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Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Variation in field test performance of untreated and CCA-treated lesser-known Surinamese wood species
2000 - IRG/WP 00-20213
In Suriname three different field test sites have been used to verify the biological durability of CCA-treated wood and a range of wood species including lesser-known and lesser-used wood species. In total 37 tropical wood species were tested untreated and for 17 of the less durable species CCA-treatments were included as well. Although the three sites are located in the tropical region they diffe...
J Van Acker, M Stevens, L Comvalius


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Optimization of oxalic acid production for bioleaching of metal components from CCA-treated wood by an unknown Polyporales sp. KUC8959
2010 - IRG/WP 10-50266
A brown-rot fungus, an unknown Polyporales sp. KUC8959, has recently been identified and proven as a prominent fungal species for bioremediation of CCA-treated wood wastes in our Lab. The fungus produced a larger amount of oxalic acid than other fungi tested, and removed 90 % or more of chromium, copper and arsenic from CCA-treated wood sawdust through bioleaching process. The bioleaching process ...
Yong-Seok Choi, Min-Ji Kim, Jae-Jin Kim, Gyu-Hyeok Kim


Fungal biodegradation of CCA-treated wood wastes
2011 - IRG/WP 10-50276
Fungal biodegradation could be employed as a pretreatment method to alleviate problems caused by landfill disposal of CCA-treated wood wastes (e.g. a shortage of landfill space and a release of leacheate). It could be used to decrease the volume of waste and to remove metals from waste simultaneously. We have screened hundreds of decay fungi, including fungi isolated from CCA-treated wood in servi...
Gyu-Hyeok Kim, Yong-Seok Choi, Jae-Jin Kim


Biodegration of treated wood waste by native fungal communities of tropical soil in French Guiana
2012 - IRG/WP 12-50285
Woods have been protected with fungicides for a long time, and the effects of these fungicides on soil after being leached into the ground have turned out to be a true environmental issue. It is in this perspective that we are proposing to study fungal communities of these contaminated woods in a purpose of bioremediation. Most of precedent studies have focused on ability of some Basidiomycetes an...
A Zaremski, L Gastonguay, C Zaremski, F Chaffannel, J Beauchêne, G LeFloch


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


A Vision of the Chilean Treated Wood Industry
2013 - IRG/WP 13-40619
Chile is an important actor in the world wide forestry industry, activity which represents 3,1% of the Gross National Product (GNP). The wood products sector, which includes pulp and paper, is the second source of export in Chile with USD 6,500 millions income per year. Native species are the main forestry source with 15,9 millions has., but the principal commercial activity is based on 2,3 mil...
F J Latorre, T A Hanke


Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


Practical extraction of metals from CCA-treated wood
2014 - IRG/WP 14-50305
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of chromated copper arsenate (CCA)-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from CCA-treated southern pine wood samples with three different wood particle sizes (i.e., (1) 0.5 cm3, (2) 0.5x05x1.0 cm, and (3) 0.5x0.5x1.5 cm) was investigated using a m...
Bin Yu, Chung Y Hse, T F Shupe


Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


Durability of treated wood Corymbia torelliana and Eucalyptus grandis x Eucalyptus urophylla against subterranean termite
2015 - IRG/WP 15-20563
This work aimed to analyze the durability of woods against termite Nasutitermes corniger Motsch. Fence posts from this study were collected in Pinheiros, north of Espírito Santo state, Brazil. Used the Corymbia torelliana and Eucalyptus grandis x Eucalyptus urophylla species with 11 and 9 years, respectively and plant spacing of 3.00 x 2.00 m. Were used 72 samples from discs removed the 0.50 m of...
D Junior Verly Lopes, J Benigno Paes, P N de Medeiros Neto, G dos Santos Bobadilha


CCA Treated Wood, Will It Last 100 Years?
2016 - IRG/WP 16-20575
Copper, chrome and arsenate (CCA) treated wood has a very successful history of use in New Zealand, for at least 60 years. In many parts of the world, CCA has been used for timber treatment since the mid-1930s. In this report, data are presented on the performance of CCA treated pine stakes and poles. Results from ground contact durability tests at Scion and other overseas test performance data su...
T Singh, D Page


Properties of Wood Plastic Composites Made of Recycled HDPE and Remediated Wood Flour from CCA/CCB Treated Wood Removed from Service
2016 - IRG/WP 16-40747
Chromated copper arsenate (CCA) and copper, chromium and boron (CCB) have been widely used in pressure treated wood as a heavy duty preservative to protect wood against insects and fungi for more than 60 years. Although many attempts have been done to solve the problems related to out-service treated wood, the problem still remains. Only a few studies were done to utilize the out-of service treate...
E D Gezer, S Akbaş, M Tufan, A Temiz


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


The Effects of Pre-Microwave Treatment on Retention Levels And Some Mechanical Properties of Spruce Wood Treated with CCA
2017 - IRG/WP 17-40800
Microwave (MW) treatment of wood has been evaluated in recent years for different purposes by several scientists. Microwave conditioning improves permeability, reduces density and heat conductivity and changes dimensional stability. Furthermore, it could even improve the permeability of refractory wood species such as spruce and Douglas fir. In this study, MW pre-treatment was applied to spruce wo...
E D Gezer, S Kuştaş, S Durmaz


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Multi-scale Experimental Study on Self-sustained Smouldering of CCA-treated Timber Poles
2023 - IRG/WP 23-40988
While it is accepted that appropriate treatment with chromated copper arsenate (CCA) will extend the design life of wood markedly, there are concerns regarding the effect of treatment on fire performance. Smouldering combustion in CCA-treated timber infrastructure can self-sustain, destroying the timber elements, as the chromium and copper present in the CCA can act as catalysts of the smouldering...
W Wu, L Yerman, J J Morrell, F Wiesner


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