Your search resulted in 125 documents. Displaying 25 entries per page.
Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren
Influence of fungal exposure on the redistribution of copper in treated spruce wood
2002 - IRG/WP 02-10450
The redistribution of copper in treated wood after exposure to basidiomycete decay fungi is described. The micro-distribution of copper in copper(II) sulphate or copper(II) octanoate/ethanolamine treated Norway spruce wood before and after exposure to 3 different wood decay fungi was studied using transmission electron microscopy with X-ray microanalysis. The copper content of the mycelium and the...
M Humar, F Pohleven, R J Murphy, D J Dickinson, I Moris, M Zupancic, P Kalan, M Petric
A comparison of shower test results from CCF, CCZF, CCB and Cu-quat treated timber
1995 - IRG/WP 95-50054
The shower test quantifies the amount of specific preservative components which leach from treated timber under simulated open storage conditions. The test method measures leaching from both organic and inorganic salt treated timber. Shower tests of CCF, CCZF, CCB and Cu-quat treated timber which have been performed over the last 5 years by TNO are reviewed and compared. Leached components are qua...
M J Boonstra, A J Pendlebury, P Esser
The natural durability of wood in different use classes - PART II
2006 - IRG/WP 06-10598
The natural durability of important European wood species has been tested on 3970 speci¬mens in field trials. The wood was exposed at five test sites in Germany with different climates, at each site in European use class 4 and 3 (with and without soil contact). Within European use class 3 three different expositions were tested: vertical with sheltered end grain, vertical unsheltered and horizont...
A O Rapp, U Augusta, K Brandt
Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker
Effects of chlorothalonil (CTN) and butylated hydroxytoluene (BHT) on microbial communities involved in the deterioration of wood using T-RFLP II: Results from field studies
2007 - IRG/WP 07-30429
The effects of Chlorothalonil (CTN) and Butylated Hydroxytoluene (BHT) on microbial species diversity in wood and the surrounding soil are being assessed by Terminal Restriction Fragment Length Polymorphism (T-RFLP). CTN was selected as a trial organic wood preservative, and the non-biocidal BHT was evaluated for its synergistic effects with CTN. ACQ-C was a positive control and untreated SYP sta...
G T Kirker, M L Prewitt, S V Diehl
Kd values of Cu, Cr, As in different soil matrix
2007 - IRG/WP 07-50247
Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient (Kd) values of these metal components. The results revealed that Kd values were higher in chromium, followed by arsenic and copper in soil matrix. Different...
Sung-Mo Kang, Seung-Hun Shin, Ja-Oon Koo
Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim
The effects of acetylation level on the growth of Postia placenta
2011 - IRG/WP 11-10751
To understand the defence mechanisms utilized by decay fungi when exposed to different wood protection systems the study of gene expression can give us some answers. When the DNA sequences are known, primers can be designed to detect transcripts of genes with gene products related to basic cellular processes and hyphal growth. The characteristic gene products induced in different fungi by differen...
A Pilgård, G Alfredsen, C G Fossdal, C J Long II
Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick
Mobilized copper(II) concentrations in earlywood and latewood of micronized copper treated red pine
2012 - IRG/WP 12-30596
Electron paramagnetic resonance (EPR) was used in conjunction with energy dispersive x-ray spectroscopy (EDX) to quantify total copper and mobilized copper retentions in MCQ and MCA treated red pine. The MCQ treated red pine was found to have higher copper retention than that of the MCA treated one. Earlywood in general had higher total copper content than latewood. The mobilized and complexed cop...
Wei Xue, P Kennepohl, J N R Ruddick
The effects of acetylation level on the growth of Postia placenta over 36 weeks
2012 - IRG/WP 12-40589
Genomic sequencing gives us a tool to systematically and rapidly discover novel genes, how their products function in the cell, and explore their interactions. When the DNA sequences are known, primers can be designed to detect transcripts of genes with gene products related to basic cellular processes and hyphal growth. The characteristic gene products induced in different fungi by different wood...
A Pilgård, G Alfredsen, C G Fossdal, C J Long II
Surface moulds and staining fungi on acetylated wood – effect of increasing acetyl content
2013 - IRG/WP 13-10797
Wood used in outside applications is susceptible to weathering and photo degradation, which often leads to surface discoloration, loss of brightness and surface deterioration. Research has shown that acetylated wood is more resistant against brown rot, white rot and soft rot, and more dimensionally stable than untreated wood. However, acetylated wood seems still to be disfigured by surface moulds ...
