Your search resulted in 193 documents. Displaying 25 entries per page.
A substantively bonded water repellent treatment based on chromium carboxylates
1985 - IRG/WP 3344
Chromium carboxylates soluble in toluene have been synthesised and applied to Scots pine (Pinus sylvestris) sapwood. Without any further treatment, the compounds may be readily leached from wood surfaces with toluene. After a period of heating however, they become fixed to the cell wall, substantial amounts being resistant to leaching even under reflux conditions for several hours. Treatment of wo...
J K Wright, W B Banks, W J Eilbeck
Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung
Creosote for wood preservation. (Reissued from earlier OECD draft)
1970 - IRG/WP III 1A
The literature on this subject is extensive and, to some extent, repetitive so that for pratical reference purposes it is essential that selective surveys and bibliographies be prepared. Many of these exist and, as an example, the reports issued by The Coal Tar Research Association (Numbers 0156, 0292 and 0396) may be quoted. The following bibliography, listing the more important sources of inform...
Anonymous
Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren
Fixation of chromated wood preservatives through technical drying
1990 - IRG/WP 3623
Twin samples of sawn timber of Pinus sylvestris and Picea sp. were treated with copper-chromate-containing wood preservatives and subsequently kiln resp. air dried. After drying, the distribution of preservative and rate of fixation were determined. Drying of freshly treated wood in a condenser type kiln at temperatures of 60°C and 80°C and in a vacuum type kiln at 55°C with a pressure of about...
R-D Peek, H Klipp
Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel
Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee
Leachability of active ingredients from some CCA treated and creosoted poles in service. A progress report after 10 years testing
1990 - IRG/WP 3627
CCA K33 TYPE B treated or creosoted poles, 10 pieces of each treatment type, have been monitored from the treatment plant to an electricity line, which was build up in Southern Finland in 1978. Preservative retention was determined by taking borings at four different levels: 1.5 m from the top end, 1 m above ground line, ground line and 0.5 m below ground. Determinations were made before setting u...
A J Nurmi
Bioefficacy of Cunapsol® treated western cedar and southern yellow pine
1996 - IRG/WP 96-30120
Western red cedar and southern yellow pine sapwood were dip treated with a new formulation of waterborne copper naphthenate (Cunapsol®) which complies with VOC regulations. Cunapsol dip treated samples were oven dried at 50°C for 48 hours and then water leached for two weeks. Decay resistance and leachability of preservatives from dip treated specimens were evaluated according to AWPA (American ...
D P Kamdem, M H Freeman, T L Woods
Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung
A comparison of shower test results from CCF, CCZF, CCB and Cu-quat treated timber
1995 - IRG/WP 95-50054
The shower test quantifies the amount of specific preservative components which leach from treated timber under simulated open storage conditions. The test method measures leaching from both organic and inorganic salt treated timber. Shower tests of CCF, CCZF, CCB and Cu-quat treated timber which have been performed over the last 5 years by TNO are reviewed and compared. Leached components are qua...
M J Boonstra, A J Pendlebury, P Esser
Treatment and recycle of CCA hazardous waste
1993 - IRG/WP 93-50007
Chromated copper arsenate containing hazardous materials is generated from the manufacture, treatment of the wood, and from the wood itself, after its life cycle. Laboratory treating of these wastes has resulted in materials suitable for recycle or disposal as non-hazardous residues. The extraction, by both acidic and ammoniacal routes, of CCA production and treating plant waste materials has been...
E A Pasek, C R McIntyre
Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar
Laboratory Leaching Tests to Study the Effects of Post-Treatment Storage Periods on CCA Leachability and Fixation in Treated Permeable and Refractory Malaysian Hardwoods
2006 - IRG/WP 06-50240
The biological resistance and environmental safety of CCA-treated wood relies on the extent of post-treatment storage fixation of CCA in wood prior to being utilized. A study on the comparative leachability (fixation) of CCA-treated refractory and permeable heartwoods of 3 Malaysian hardwoods subjected to different post-treatment storage (fixation) periods of up to 4 weeks, at 2 laboratory leachin...
