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Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley


The effective control of moulds on freshly impregnated wood
2004 - IRG/WP 04-30352
Beside natural timber it is known, that moulds can also groth at the surface of impregnated wood. This material shows “defects” like resistant dark spots or color changes and causes complaints. During the last years, the problem by moulds seems to increase. Laboratory studies were carried out to show the effect of impregnations against moulds. Wood samples (Pinus sylvestris L.) were impregn...
G Cofta, K Lutomski, P Jüngel


Oxalic acid production of fifteen brown-rot fungi in copper citrate- treated southern yellow pine
2001 - IRG/WP 01-10388
Non-arsenical copper-based wood preservatives have grown in number since the 1980's as a response to environmental concerns posed by arsenicals. Interest in copper tolerant decay fungi has increased accordingly. Oxalic acid (OA) production by brown-rot fungi has been proposed as one mechanism of copper tolerance. Fifteen brown-rot fungi representing the genera Postia, Wolfiporia, Serpula,...
F Green III, C A Clausen


Environmental risk assessment of preservative treated wood
1998 - IRG/WP 98-50101-19
This paper reviews the status of the environmental risk assessment of preservative treated wood and confirms the distinction between the risks presented by wood preservatives and preservative treated wood. The paper proposes a tiered approach to risk assessment and discusses the rationale. Flowcharts are presented which summarise the tiered approach to risk assessment, show the tests required, and...
E F Baines, S J Davis


A method of predicting the average life of field tests on preservative-treated stakes
1977 - IRG/WP 297
The paper presents an analysis of the results of completed field stake tests on untreated and preserved timber, and develops a method of predicting the average life of incomplete stake tests on wood preservatives from the failures that have occurred so far....
D F Purslow


How to determine what is a realistic emission from treated wood - basic reflections
1998 - IRG/WP 98-50105
Emissions from treated wood occur by evaporation and by leaching. Up to date by far more experience exists on leaching tests than on evaporation test. The methods applied will be of interest to give answers to the questions about the quantity of possible emissions. Standardisation on leaching started very early. One of the first attempts to quantify the effect of leaching on the remaining efficacy...
H Willeitner, R-D Peek


Performance of treated spruce in Canadian field test sites
1989 - IRG/WP 3506
Spruce material under test in Canadian field test sites is performing better than anticipated. From the comparison of the performance of spruce treated with various preservatives, it appears that penetration may be far more important on durability performance than the preservative itself or the retention of preservatives in the wood. However, there is still insufficient data on the influence of pe...
J P Hösli, E E Doyle


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


Isolation and identification of the fungal flora in treated wood
1976 - IRG/WP 144
J F Levy


Timber Preservation and Sustainable Construction in Australia
2005 - IRG/WP 05-50224-14
Sustainable development has been described as meeting the needs of the present without compromising the ability of future generations to meeting their own needs. (Bruntland 1987) To achieve the sustainable development goal therefore, the maximum performance has to be obtained from existing resources (timber) so that the remaining resource is protected from over-exploitation. Clearly, wood preserva...
J Norton


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


Restriction for use and waste management for pressure treated wood - The current situation in Norway
2001 - IRG/WP 01-50175
The Norwegian Environmental Authorities have this winter sent out a draft on restrictions in production and use of heavy metals in preservative treated timber. If it is passed, it will lead to drastic changes in the use of preservatives in Norway from this autumn. The environmental authorities and the preservative industry are both at present discussing waste management for CCA and creosote treate...
F G Evans


Performance of chromated copper arsenate-treated aspen fence posts installed in Forintek's Eastern test plot from 1951 to 1963
1984 - IRG/WP 3272
Aspen poplar fence posts were pressure treated by the full cell process using three formulations of copper chrome arsenate wood preservative. A total of one hundred and fifty nine of the posts were installed in service in Forintek's Chalk River post plot from 1951 to 1962. During the 1982 general inspection of the post plot all 159 posts were still in service. A groundline inspection was ...
C D Ralph


Use of the Pilodyn to assess deterioration of treated aspen waferboard after 30 months of outdoor exposure
1986 - IRG/WP 2254
Samples of preservative treated aspen waferboard exposed outdoors for 30 mo. were compared using pin penetrations of the 6 Joule Pilodyn. These results correlated well with rankings of treatment performance based on more laborious standard mechanical tests, and demonstrate the potential for use of the Pilodyn as a tool to evaluate wood composites in test exposures with minimal destruction....
E L Schmidt, M G Dietz