L Ross Gobakken, S Bardage, C J Long II
A case study of investigating fungi that affect traditional Japanese shake roof with/without copper plates
2013 - IRG/WP 13-10810
A Japanese traditional shake roof is made from split logs. To keep the roof long, copper (Cu) plates are often inserted between the shakes. It has been thought that Cu elements from copper plates would flow out when a shake roof is exposed to rain and inhibit growth of wood rotting fungi. Actually there are some examples where the Cu plates seem to be effective in preventing fungal damage, but on ...
T Wada, Y Fujiwara, Y Fujii, R Kigawa
Effect of soil contact on reacted copper(II) levels in micronized copper treated wood
2013 - IRG/WP 13-30616
Small 3 to 4 mm thick and approximately 80 to 100 mm long, samples were removed from wood treated with micronized copper quat (MCQ) or micronized copper azole (MCA) and buried full length in a soil bed. Samples were removed after 2, 4 and 8 weeks. The total copper was determined by x-ray fluorescence (XRF) spectroscopy and the amount of reacted micronized copper measured by electron paramagnetic r...
Wei Xue, P Kennepohl, Xingguo Jin, J N R Ruddick
Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar
Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow
The use of new, aqueous chemical wood modifications to improve the durability of wood-plastic composites
2017 - IRG/WP 17-40787
The wood flour used in wood-plastic composites (WPCs) can biologically deteriorate and thus the overall mechanical performance of WPCs decrease when exposed to moisture and fungal decay. Protecting the wood flour by chemical modification can improve the durability of the wood in a nontoxic way so it is not harmful to the environment. WPCs were made with modified wood flour and then evaluated for m...
R E Ibach, C M Clemons, G C Chen
A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel
Fipronil Concentrations in Soil after Vertical Termiticide Applications Using the “Termidor®H•P High Precision Injection System”
2017 - IRG/WP 17-20630
Termidor®H•P II High Precision Termiticide concentrations in sandy-loam and sandy-clay-loam building foundation soil were measured 1.0-hour after high-pressure vertical liquid injections into the soil using the Termidor®H•P High Precision Injection System. Cylindrical, vertical 30.5-cm-deep soil cores were extracted and separated into four 7.6-cm-long sequential partitions, and fipronil res...
B M Kard
Evaluation of ecotoxicological effects of different coniferous wood treatments on two marine bioindicator species
2022 - IRG/WP 22-10999
Coniferous wood panels (Picea abies) were treated with two concentrations of copper-based impregnating agent to increase its durability in marine and brackish environment. In order to assess the environmental compatibility of the treatments a laboratory experiment was conducted with two marine invertebrate species: bivalve Mytilus galloprovincialis and a gastropod Steromphala albida. The bioindica...
T Marčeta, N Nesto, I Guarneri, D Tagliapietra, V Moschino
Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete
Properties of Iron (II) Sulphate treated Norway Spruce
2022 - IRG/WP 22-30765
Exterior wood is exposed to various environmental factors that cause weathering. Weathering is important primarily from an aesthetic standpoint. However, not all parts of the building are equally susceptible to weathering. Parts exposed to moisture will discolour faster than protected parts, such as wood under roof overhangs. To achieve fast and uniform artificial greying, a surface treatment with...
B Lesar, M Humar, M Škamlec
Comparative study of the properties of silicate coatings with different mineral pigments (titanium dioxide, iron (III) oxide, copper (II) oxide) on the surface of wood
2022 - IRG/WP 22-40936
Silicate coatings are attractive alternatives to conventional organic-based coatings for wood protection. In this work, silicate coatings were prepared with a potassium silicate binder modified with a methyl siliconate solution, and three types of mineral pigments titanium dioxide, iron (III) oxide and copper (II) oxide. The coatings were applied on beech wood and cured under ambient conditions. T...
A M Cheumani Yona, M Petrič
Influence of weathering of wood surfaces before and after treatment with iron(II) sulphate
2023 - IRG/WP 23-30786
Outdoor wood is exposed to various factors that cause the wood to grey or age. The ageing processes can vary greatly depending on the exposure. Parts of the wood that are not exposed to external factors, e.g. under the eaves, are less exposed and the ageing process is therefore slower. This can be accelerated by solutions based on iron ions. In this way, the wood greys quickly and evenly. However,...
B Lesar, M Humar, F Osvald