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Wart Morphology can Distinguish White Cypress Pine from the Less Durable Species, Black Cypress Pine
2009 - IRG/WP 09-20406
White cypress pine (Callitris glaucophylla) wood is durable enough to be used outdoors, but occasionally there are reports of its premature failure in ground contact, which may be due to its substitution by the less durable species, black cypress pine (C. endlicheri). It has been difficult to prove this, however, because the woods of both species are very similar in structure and cannot be separat...
R Heady, R Cunningham, P Evans


Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Colour change monitoring of photodegradation in Scots pine (Pinus sylvestris) – a short term focus
2009 - IRG/WP 09-40442
Colour change monitoring of photodegradation is a quick and easy method for monitoring rates of photodegradation in timber. A study was undertaken to compare this technique to other monitoring methods, including microtensile strength changes and weight loss. Colour changes due to accelerated sunlight exposure were monitored using a Datacolor check spectrophotometer and compared with a set of contr...
V Sharratt, C A S Hill, D P R Kint


Effectiveness of a superficial treatment of bifenthrin to protect softwood framing from damage by subterranean and drywood termites in Indonesia
2009 - IRG/WP 09-40443
Various experimental testing procedures were undertaken in Indonesia to determine the effectiveness of a superficial (envelope) treatment of bifenthrin to protect softwood framing from damage by two species of subterranean termite (Macrotermes gilvus and Coptotermes curvignathus) and one species of drywood termite (Cryptotermes cynocephalus). Lengths of framing (Pinus radiata sapwood) were commerc...
P Sukartana, J W Creffield, A Ismanto, N E Lelana


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Microwave Surface Modification of Radiata Pine Peeler Cores for Preservative Treatment
2009 - IRG/WP 09-40453
Radiata pine peeler cores are classified as a by-product derived from the cores of logs left over after the veneer peeling process. The core can be potentially developed for value added solid wood products as it is abundantly available and has a constant diameter. However, the core needs to be preservative treated because of low durability in ground contact. An additional problem is that the wood ...
K Sugiyanto, G Torgovnikov, P Vinden


Wood properties influencing the penetration of Scots pine (Pinus sylvestris) sapwood with the wood modification agent furfuryl alcohol
2009 - IRG/WP 09-40470
The European standard EN 350-2 classifies Scots pine sapwood as class 1 (easy to treat). However large variations in sapwood penetration exist which affect a homogenous distribution of preservatives. Hence individual penetration schemes have to be developed and adjusted to the material most difficult to treat in order to provide adequate sapwood penetration. To ensure better economic process con...
K Zimmer, E Larnøy, G Koch


Frequency of fungal decay in softwood windows in Germany
2010 - IRG/WP 10-10725
Knowing how often fungal decay occurs is a fundamental basis for general recommendations of preservative measures. To optimize the German recommendations for chemical wood preservation of windows made out of pine or spruce more than 2000 windows have been inspected. All windows had an opaque coating and were between 2 and 17 years old. The selection of the inspected windows was kept as randomly as...
D Lukowsky, O Moarcas, A Luette


Methods for Studying Penetration Depth of Wood Protection Products
2010 - IRG/WP 10-20432
EN 152 is an accepted standard in Europe for measuring how deep a wood protection product penetrates into the surface of treated pine wood. The method has provided consumers with a wide assortment of products that meet the specifications outlined in the standard. Because the test takes 8 or more months to carry out, artificial ageing procedures have evolved in order to standardize and speed up the...
K Hansen, L Sites, D D Nicholas


Adsorption of ionic liquids by Scots pine wood (Pinus sylvestris L.) and beech (Fagus sylvatica L.): equilibrium and kinetic modeling
2010 - IRG/WP 10-20447
In this paper methods for the adsorption study of quaternary ammonium-based ionic liquids on Scots pine (Pinus sylvestris L.) and beech (Fagus sylvatica L) are presented. Kinetic and equilibrium adsorption of compounds were evaluated. The equilibrium data fitted very well to the Langmuir adsorption models. The highest correlation coefficients determined from the pseudo-second order kinetic model ...
J Zabielska-Matejuk, A Stangierska, M Kot