Restrictions or environmental taxes as regulatory means - How will they influence the use of pressure treated wood?
1998 - IRG/WP 98-50101-28
In all the Nordic countries except Norway, we have environmental restrictions on the use of pressure treated wood. In Norway we expect environmental taxes on a large number of various products in 1998/99 - probably also pressure treated wood with one or more of the heavy metals copper, chromium and arsenic. The paper will discuss how this can influence the use of pressure treated wood and cause a...
F G Evans


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


Biological degradation resistance of pine wood treated with dimethylol compounds
1989 - IRG/WP 3528
The study reports the increase of dimensional stability and biological degradation resistance of pine wood (Pinus sylvestris L) after impregnation with dimethyloldibydroxyethyleneurea. Decay resistance was determined according to BS 838:961. Nearly complete protection against Coniophora puteana, (Schum.ex Fr. Karst) weight loss of 2-3% was shown when modification, expressed as weight gain, exceede...
C L Videlov


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


Removal of heavy metals from treated wood using biological methods
2005 - IRG/WP 05-50226
Heavy metals were removed from wood treated with copper based preservatives using brown-rot fungus Fomitopsis palustris. The amount of effective elements removed by treatment methods was examined. The relationship between oxalic acid concentration and the amount of heavy metals removed from each treated wood was also investigated. The relationship between fungus weight and removal rate was also in...
Dong-won Son, Dong-heub Lee


Pyrolytic treatment of CCB treated wood
2005 - IRG/WP 05-50224-23
Environmental problems caused by the toxicity of metallic elements of the preservative occur when treated wood comes to end of use. In the experiment, CCB treated wood chips were pyrolysed at various temperatures and residence times and the behaviour of boron, chromium and copper was observed. The three elements are almost entirely retained in the charcoal. There is no influence of final tempera...
J F Collin, C G Jung, J M Romnée, J Delcarte


Contribution of wood components on the absorption of copper amine
2000 - IRG/WP 00-30216
The contribution of wood components on the absorption of copper amine was investigated. Holocellulose, lignin and xylan absorbed significant amount of copper. The amount of copper absorbed by cellulose was almost negligible. The removal of extractive also decreased the amount of copper absorption. This study clearly indicates the importance of lignin, hemicellulose in the absorption of copper amin...
D P Kamdem, Jun Zhang


EPR investigations of interactions between ammoniacal Cu(II) octanoate and wood
1996 - IRG/WP 96-30110
Ammoniacal solutions of copper(II) octanoate [ C u . h l f . 2 . r h l f.(O2CC7H15)4], interactions of these solutions with wood and wood components, and leaching of copper(II) octanoate from impregnated wood samples, have been studied by electron paramagnetic resonance (EPR) method. It is still not clear if in the Cu(II) octanoate - water - ammonia system, Cu(II) remains in a (copper(II) octanoat...
F Dagarin, M Petric, F Pohleven, M Sentjurc


Current models used by the European Health Authorities to evaluate the volatilization of active ingredients from treated wood used inside dwellings. A case study: Volatilization of azaconazole and propiconazole from treated wood
1990 - IRG/WP 3565
The use of wood preservatives inside houses may result in measurable aerial concentrations of active ingredients. These airborne contaminants may be inhaled by the inhabitants over periods lasting from a couple of days to several months. To assess the potential health hazard of preservative residues in the air, various risk-assessment models have been worked out. Three schemes, currently used by t...
A R Valcke, L Van Leemput


Production of preservative-treated wood in some countries
1990 - IRG/WP 3598
This report presents figures of the production of preservative-treated wood and wood treated with anti-stain chemicals in 26 and 20 countries respectively from all over the world....
J Jermer


Leaching of chromium and other cca components from wood-cement composites made with spent CCA treated wood
2000 - IRG/WP 00-50153
Wood cement composites are an attractive option for recycling spent treated wood, since the CCA treatment enhances the physical, mechanical and biological resistance properties of the composite. However, we have noted a higher than normal leaching of chromium from these products and this appears to result from conversion of some of the trivalent chromium to the more leachable and toxic hexavalent ...
D Qi, P A Cooper


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