IRG Documents Database and Compendium


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The potential for using CuO nanoparticles as a wood preservative
2011 - IRG/WP 11-30569
The potential for using nano-copper particles for wood protection was investigated using mini-agar slant and wood block tests with Gloeophyllum trabeum or Trametes versicolor. Nano-copper was more effective against G. trabeum than T. versicolor, although neither of these fungi would be considered copper tolerant. Nano-copper solutions were stable over a 17 week storage period, but precipitated w...
I S Weitz, K Knani, M Maoz, C Freitag, J J Morrell


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Performance of Wood Protection Systems at Multiple Field Test Sites Using the Ground Proximity Test Method
2012 - IRG/WP 12-20499
A series of preservative systems were used to treat southern pine ground proximity test samples which were then exposed at a range of test sites located throughout the world. The sites were chosen on the basis of having vastly different Scheffer Climate decay indices. After almost 14 years exposure, distinct differences are apparent in how different preservative systems perform at the different ...
A Zahora, A Preston, L Jin


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Mobilized copper(II) concentrations in earlywood and latewood of micronized copper treated red pine
2012 - IRG/WP 12-30596
Electron paramagnetic resonance (EPR) was used in conjunction with energy dispersive x-ray spectroscopy (EDX) to quantify total copper and mobilized copper retentions in MCQ and MCA treated red pine. The MCQ treated red pine was found to have higher copper retention than that of the MCA treated one. Earlywood in general had higher total copper content than latewood. The mobilized and complexed cop...
Wei Xue, P Kennepohl, J N R Ruddick


KERUING and APITONG: A Timely Review of the Perfect Choice Wood Species for Crossarms and Brace Arms, Including Data on Copper Naphthenate Treatments
2012 - IRG/WP 12-40603
Apitong or the wood species more commonly known as Keruing is an important tropical hardwood known for its high strength to weight ratio and its reasonable durability and preservative treatability. This wood has been exported from managed permanent forest estates in Malaysia into the United States for over 4 decades for its widespread use in wooden utility industry brace arms and crossarms, yet cu...
A Wong, M Freeman


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Copper naphthenate treatment for wood pols - a review and update
2012 - IRG/WP 12-30600
This paper reviews copper naphthenate (CuNap) and its utility as a treatment for wooden utility poles. One of the principal reasons that CuNap has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity. CuNap is a well-proven non-restricted use preservative, used extensively and specified for environmental reasons by ut...
J A Brient, M H Freeman


Detection of Aureobasidium as the dominant fungus on coated wood
2013 - IRG/WP 13-10796
Wood is often covered with a coating in order to protect the surface. Unwanted dark mold growth on paint covered surfaces in external conditions is a familiar phenomenon. Simple microbial techniques have commonly been used to determine the dominant fungal species present in the discoloured area, for example morphological analysis of microscopic preparations of fungal pieces sticking to an adhesive...
E J Van Nieuwenhuijzen, M F Sailer, R A Samson, O C G Adan


A case study of investigating fungi that affect traditional Japanese shake roof with/without copper plates
2013 - IRG/WP 13-10810
A Japanese traditional shake roof is made from split logs. To keep the roof long, copper (Cu) plates are often inserted between the shakes. It has been thought that Cu elements from copper plates would flow out when a shake roof is exposed to rain and inhibit growth of wood rotting fungi. Actually there are some examples where the Cu plates seem to be effective in preventing fungal damage, but on ...
T Wada, Y Fujiwara, Y Fujii, R Kigawa


Image analysis for mould and sapstain detection on wood
2013 - IRG/WP 13-20519
Laboratory tests for mould growth on wood products are time consuming and rely on visual assessments of specimens utilizing subjective rating systems. Accelerated laboratory methods are needed that can provide rapid, quantitative assessment of mould and sapstain growth on solid and composite wood products. Image analysis of scanned spore imprints from southern pine or oriented strandboard (OSB) sp...
C A Clausen, V W Yang


The activity of a wood-decaying fungus during drying and rewetting cycles measured by isothermal calorimetry
2013 - IRG/WP 13-20526
Wood decaying fungi are an essential part of any ecosystems as they are the main decomposers of cellulose and lignin-containing materials. But as wood is a common building material the risk for decay fungi growth and subsequent degradation of our construction material is a concern. There are important physiological aspects of the growth and activity of decay fungi that are unknown today, and witho...
S Johansson, L Wadsö, A Pilgård, G Alfredsen


Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre


Effect of soil contact on reacted copper(II) levels in micronized copper treated wood
2013 - IRG/WP 13-30616
Small 3 to 4 mm thick and approximately 80 to 100 mm long, samples were removed from wood treated with micronized copper quat (MCQ) or micronized copper azole (MCA) and buried full length in a soil bed. Samples were removed after 2, 4 and 8 weeks. The total copper was determined by x-ray fluorescence (XRF) spectroscopy and the amount of reacted micronized copper measured by electron paramagnetic r...
Wei Xue, P Kennepohl, Xingguo Jin, J N R Ruddick


Copper Coating on Wood: a New Way of Protecting Wood
2013 - IRG/WP 13-30617
Thermal spray metal coating technology was used to apply a thin layer of copper on the surfaces of a number of wood species. The adhesion of metal coating to mahogany, oak, soft maple, spruce, white pine and medium density fibreboard (MDF) was evaluated by pull off adhesion test. The resistance of copper coated wood samples to mildew were assessed in the lab. Also, the decay resitance and water re...
M Nejad, R Shafaghi, L Pershin, J Mostaghimi, P Cooper


Preparation of Copper Rosinate Emulsion and Its Resistance against Wood Decay Fungi
2013 - IRG/WP 13-30619
A leaching-resistant water-borne copper preservative was prepared by means of the following three steps: (1) Gum rosin was saponified with potassium hydroxide. (2) The soap reacted with copper sulfate to form copper rosinate. (3) The copper rosinate was emulsified with a mixture of Tween 20 and Span 80. Poplar (Populus ussuriensis) wood was impregnated with 0.5%, 1.0%, 1.5%, or 2.0% of the copper ...
Mingxin Zhang, Shujun Li, Qian Wang, Bo Li, Qiong Wu


Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the termites...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani


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