IRG Documents Database and Compendium


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Impact of an Antioxidant on the Efficacy of Quaternary Ammonium Compounds (Quats) and Triazoles – Seven Year Above-Ground Study
2009 - IRG/WP 09-30504
It has been reported that antioxidants have great potential for use with organic biocides in the area of wood protection. This paper demonstrates the impact of a low level of the antioxidant butylated hydroxytoluene (BHT) on the efficacy of quat-based and triazole-based formulations. A seven year lap joint test revealed a positive effect of BHT on the efficacy of quat-based formulations, especiall...
Xiao Jiang, D Biro, W Holcombe


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Properties of strand board bonded with ammonium pentaborate (APB) modified phenol formaldehyde resin
2009 - IRG/WP 09-40455
Ammonium pentaborate (APB) is combined with phenol formaldehyde (PF) resin in this study to develop a high-performance wood-based composite. The effect of APB and its combination with polyethylene glycol (PEG) on the physical, mechanical properties as well as formaldehyde emission of strand board were tested and compared with disodium octaborate tetrahydrateand (DOT) and zinc borate (ZB). The resu...
Wei Gao, Jinzhen Cao


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Methylene Chloride compared with white spirit as a treatment solvent for wood preservation – results from decay and termite studies
2013 - IRG/WP 13-30611
Non-aqueous solvents have a long history in the treatment of wood products in various parts of the world. The most familiar solvent treatment is the ‘light organic solvent preservative’ (LOSP) treatment based on low density solvents such as white sprit. Until recently white spirit was the only non-aqueous solvent approved for use in wood preservation in New Zealand. Australia also permitted...
A Siraa, P Lobb, C Molloy


Screening method to test efficacy of fumigants against fungi and preliminary data on the efficacy of sulfuryl fluoride
2014 - IRG/WP 14-20551
Methyl bromide is being phased out and there is an urgent need to find a suitable replacement that is effective in reducing exotic pest establishments via trade in wood products. Efficacy data for established phytosanitary fumigants were mostly developed for arthropods and nematodes, and limited information exists for plant pathogens. Increased interest in developing a fast screening process for f...
A Uzunovic, A Mukherjee, R Mack, P Elder, S Myers


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Above ground field testing: results of experiments in Brazil after one year
2015 - IRG/WP 15-30660
After the development of new products they need to be field-tested to assess their efficacy under diverse conditions of climate, comparing them with a preservative with proven efficacy. In some testing sites, decay occurs very slowly. The solution would be to bring these tests to locations that are conducive to biodeterioration, like tropical climates. Tropical sites provide higher temperature and...
M F Natale, J M Vidal


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


A non-VOC approach of solvent-based wood preservatives for remedial treatment
2016 - IRG/WP 16-30681
Solvent-based wood preservatives are the workhorses in the field of remedial treatment. Due to new European regulations on the indoor air quality there is an increasing pressure on the VOC-content on these solvent-based product types. The transfer of these European regulations into national law is left up to each European member state and handled in different ways. E.g. France has introduced a VO...
M Pallaske, S Hellkamp, P Jüngel


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Alternative fumigants to Methyl Bromide for wood products: Review of the development and preliminary tests of Ethane Dinitrile (EDN) in Canada
2019 - IRG/WP 19-30743
This paper reviews recent developments and updates in the search for alternative fumigants to ozone-depleting methyl bromide, for wood products fumigation. The absence of alternative treatments may result in significant market disruption if further restrictions on methyl bromide are imposed. This paper reviews key challenges and key attributes of an ideal fumigant and also the status of standardis...
A Uzunovic


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