Use of Internal Remedial Treatment to Extend Wood Life at the Fort Vancouver National Historic Site
2010 - IRG/WP 10-30525
The condition of wood in a reconstructed fur trading fort was assessed over a 30 year period. Poor initial treatment had resulted in the development of extensive early decay. While supplemental treatment with chloropicrin and methylisothiocyanate had arrested the attack, the results suggested that remedial treatments were unable to completely overcome the initial problems associated with treatmen...
C S Love, C Freitag, J J Morrell


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Assessment of Boracol 200RH (FrameSaver) as a remedial treatment to control decay in pre-decayed model timber frame units
2010 - IRG/WP 10-30529
Model timber frame units constructed from untreated radiata pine were pre-wetted to approximately 40% moisture content and inoculated with Coniophora puteana and Oligoporus placenta. Units were transferred to a controlled environment room maintained at 25°C and 95% RH for 7 and 10 weeks to allow two levels of decay to become established in units. Following pre-decay, units were disassembled, clea...
Mick Hedley, Dave Page, Jackie van der Waals


Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su


Treatment of Scots pine wood with oil in water and water in oil emulsion systems: Effects on boron leaching and water absorption
2010 - IRG/WP 10-30535
The aim of this study was to investigate the water absorption and water repellent efficiency of oils and oil water emulsions [oil-in-water (O/W) and water-in-oil (W/O)] and possibilities of reducing the amount of boron leaching from treated wood. Scots pine wood samples treated with waste or sunflower oil and water formulations contained 3%BA. The level of water absorption and water repellent effi...
E D Tomak, Ü C Yildiz, A Can


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The kinetics of catalytic acetylation of Pinus radiata (D. Don) using conventional and microwave heating
2010 - IRG/WP 10-40485
This study outlines the effect of catalyst and microwave heating on the degree of acetylation in radiata pine. Samples of radiata pine sapwood were impregnated with potassium acetate (KAc) dissolved in two different solvents (water and methanol). Impregnated samples were dried and subjected to acetic anhydride loading followed by conventional and microwave heating. The degree of acetylation was ev...
A Kumar Sethy, P Vinden, G Torgovnikov, S Przewloka


Chemical protection of historic timber structures: Results and future needs
2010 - IRG/WP 10-40487
The paper concentrates on the analysis of the effectiveness of chemical protection for timber structures in the Russian State Museums “Kizhi” (Karelia) and “Vitoslavlitsy” (Novgorod). The condition of historic timber was tested at the monuments treated with PCP, borax, potassium carbonate, boric acid, Pinotex chemicals in the 1970-80. Long-term analysis revealed that in many cases the...
M Kisternaya, V Kozlov


Fungal decay resistance and mechanical properties of plywood panels made from maritime pine (Pinus pinaster) and bonded with cornstarch-quebracho tannin-phenol formaldehyde adhesive
2010 - IRG/WP 10-40490
The aim of this work is to demonstrate the performances of cornstarch-quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol-formaldehyde (PF). In order to evaluate the mechanical performances of optimal cornstarch-quebracho tannin-PF, plywo...
F Charrier, A Moubarik, A Allal, A Pizzi, B Charrier


Biological degradation of acetylated wood after 18 years in ground contact and 10 years in marine water
2010 - IRG/WP 10-40522
This paper addresses the resistance to biological degradation of acetylated wood. Firstly, it presents results from an EN 252 test after 18 years’ exposure. The test is still running in Nordic NWPC test fields, Simlångsdalen in Sweden and Viikki in Finland. Results from this test were presented after 5 years’ exposure ( IRG/WP 97-30139), and showed that the resistance of acetylated wood wit...
P Larsson Brelid, M Westin


Testing of decay resistance of sapwood and heartwood of thermally modified Scots pine and Norway spruce
2010 - IRG/WP 10-40523
Thermal modification at elevated temperatures changes the chemical, biological and physical properties of wood. One of the main targets of thermal modification is to increase the biological durability and decay resistance of wood. Although the effects of thermal modification on wood have been widely studied, the significance of sapwood and heartwood on the resistance of thermally modified wood has...
H Viitanen, S Metsä-Kortelainen


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman


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