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Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Repairing of wooden elements by beta-method using carbon, steel or beech rods
2010 - IRG/WP 10-40488
Presented paper is focused on repairing of wooden elements by Beta joints reinforced with carbon, steel or beech rods, and on comparing the efficiency of these joints with traditional carpentry joints. In model laboratory experiments have been determined the bending strength (fm) and the modulus of elasticity (E) of control or original elements (fm-Control; Eo) from Norway spruce (Picea abies Kars...
L Reinprecht


Ten Year Field Tests of Borate-Treated Wood Against Subterranean Termites
2011 - IRG/WP 11-30557
In the mid 1990s, Forintek Canada Corp. initiated a study of the termite resistance of borate-treated lumber above ground, protected from rain in Canada, Japan and Hawaii. Predominant termite species at three test were Reticulitermes flavipes in Canada, and Coptotermes formosanus in both Japan and Hawaii. The material included hemlock and amabilis fir lumber treated with disodium octaborate tetrah...
P I Morris, J K Grace, K Tsunoda


Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Effectiveness of Water Based Bentonite-Borate Slurry for In-situ Remedial Protection of Historic Wooden Piles: The Eurobor Protocol, Part 2
2011 - IRG/WP 11-30574
The study of the biocide product Eurobor®, water mixture of boric acid, borax and sodium bentonite, aimed to verify previous findings regarding borates penetration from a clay-water mixture of foundation timber. The product was applied on samples from 100 year old timber foundation from the city of Göteborg. Although in ground for this long the timber was in acceptable god condition due to groun...
M. Theorin, K. Fimmerstad, K-M. Bandh


Ambient-temperature borate dip-diffusion treatment of green railroad crossties
2011 - IRG/WP 11-40556
In the USA, borates are increasingly being applied prior to air seasoning and creosote treatment of railroad ties (railway sleepers). Borates are typically applied to green ties by vacuum pressure application at 1 to 10% disodium octaborate tetrahydrate (DOT) concentration or by traditional dip-diffusion treatments at elevated temperatures. Higher temperatures are used to maintain the 30 to 50% so...
Jae-Woo Kim, A M Taylor, C Köse


Performance of Zinc Borate-Treated Oriented Structural Straw Board against Mold Fungi, Decay Fungi and Termites–A Preliminary Trial
2011 - IRG/WP 11-40571
The performance of zinc borate (ZB)-treated oriented structural straw board (OSSB) against mold fungi, decay fungi and termites was examined in standard laboratory evaluations. OSSB was fabricated with split wheat straw and diphenylmethane diisocyante (pMDI) resin. The ZB was added during panel manufacture to achieve preservative levels (wt.%) of 1.0%, 1.5%, 2.0%, and 3.0%. Untreated (0.0% ZB) OSS...
Guangping Han, M Manning, Wanli Cheng, E Pierre, W Wasylciw


Life Cycle Assessment Comparison of Treated Wood to Alternate Materials – Overview, Results and Lessons
2011 - IRG/WP 11-50282
Life Cycle Assessment (LCA) has proven useful in documenting the “green” benefits of various treated products compared to the commonly used alternates. To date, six LCA comparisons have been done or are nearing completion using ISO14040 and 14044 principles and data from US EPA databases. In almost all cases, the impact indicators for treated wood products show considerably smaller adverse e...
T Stephen, P E Smith, C R McIntyre


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Biological performance of wood- and bamboo-polypropylene composites: Effects of particle content, particle size and Zn borate
2012 - IRG/WP 12-40577
Particle content and size of wood material in wood plastic composites (WPCs) can affect efficacy of WPCs against fungi and termites. This study evaluated fungal and termite resistance of WPCs manufactured by using two different levels of particle content (50 and 70%) and three different particle sizes (30, 60, and 100 mesh). In fungal resistance tests, Tyromyces palustris, a standardized test fung...
S N Kartal, S Aysal, E Terzi, T Yoshimura, K Tsunoda


Pre-treatment decay and strength loss of railroad ties, and their prevention
2013 - IRG/WP 13-30610
Evidence of fungal decay in air-drying, untreated railway crossties is referred to as ‘stack burn’ in the industry. The deleterious consequences of stack burn on tie mechanical properties was confirmed by evaluating the impact bending toughness of wood samples taken from untreated tie stock air dried in the southern United States. These results suggest that careful consideration should be give...
A M Taylor, B Jordan, J D Lloyd


