Your search resulted in 178 documents. Displaying 25 entries per page.
Influence of ethanolamine on lignin depolymerization and copper leaching from treated Norway spruce and beech wood
2007 - IRG/WP 07-30423
Copper-ethanolamine based wood preservatives are replacing several classical copper-chromium based solutions, due to foreseen ban of chromium. Fixation of copper-ethanolamine based wood preservatives is not as good as fixation of copper-chromium ones. The main object of this manuscript was to prove, that ethanolamine is the prime reason for insufficient fixation of copper-ethanolamine formulations...
M Humar, B Bucar, M Zupancic, D Žlindra, F Pohleven
Copper fixation in ACQ-D treated Chinese fir at various temperature and relative humidity conditions
2007 - IRG/WP 07-30436
In this study, the effect of different conditions of temperature, relative humidity, and duration of post-treatments on accelerating copper fixation in ACQ-D treated Chinese fir wood blocks was investigated. The conditions include the combination of three temperatures (21, 50, and 70?) and two relative humidity levels (20% and 80%), also include four temperatures (50, 70, 90, and 110?) without con...
Jinzhen Cao, Lili Yu
Comparative Laboratory Leaching Test Methods to Study Post-Treatment Storage Period Impacts on CCA Leachability and Fixation in Treated Kempas (Koompassia malaccensis) Heartwood
2007 - IRG/WP 07-20376
Three laboratory leaching test methods were compared to determine the effects of different post-treatment storage fixation periods on leachability/fixation of CCA components from treated kempas (Koompassia malaccensis) permeable heartwood. End-sealed test wood blocks of permeable were treated with CCA to target retention of 5.6 kg/m3, immediately stored to fix at ambient conditions for 0 and 48 ho...
A H H Wong, H C Lai
Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating.
Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi
Influence of Polyvinyl acetate emulsion (PVA) on boron leaching and fungicidal properties
2008 - IRG/WP 08-30451
Boron compounds are very effective fungicides, but unfortunately they leach from wood. In order to improve boron fixation, boric acid, borax were combined with polyvinyl acetate emulsion (PVA). For comparison copper salts were included into this research as well. Selected preservative solutions were chosen for impregnation of Norway spruce wood specimens (Picea abies). Wood blocks were exposed to ...
M Humar, B Lesar, P Kralj
The Comparison of Fixation and Leachability of Bark, Fruit and Leaf Tannin Extracts with Boron Minerals
2008 - IRG/WP 08-30473
Tannins extracted from several plants have natural durability properties. Due to these properties, some of the researchers have studied them for protecting wood. In this study, Scots pine (Pinus sylvestris) and beech (Fagus orientalis) wood samples were treated with bark, fruit, and leaf extracts as well as water-based wood preservative salts at various concentrations to increase fixation. The pen...
S Sen, C Tascioglu, K Tirak
Accelerated fixation of ACQ-D treated Chinese fir with different post-treatments
2008 - IRG/WP 08-40400
With the enhanced focus on the environmental impact of the preservative-treated wood in recent years, it is necessary to perform some post treatments to prevent contamination of soil and ground water and reduce copper losses from ACQ treated wood in service. In this study, the potential of hot air, hot water, steaming and microwave post treatments to accelerate the fixation of copper in ACQ-D trea...
Lili Yu, Jinzhen Cao, P A Cooper
Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim
Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes
Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston
Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi
A theoretical-industrial correlation and perspective on copper-based wood preservatives - a review of thermodynamic and kinetic aspects on copper-wood fixation mechanism
2009 - IRG/WP 09-30499
Copper was and it will continue to remain one of the key active component in wood protection industry. Over the past decades, a significant effort from R&D teams in industry, academia and research institutes was directed toward understanding the copper-wood fixation mechanism, optimising the copper retentions in the wood and reduce leaching in order to maximized performance, prolong the lifetime o...
