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Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Influence addition of boron compounds to adhesives on the bonding quality and fungicidal properties of glued wood
2010 - IRG/WP 10-40497
Wood is one of the most important construction materials. However, users of wood face two issues: limited dimensions and insufficient durability. These issues have been overcome with the development of bonding and wood preservation. The preservation of glued wood is elucidated in this paper. Through the addition of boric acid to adhesives, we tried to improve the fungicidal properties of glued woo...
M Humar, B Lesar, A Ugovsek, M Kariz, P Kralj, M Šernek


Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman


Comparison of laboratory and semi-field tests for the estimation of leaching rates from treated wood
2010 - IRG/WP 10-50274
The authorization of wood preservative formulations in the European Union according to the Biocidal Products Directive (BPD) includes the assessment of environmental risks by the emission of active ingredients. This risk assessment includes scenarios for preserved wood (e.g. house scenario, noise barrier), in which the predicted environmental concentration (PEC) for soil and water is calculated, u...
N Morsing, M Klamer, B Seidel, J Wittenzellner, M Maier, J Habicht


A Method for Studying Boron Redistribution and Leaching in Timber Framing
2011 - IRG/WP 11-20476
In typical New Zealand timber framed house construction, the timber framing has a vapour permeable building wrap applied to the exterior and a cladding applied over 20 mm battens. An interior lining usually of gypsum plasterboard is then fixed once the timber framing has a moisture content of < 20%. Timber framing within the building envelope is not expected to be wet in-service or exposed to a le...
J A Drysdale, N Marston, M E Hedley


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Tannin resin-boron for outdoor wood protection and fire retardancy
2011 - IRG/WP 11-30567
Boron in the form of boric acid is well known for its efficacy against wood destroying organisms, as well as for its high leachability from treated wood when in outside exposure. Moreover, due to the European directive 2008/58/EC, boric acid is only authorized at low levels. In order to keep considering boric acid as an interesting active ingredient for wood protection, the issue is now to fix it ...
M-F Thévenon, G Tondi, N Leménager, S Wieland, A Pizzi


The case for using borates in termite control in tropical Australia
2011 - IRG/WP 11-30573
A brief historical overview of boron based wood preservatives efficacy against subterranean termite management worldwide, and in Australia, is presented. The boron based compounds to be used in H2 hazard conditions, may be applied as a surface treatment by dip, flood coat or spray, and rapidly penetrates to the centre of timber substrates, whether containing sapwood or heartwood. However, section ...
B M Ahmed (Shiday), J R J French


Design, synthesis, characterisation and effectiveness of ‘Locked-in-Boron’ chemicals for H3.2 level of wood protection
2011 - IRG/WP 11-30577
Boratrane molecules with five-membered and six-membered molecular ring systems, and with various ring substituents were synthesised, characterised and formulated for wood treatment for accelerated laboratory bioassays using wood decay fungi as test organisms. Six-membered ring boratranes showed lower efficacy in laboratory assays than five-membered ring boratranes. One alkyl-substituted boratran...
R Franich, H Kroese, S Gallagher, S Hill, B Kelly, G Billett, R Meder, W Rae


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Ambient-temperature borate dip-diffusion treatment of green railroad crossties
2011 - IRG/WP 11-40556
In the USA, borates are increasingly being applied prior to air seasoning and creosote treatment of railroad ties (railway sleepers). Borates are typically applied to green ties by vacuum pressure application at 1 to 10% disodium octaborate tetrahydrate (DOT) concentration or by traditional dip-diffusion treatments at elevated temperatures. Higher temperatures are used to maintain the 30 to 50% so...
Jae-Woo Kim, A M Taylor, C Köse


Performance of boron diffused wood products used indoors for 144 months in Bangladesh
2012 - IRG/WP 12-30581
In this service performance study of boron diffused hardwoods, boron in the form of boric acid (H3BO3) was applied separately through paste and through wet cloth. The born diffused woods were kept indoors for 144-months in Bangladesh to ascertain the performance of treated wood against wood destroying insects. The new easy application processes of cost effectual boric acid have been found effectiv...
A K Lahiry, T Lahiry


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


The Effects of Industrial-Scale Heat Treatment and Impregnation with Boron Compounds on Water Uptake and Tangential Swelling of Some Wood Species
2012 - IRG/WP 12-40599
This study evaluated the effects of boron impregnation and heat treatment on water uptake and tangential swelling of spruce (Picea orientalis), pine (Pinus nigra), beech (Fagus orientalis) and poplar (Populus deltoides) wood species. The samples (10 x 5 x 40 - tangential x radial x longitudinal cm) were impregnated with 4 % boric acid and 4 % borax according to the ASTM D-1413 standard method. Aft...
A Can, S Yildiz, Ü C Yildiz


Hydrogels: a solution to reduce boron leachability without reduction of its biodisponibility to wood decaying fungi?
2012 - IRG/WP 12-30602
Products used today for wood protection must fulfill to more and more environmental constraints, such as being of low toxicity in answer to the Biocidal Product Directory, but also to involve waterborne treatments to limit rejection of volatile organic compounds in the atmosphere. Boron preservatives have been described as valuable alternatives for wood protection for non-ground contact applicatio...
F Obounou Akong, P Gérardin, M-F Thévenon, S Parant, C Gérardin-Charbonnier


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


State of progress of utilisation of supramolecular gels for formulations of water-soluble wood preservation salts
2013 - IRG/WP 13-30630
This article is a compilation of the work done so far concerning the utilization of supramolecular hydrogels, built on low-molecular-weight amphiphilic molecules and containing boron salts conferring fungicidal properties. Mixing boron with thermoreversible hydrogels allows the formation of a supra molecular network incorporating boron and important amount of water upon gelification of the solutio...
F Obounou Akong, P Gérardin, M-F Thévenon, C Gérardin-Charbonnier


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


Effectiveness of Copper Indicators in Treated Wood Exposed to Copper Tolerant Fungi
2014 - IRG/WP 14-20554
Wood treated with a copper based wood preservative will typically turn a green color. While the depth of copper penetration can be readily discerned from the green color of the copper it is standard practice in research and commercial treating plants to make use of a color reagent such as Chrome Azurol S, Rubeanic acid or PAN indicator to reveal the penetration more clearly. When copper treat...
L Jin, K Brown, A Zahora, K Archer


Potential for using boron for mitigation of Phytophthora ramorum in Douglas-fir logs
2014 - IRG/WP 14-30643
Phytophthora ramorum is a relatively newly described pathogen present in the forests of Northern California and southwest Oregon in the United States. This organism has an extremely wide host range, including a number of commercial important conifers, among them Douglas-fir (Pseudotsuga menziesii). The continuing expansion of the range of P. ramorum will result in an increasing quarantine area w...
J M Hulbert, J J Morrell E M Hansen


Potential for migration of boron from fused boron rods used as internal remedial treatments of utility poles
2014 - IRG/WP 14-50301
The distribution of boron in Douglas-fir utility poles and in the surrounding soil was assessed over a 54 month period following application of fused boron rods. Boron levels in the wood never reached the levels that might be predicted if diffusion were to produce a uniform chemical distribution, nor did levels in the soil suggest that boron was becoming more concentrated. The results suggest th...
M Konkler, C Freitag, C S Love, J J Morrell, J Renfroe


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