Conclusions and Summary Report on an Environmental Life Cycle Assessment of Borate-Treated Lumber Structural Framing with Comparisons to Galvanized Steel Framing
2013 - IRG/WP 13-50296
The Treated Wood Council has completed a quantitative evaluation of the environmental impacts associated with the national production, use, and disposition of borate (disodium octaborate tetrahydrate)-treated lumber structural framing and galvanized steel framing using life cycle assessment (LCA) methodologies and following ISO 14044 standards. The results for treated wood framing are significant....
AquAeTer, Inc.


Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim


Encapsulation Systems Combined with DOT Borate Treatments – The Future of Treated Crossties
2014 - IRG/WP 14-40670
Borates have been utilized in wood protection systems for many decades but only recently have been used in North America to treat crossties. This colorless, ordorless and very effective wood protection chemical has the ability to arrest and prevent the colonization of wood by both basidiomycete decay fungi and insects such as beetles and termites while ties are air seasoning or in service. Since ...
S C Kitchens, T L Amburgey


Borate treatment of green ties: An initial report on the effects on mechanical properties
2014 - IRG/WP 14-40686
Borates are increasingly used as components of wood preservative systems for railway cross ties (“sleepers”) in the USA. A variety of methods exist for incorporating the borate component; however, the so-called ‘two-step’ treatment, which involves treating the green tie in borate, followed by a pressure treatment with creosote or copper naphthenate after drying (‘seasoning’), offers th...
A M Taylor, J D Lloyd


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Steam accelerated borate diffusion: Optimizing dry tie treatment
2015 - IRG/WP 15-40713
A small laboratory study was carried out which demonstrated that dry wood dip treated in a high concentration borate solution could not be subsequently treated properly with oil borne copper naphthenate unless it was subsequently steam treated to accelerate borate penetration into the wood and re-dry the wood beforehand. A larger study with commercial sized cross ties (railway sleepers) was carri...
J-W Kim, J D Lloyd


Best handling practices for wood crossties (sleepers)
2015 - IRG/WP 15-40714
Wooden crossties (sleepers) dominate the rail industry in the USA. Most ties are hardwood treated with oil-borne preservatives using pressure treatment. Incipient decay (called ‘stack burn’) commonly develops during the pre-treatment drying process and reduces tie performance and longevity. Practices to minimize stack burn and enhance wooden tie performance are discussed as an aid to non-wood ...
N Irby, J Lloyd, A Taylor, J Watt


The termite resistance of wood impregnated with nano-zinc oxide and nano-zinc borate dispersions
2016 - IRG/WP 16-30691
In this work, the effects of the impregnation with nano-ZnO and nano-ZnB dispersions on the termite resistance of European beech wood were investigated. Three different concentrations (namely 0.5%, 1% and 2%) of the above two materials were tested. Water leaching effect was also investigated. It was concluded that a severe effect in terms of termite workers mortality is induced by the use of both ...
C Lykidis, T de Troya, M Conde, J Galván, G Mantanis


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


Decay Resistance of MDF Manufactured with Huntite- Hydromagnesite and Zinc borate
2017 - IRG/WP 17-30710
The objective of this study was to evaluate the effectiveness of some mineral based fire retardants on decay resistance of Medium density fiberboard (MDF). Two mineral based chemicals containing (Huntite/Hydromagnesite) and zinc borate (ZB) were used at two different concentrations for panel manufacturing. Decay test of samples was performed according to EN 113 standard method. At the end of the t...
U E Başer, D Ustaömer, Ö Özgenç


Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd


Dual Borate and Copper Naphthenate Treatment of Bridge Timbers:- Potential Performance Enhancements and Cost Savings
2017 - IRG/WP 17-40797
Dual treatment technology combining diffusible preservatives with oil borne preservatives, widely used for crossties in the USA, has now also been commercialized with bridge ties/timbers. In order to understand the implications of these changes, the historic service life of creosote treated bridge timbers in northern and southeastern USA were considered as well as field test data for both creosote...
J Lloyd, C Brischke, R Bennett, A Taylor


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