation processing are sp...
A J Pendlebury, M Riepen, M J Boonstra, W Gard


Differences and their causes of CCA and CCB efficacay among some softwoods and hardwoods
1991 - IRG/WP 3656
Wood blocks from two softwoods and two tropical hardwoods species treated with different concentrations of CCA, CCB, and combinations of CrO3, CuS04, H3BO3 were subjected to the decay by brown rot fungus, Tyromyces palustris. CCA maintained good effect both in softwoods and hardwoods, while CCB and the other combinations lost their effectiveness after leaching. Chemicals leached from CCA treated w...
K Yamamoto, M Rokova


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


Copper based water-borne preservatives: Copper adsorption in relation to performance against soft rot
1987 - IRG/WP 3452
As part of a fundamental study concerned with the performance of copper based water-borne preservatives the adsorption of copper from aqueous solutions by 4 hardwood and 1 softwood species has been studied. Experiments were conducted to determine the influence of solution pH, solution concentration and solution temperature. The results obtained were consistent with an acid form ion-exchange mechan...
P M S Rennie, S M Gray, D J Dickinson


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


The multi-phase pressure (MPP) process. One-stage CCA treatment and accelerated fixation process - The process as a new concept in preservative treatment
1997 - IRG/WP 97-40078
The background to current commercial CCA treatment schedules used in New Zealand and fixation processing is reviewed. The limitations of these conventional practices with respect to treated product quality and CCA solution handling issues are defined. A novel, patented treatment schedule has been developed using a combination of hydraulic and pneumatic pressure phases and hot (~ 75°C) CCA solutio...
K Nasheri, A J Pendlebury, J A Drysdale, H Pearson, M E Hedley


Bibliography on the use of boron compounds for the preservation of wood
1973 - IRG/WP 315
This bibliography is based on an earlier literature survey prepared by J. Thornton and Wm. E. Bruce (O.E.C.D. Document No. 27/DAS/CSI/M/91) which was enlarged and revised for a meeting in Paris in October 1968 (Document 27/DAS/CSI/M554) by Professor W. Bavendamm of Reinbek. The latter (1968) document with its 166 references has now been extended and brought up to date. Acknowledgments are due to B...
R Cockcroft, J F Levy


Quantification des émanations de substances dans l'air ambiant a partir des bois traités
1993 - IRG/WP 93-50001-27
Pesticides on wood for the purpose of its protection may evaporate. Eventual toxicity of such emanations justifies risk assessment procedures for indoor air in building. This document describes bench scale tests based on the technique of chambers developped by CTBA/BIOTEC to determine the amount of pesticides and associated substances released to the ambient air. Results obtained with various pest...
H Sageot, M Lamour


Mechanical properties of CCA-treated southern pine after post-treatment kiln drying
1989 - IRG/WP 3543
This report reviews current research dealing with the effects of waterborne preservative treatment and redrying on the mechanical properties of wood. In general, waterborne preservative treatments reduce average mechanical properties. This effect is exaggerated when treated wood is kiln-dried after treatment, especially at elevated temperatures. For lumber, recently completed research at the Missi...
H M Barnes, J E Winandy


Investigation of CCA fixation in wood by sequential extraction. I Determination of CCA component fixation and preliminary extraction results
2002 - IRG/WP 02-50188
The fixation of CCA-C preservative was investigated in sapwood of red pine (Pinus resinosa Ait.), trembling aspen (Populus tremuloides Michx.) and red maple (Populus tremuloides Michx.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. Treated wood sawdust was water extracted at close time intervals during the fixation and analyzed for the contents of unfixed hexavalent chromium, total Cr, Cu ...
S Radivojevic, P A Cooper


Thermotolerant moulds on timber during kiln drying
1980 - IRG/WP 1109
In recent years a special disease named the wood trimmer's disease has been observed with increasing frequency among saw mill workers. Particularly workers in the trimming department have been affected. The medical symptoms are usually high fever, ague headache, pain in muscles and joints. It was shown that the disease was of immunologic nature and caused by over-exposure to spores from m...
B Henningsson


Effect of post-treatment drying schedule on the modulus of elasticity of CCA-treated southern pine dimension stock using nondestructive methods
1987 - IRG/WP 3413
This paper describes the results from the nondestructive testing for modulus of elasticity (MOE) of southern pine (Pinus sp.) 2 x 6's treated with chromated copper arsenate and redried using three commercial kiln schedules. The data indicate that redrying CCA-treated southern pine dimension stock treated to above-ground retentions (4 kg/m³) has no deleterious effect on the MOE, regardles...
H M Barnes, S Moore