A H H Wong, H C Lai, N P T Lim
Potential for controlling carpenter ants in utility poles with borates
2007 - IRG/WP 07-10623
Carpenter ants (genus Camponotus) are important scavengers and predators in the ecosystems in which they occur. Because they excavate and tunnel into wood, carpenter ants are considered structural pests in many parts of North America where they overlap with human activity. The excavation of extensive galleries in wood by carpenter ants can seriously compromise the physical properties of wood in ...
M Mankowski
Influence of ethanolamine on lignin depolymerization and copper leaching from treated Norway spruce and beech wood
2007 - IRG/WP 07-30423
Copper-ethanolamine based wood preservatives are replacing several classical copper-chromium based solutions, due to foreseen ban of chromium. Fixation of copper-ethanolamine based wood preservatives is not as good as fixation of copper-chromium ones. The main object of this manuscript was to prove, that ethanolamine is the prime reason for insufficient fixation of copper-ethanolamine formulations...
M Humar, B Bucar, M Zupancic, D Žlindra, F Pohleven
Copper fixation in ACQ-D treated Chinese fir at various temperature and relative humidity conditions
2007 - IRG/WP 07-30436
In this study, the effect of different conditions of temperature, relative humidity, and duration of post-treatments on accelerating copper fixation in ACQ-D treated Chinese fir wood blocks was investigated. The conditions include the combination of three temperatures (21, 50, and 70?) and two relative humidity levels (20% and 80%), also include four temperatures (50, 70, 90, and 110?) without con...
Jinzhen Cao, Lili Yu
Comparative Laboratory Leaching Test Methods to Study Post-Treatment Storage Period Impacts on CCA Leachability and Fixation in Treated Kempas (Koompassia malaccensis) Heartwood
2007 - IRG/WP 07-20376
Three laboratory leaching test methods were compared to determine the effects of different post-treatment storage fixation periods on leachability/fixation of CCA components from treated kempas (Koompassia malaccensis) permeable heartwood. End-sealed test wood blocks of permeable were treated with CCA to target retention of 5.6 kg/m3, immediately stored to fix at ambient conditions for 0 and 48 ho...
A H H Wong, H C Lai
Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating.
Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi
Influence of Polyvinyl acetate emulsion (PVA) on boron leaching and fungicidal properties
2008 - IRG/WP 08-30451
Boron compounds are very effective fungicides, but unfortunately they leach from wood. In order to improve boron fixation, boric acid, borax were combined with polyvinyl acetate emulsion (PVA). For comparison copper salts were included into this research as well. Selected preservative solutions were chosen for impregnation of Norway spruce wood specimens (Picea abies). Wood blocks were exposed to ...
M Humar, B Lesar, P Kralj
The Comparison of Fixation and Leachability of Bark, Fruit and Leaf Tannin Extracts with Boron Minerals
2008 - IRG/WP 08-30473
Tannins extracted from several plants have natural durability properties. Due to these properties, some of the researchers have studied them for protecting wood. In this study, Scots pine (Pinus sylvestris) and beech (Fagus orientalis) wood samples were treated with bark, fruit, and leaf extracts as well as water-based wood preservative salts at various concentrations to increase fixation. The pen...
S Sen, C Tascioglu, K Tirak
Accelerated fixation of ACQ-D treated Chinese fir with different post-treatments
2008 - IRG/WP 08-40400
With the enhanced focus on the environmental impact of the preservative-treated wood in recent years, it is necessary to perform some post treatments to prevent contamination of soil and ground water and reduce copper losses from ACQ treated wood in service. In this study, the potential of hot air, hot water, steaming and microwave post treatments to accelerate the fixation of copper in ACQ-D trea...
Lili Yu, Jinzhen Cao, P A Cooper
Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim
Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes
Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston