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Anti-fungal activity of rutin and rutin-metal complexes as wood protectants
2017 - IRG/WP 17-30708
The anti-fungal activity of Rutin, a flavonoid, alone or complexed with copper or zinc was investigated in a petri dish test with Gloeophyllum trabeum and Trametes versicolor as the test fungi. Rutin and the Rutin-metal complexes showed significant inhibition against each fungus. Rutin-Cu and Rutin-Zn strongly inhibited the brown rot fungus, G. trabeum, while Rutin and Rutin-Zn inhibited T. versic...
Li Yan, J J Morrell, Jie Zhong, Xiuzhu Mao


Surface Protection of Wood with Metal Acetylacetonates
2017 - IRG/WP 17-40802
Metal acetylacetonates are coordination complexes of metal ions and the acetylacetonate anion. They have diverse uses as catalysts, cross-linking and curing agents and adhesion promotors. Some metal acetylacetonates can photostabilise polymers whereas others are photocatalysts. We hypothesise that the ability of metal acetylacetonates to photostabilise wood will vary depending on the metal in the ...
Yuner Zhu, P D Evans


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Influence of sea water on timber and metal joints
2017 - IRG/WP 17-40818
In the Great East Japan Earthquake that occurred in March 2011, many buildings suffered from seawater immersion caused by the tsunami. Saito's study revealed that corrosion progresses on metal plate that experienced seawater immersion 1). However, the detailed mechanism of corrosion progresses has not yet been clarified. Therefore, in this study, salinity which is one of causes of corrosion w...
T Nishimura, H Ishiyama, F Hirose, N Wada


Exterior paint for the future - Will there be any dry-film preservatives left?
2017 - IRG/WP 17-50332
Wooden houses have a long tradition in several of the Nordic countries. Wood can be protected in various ways; constructional, chemically and by surface treatment. The use of various types of exterior paints as a surface treatment is a common way to prolong the durability of the wood. To further protect the painted surface against growth of fungi and algae, dry-film biocides remains an essential p...
H Jensen, M Sandve, S M Lystvet


Response of the symbiotic flagellate protists community of subterranean termites to sublethal amounts of biocides
2018 - IRG/WP 18-10911
Subterranean termites are quite efficient at extracting nutrients from lignocellulose. Their ability relies not only on the digestive tract physiology but also on symbiotic relationships established with flagellate protists and bacteria. This work aimed to screen the response of the flagellate protists community of the subterranean termite Reticulitermes grassei Clément to the ingestion of differ...
S Duarte, T Nobre, P Borges, L Nunes


Rapid Screening test of potential antimicrobial agents for wood coatings
2018 - RG/WP 18-20644
A two-part screening test has been developed to evaluate additives for wood coatings. First, an additive is tested in the microbial laboratory and evaluated based on its inhibitory properties against selected test organisms, directly on agar plates. A microbial growth analysis is prepared and evaluated. If the additive is considered effective, it will be tested in a standard top coating (acrylic o...
J Stenbæk, E Morsing, T Østergaard Jensen


Mechanism of nano metal fluorides against fungi
2018 - IRG/WP 18-30730
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredient in wood preservatives such as copper and boron. Wood specimens treated with fluoride sols of MgF2 and CaF2 have been tested against brown-rot fungi (Coniophora puteana and Rhodonia placenta) in accordance with EN 113 and against termites (...
S M Usmani, K Klutzny, I Stephan, T Hübert, E Kemnitz


Influence of different triazoles as co-biocides in wood preservatives on efficacy and the environmental impact
2018 - IRG/WP 18-50333
In this study we investigated the efficacy and impact on the environment of different co-biocide triazoles in wood preservatives. Four different formulations (all containing 9.5% Copper) contained individual and combinations of cyproconazole, tebuconazole, propiconazole as co-biocides. Four formulations were tested according to EN 113 and EN 84 (ageing) to determine the brv for each formulation. T...
M Klamer, T Jensen, S Bang-Achton, E Morsing