Kiln drying of LSOP treated timber: rate of solvent evaporation, overpaintability and recovery of the solvent
1992 - IRG/WP 92-3711
The rate of solvent evaporation from LOSP treated timber dried in a kiln at 35°C has been investigated. Around 50% solvent removal has been found to be consistent with good overpaintability using a water based acrylic primer. It has been demonstrated that an activated carbon solvent recovery system is capable of removing all the solvent vapour from the outlet of a commercial joinery drying kiIn, ...
P Warburton, L B Sheard


Remediation of environmental impacts related to inorganic wood preservative chemicals using in-situ geochemical fixation
2001 - IRG/WP 01-50166-17
Use of the inorganic wood preservative chemical chromated copper arsenate (CCA) has resulted in several documented cases of soil and ground water contamination at wood treatment plants due to spills or releases of the treatment chemical. The most significant impact from releases of CCA to the environment is related to hexavalent chromium contamination of ground water. This is due to the relative s...
R M Thomasser, J V Rouse


Survey of conditioning treatment practices in the Philippines
1975 - IRG/WP 349
The wood preservation industry in the Philippines is at present beset by many problems. An association of the industry similar to those existing in other countries has only been initiated last year by FORPRIDECOM. It is hoped that the formal organisation of this association will bring into focus the importance of this particular industry in the economic and industrial development of the country. L...
R F Casin


Borates as wood preserving compounds: The status of research in the United States
1989 - IRG/WP 3542
This paper describes the extensive, on-going cooperative research effort among government and university research laboratories and industry to fully evaluate the potential for borates as wood preservatives in the United States. Research is discussed in terms of laboratory evaluations, field testing and mill trials, pilot plant pressure treatment studies, and remedial treatments. Future research pl...
H M Barnes, T L Amburgey, L H Williams, J J Morrell


A study of the rate of fixation of various chromium-containing preservatives
1991 - IRG/WP 3653
Denmark, and Scandinavia in general, has perhaps the widest range of approved industrial wood preservative types in the world. As an aid in setting realistic fixation periods, work was undertaken to investigate the rate of fixation of chromium in CCA salt, CCA oxide, CCP, CCB, CC and CCF formulations at summer and winter temperatures. The rate of fixation measured in terms of the concentration of ...
L B Sheard


Five years field test results for CCA and ACQ preservatives fixed in different climates
1999 - IRG/WP 99-30208
During assessment of the ground contact stakes in the Norwegian test field, we have found that very often the first visual rot attack is in the zone of the stakes were the stakes have been in contact with each other during the fixation. These parts are usually light green, caused by the lack of light during fixation, compared to the rest of the stake surface, which has a darker colour. To investig...
F G Evans


Investigation of temperature effect on fixation of Celcure preservative (ACC) in Hornbeam (Carpinus betulus I)
2003 - IRG/WP 03-30304
In this research, the fixation speed of Celcure 2 % (ACC) preservative salt, under temperature of 30 ºC, 40 ºC and 50 ºC on intact wood specimens of hornbeam was investigated. For this purpose, blocks of wood with 2Í 2 Í2 cm dimensions of hornbeam were prepared and saturated with 2% ACC concentration by full-cell process. The specimens were put in three incubators at the above-mentioned temperatures. For measuring the percentage of fixation through time, the specimens were extracted by using hydraulic pressure equipment, under 70 Mpa pressure. The PH of extraction was measured with the method of Diphenyl Carbazid and by using spectrophotometer. This measurement was done continuously and the amount of 6-valence chromium concentration present in the extract was compared with the amount of chromium concentration in the primary solution and then the percentage of fixation was calculated. The results showed that the decrease in 6-valence chromium is accompanied with increase of PH, this due to absorption of positive hydrogen ion by 6-valence chromium for reduction to 3-valence chromium and also ion –exchange of active components with wood during the primary phase of fixation. Also, the time necessary for reaching complete fixation in intact wood in the fixation temperature conditions of 30, 40, 50 ºC were 98, 52, 24 hours, respectively. In general, the results showed that temperature has effective role accelerating of fixation process.
R Imani, R E Majdar, A Karimi


Termite durability of sugi (Cryptomeria japonica) heartwood kiln-dried under high-temperature process in relation to wood extractives
2005 - IRG/WP 05-10547
Termite durability of sugi heartwood samples kiln-dried under a high-temperature process were evaluated by using Reticulitermes speratus (Kolbe) as a test termite sp. The n-hexane extractives of these samples were analysed by a GC technique. The less termite durability was shown on the wood samples dried under the high-temperature process, in comparison with that of the air-dried samples. No GC-p...
S Shibutani, E Obataya, K Hanata, S Doi


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