R Craciun, M Maier, J Habicht
Effects of new fixative additives on leachability of boron wood preservatives
2009 - IRG/WP 09-30507
Borates are well known with their protective capacity against both fungi and insects with low mammalian toxicity and environmental acceptable. However, boron itself does not ensure the appropriate protection for wood in the exterior applications because of their easily depletion from the treated wood under wet conditions. In this study, the potential use of monoglyceride and polyvinyl alcohol prod...
A Mohareb, J Henry, E Wozniak, P Gérardin
Determination of a fixation time of wood preservatives: A discussion paper
2010 - IRG/WP 10-20436
The intention of that paper is to initiate a discussion on the basis of a French method in combination with a German approach regarding the need of a method for the determination of a fixation time and especially to obtain input as well as ideas concerning a possible test design. Since no harmonised European approach exists up to now concerning the determination of a fixation time, CEN TC 38 (2009...
E Raphalen, E Melcher
Effects of polyvinyl alcohol on leachability and efficacy of boron wood preservatives against fungal decay and termites attack
2010 - IRG/WP 10-30526
In this study, the use of polyvinyl alcohol (PVA) as boron fixative agent was investigated. Two levels of PVA (2.5 and 4%) were evaluated with disodium octaborate tetrahydrate (DOT) at three concentrations (1, 2 and 4% boric acid equivalent (BAE) using a double vacuum impregnation processes on Scots pine sapwood specimens. Leaching was performed according to a laboratory leaching procedure. Boron ...
A Mohareb, M F Thévenon, E Wozniak, P Gérardin
Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen
Chapter 13 - Slow fixation of CCA-treated bamboo
2007 - IRG/WP 07-10635-13
Chromated copper arsenate (CCA) leachability tests on full-cell
pressure impregnated (with 2-3% CCA solution) and slow dried (six
months air-drying under cover) bamboo block of three major
bamboo species of Bangladesh revealed initial insignificant leaching
of CCA within first week and no leaching in next week. Use of low
concentration of CCA, release of particle form of CCA due to
exposure ...
A K Lahiry
Chapter 14 - Accelerated fixation of CCA-treated bamboo
2007 - IRG/WP 07-10635-14
Chromated copper arsenate type C (CCA-C) fixation study on
impregnated (with adequate w/v 6% CCA solution) then boiled,
oven-dried, normal, air-dried and steamed bamboo slices of airdried
borakbamboo (Bambusa balcooa Roxb.) of Bangladesh,
revealed almost complete fixation in steamed (accelerated fixation)
and air-dried (3 weeks, slow fixation) bamboo slices compared to
moderate to low fixati...
A K Lahiry
Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake
Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon
Fixation and leaching characteristics of Malaysian tropical hardwoods treated with CCA-C
2012 - IRG/WP 12-50289
The fixation and leaching characteristics of 8 Malaysian tropical hardwood (MTH) species treated with chromated copper arsenate (CCA-C) wood preservative were examined. The species evaluated were Acacia (Acacia mangium), Bintangor (Calophyllum sp.), Geronggang (Cratoxylon arborescens), Medang (Litsea sp.), Meranti rambai daun (Shorea acuminata), Putat (Planchonia sp.), Ramin (Gonystylus sp.) and S...
S Salim, S Shahomlail, Z Ashaari, Yong-Seok Choi, Gyu-Hyeok Kim
Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev
Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim
Chemistry of copper preservative treated wood
2014 - IRG/WP 14-30651
The reaction chemistry of micronized copper wood preservatives is fundamentally different from any previous inorganic preservative system. In order to study the chemistry, analytical procedures had to be developed which allowed the determination of the total copper as well as the copper which reacted with the wood forming copper-wood complexes. With the success of this approach it also became poss...
Wei Xue, P Kennepohl, J N R Ruddick
State of Nanocopper Fixation by Steam-Densification
2016 - IRG/WP 16-40723
This study was aimed to investigate the effect of steam treatment before densification on leachability and dimensional stability of nanocopper impregnated poplar (Popolus alba). Wood samples were impregnated with nanocopper suspension (200 and 400 ppm) for 20 minutes under 4 bar pressure. Steaming process was done before densification at 150°C for 2 hour. Radial densification (33%) was done conse...
G Rassam, A Talaei, A Ahmadi