Biocidic effect of nano metal fluorides against brown-rot fungi
2019 - IRG/WP 19-30732
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredients in wood preservatives such as copper and boron. The effectiveness of nano metal fluorides was compared to sodium fluoride treated wood samples. Wood specimens treated with homo-dispersed sols of MgF2 and CaF2 were tested against brown-rot...
S M Usmani, K Klutzny, I Stephan, E Kemnitz


Application of nano metal fluorides against termites
2019 - IRG/WP 19-30733
Recent research has shown that fluorides such as NaF have potential as a wood preservative against termite attack (Pan and Wang, 2015). However, NaF has high leaching susceptibility because of its solubility (40 g/l ) which can reduce its efficacy over long term. Metal fluoride nanoparticles such as MgF2 and CaF2 present a viable alternative to water soluble fluoride-based wood preservatives as th...
S M Usmani, K Klutzny, Y de Laval, R Plarre, D McMahon, I Stephan, T Hübert, E Kemnitz


Exemplary aboveground hardwood protection from Coptotermes curvignathus under weathered conditions conferred by proprietary microemulsion-based cypermethrin (SARPECO®) and permethrin (AXIL®) biocides
2019 - IRG/WP 19-30749
SARPECO® (with cypermethrin) and AXIL® (with permethrin) solutions are water-based wood preservatives approved for dipping treatment providing 25 years of termite protection for solid wood and wood-based products in Europe and for more than 10 years in Indonesia. SARPECO® and AXIL® solutions are patented formulations based on concentrated microemulsions (ME) diluted with water as a dipping tre...
D Messaoudi, A H H Wong, C A D Tawi, N Bourguiba, O Fahy


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Monitoring of wood preservatives exposed to weathering: Extraction and analysis methods of organic biocides from treated wood and collected rain runoff
2020 - IRG/WP 20-30753
Weathering is the cause of numerous damages for outdoor joineries. Protection of wood using a preservative treatment covered with a coating is a process widely used to limit these damages. However, biocides from preservative treated wood are prone to degradation and leaching, having a direct influence on the joinery service life. This document deals with extraction and analytical methods for bioci...
O Ouali, K Le Ménach, E Raphalen, L Podgorski, S Legay, H Budzinski


Wood Protection Using Nano Metal Oxides in Propylene Glycol
2022 - IRG/WP 22-30760
Metals and metal oxides are known to have properties that can protect wood from degradation. Nanoparticles, due to its unique physical and chemical properties can enhance the protection to a much greater extent. Major constraints in dealing with nanoparticle dispersion can only be resolved by identifying a proper dispersive medium. Studies were carried out by preparing nanodispersion of four metal...
S Nair, G B Nagarajappa, K K Pandey


An Update on the Status of Industrial Heavy-Duty Preservatives in Europe
2022 - IRG/WP 22-30762
Creosote has been used for over 150 years for preservation of heavy duty industrial timbers such as railway sleepers, utility poles, and agricultural posts. The regulatory regimes in place today across Europe (eg EU & GB Biocidal Products Regulation (BPR)) require a detailed assessment of the environmental and human health properties of wood preservatives at both the active substance and product l...
S Uphill, H Griffiths, M Giannuzzi, A Hughes


Outdoor performance of Tanalith® K treated timber: Dimensional stability and corrosivity towards metal fasteners
2023 - IRG/WP 23-30798
This study was carried out to investigate dimensional stability and corrosivity towards metal fasteners in radiata pine (Pinus radiata D. Don) treated with Tanalith® K to Hazard class 4 (H4) retentions in comparison with chromated copper arsenic (CCA) treated timber. For corrosion test, untreated and treated matched specimens were prepared from Australian-grown radiata pine, tested with mild stee...
G Rassam, J Hague, D Humphrey


Quantifying metal migration from a deck constructed with copper-azole-treated lumber
2024 - IRG/WP 24-50391
Soluble copper or micronized copper wood preservatives are the most common available wood preservative systems for residential applications in the United States. Copper containing wood preservatives have been scrutinized for their potential negative impacts on the environment, across many jurisdictions. Concerns arise from the potential for preservatives to migrate out of treated wood upon water e...
G Presley, M Konkler


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