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Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Leaching of arsenic, copper and chrome from preservative-treated timber in playground equipment
1984 - IRG/WP 3149
Samples were taken from CCA-treated timber in sand play boxes and other play ground equipment. Sand was also sampled. Sand and wood samples were analysed for copper, chrome and arsenic by AAS. About 20-25% of the arsenic had leached from the timber after 2-4 year's exposure in the playgrounds. Very little of the copper and chrome had been leached. Sand collected in the close vicinity of t...
B Henningsson, B Carlsson


Practical experiments with Boracol 10 Rh used as a fungicide in the repair process after attack by the dry rot fungus (Serpula lacrymans)
1987 - IRG/WP 3458
The test is carried out in an old house in Nyhavn, Copenhagen. The roof and the walls close to were heavily attacked by dry rot fungus (Serpula lacrymans) because damage to the zinc covering the frontspice were letting in water to the wood and wall construction. An attack by the dry rot fungus is more complicated to repair compared with other wood destroying fungi because beside the damage on wood...
J Bech-Andersen


Soft rot fungi found in copper/chrome/arsenic treated hardwood power transmission poles in Queensland
1978 - IRG/WP 185
In Queensland the effective service life of copper/chrome/arsenic (CCA) treated hardwood telegraph and power transmission poles is being dramatically shortened due to attack by soft rot decay fungi. The Australian Wood Preservation and Pole Industries are funding research into this serious soft rot problem involving C.S.I.R.O. and the University of Queensland. The C.S.I.R.O. is actively engaged wi...
L E Leightley


Soft rot decay in CCA treated eucalypts in Queensland - A comment
1986 - IRG/WP 1301
A survey has been completed concerned with the distribution and severity of groundline soft rot decay in the CCA treated sapwood of eucalypt poles in Queensland. The survey encountered some 1000 poles of which 55% were slightly, 28% moderately and 17% severely decayed. Soft rot decay was more severe in urban than rural locations. Embedment of poles in concrete resulted in severe soft rot. No signi...
L E Leightley


Decay resistance of Siberian larch wood against brown rot fungus. - Part 3. The variation between plus trees and their grafted clones
2000 - IRG/WP 00-10350
The aim of the study was to estimate the variation in the decay resistance of Siberian larch (Larix sibirica Ledeb.) wood using mature plus trees and their grafted clones. Samples were collected with an increment core borer from 11 original plus trees and their 25-year-old grafted seed orchard clones. A typical brown rot fungus, Coniophora puteana (Schum. ex Fr.) Karst. (BAM Ebw. 15), was used as ...
H Viitanen, L Paajanen, M Venäläinen, A Harju, P Velling


Weathering of copper-amine treated wood
2000 - IRG/WP 00-40155
Copper ethanolamine (Cu-EA) treated southern pine (SP) were artificially weathered with a QUV Weathering Tester. The weathering regime was composed of a continuous UV-light irradiation for 2 hours followed by a water spray for 18 minutes for a total time of 1200 hours. The changes on the surface of the weathered samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis,...
J Zhang, D P Kamdem


Solid state NMR study on pine wood degraded by brown rot fungus Gloeophyllum trabeum
1994 - IRG/WP 94-10067
Blocks of Pinus koraiensis wood were degraded by Gloeophyllum trabeum and examined by solid-state 13C NMR spectroscopy. Chemical compositions were estimated from relative signal aras. There was no evidence for preferential degradation of the noncrystalline cellulose which accounted for about 4% by weight of the wood. Loss of partly ordered cellulose on crystal surfaces exceeded the loss of crystal...
Yoon Soo Kim, R Newman


New ways of chemical wood preservation
1997 - IRG/WP 97-40087
Synergistic effects pertaining to wood preservation have been investigated by combining different polymerizing agents with modifying chemicals, modifying chemicals with known preservatives and new types of preservative chemicals with each other. One of the investigated methods is the use of impregnating solutions based on furfuryl alcohol (produced from biomass), in which the chemicals polymerizes...
M Westin, T Nilsson, B Ohlsson, R Simonson


Remedial ground-line treatment of CCA poles in service. A progress report after 28 months' testing
1988 - IRG/WP 3481
Remedial treatments of CCA-treated poles in service with incipient soft rot were carried out with boron rods, boron/glycol solution, boric acid paste, copper/creosote paste and a commercial product (DFCK paste) respectively. The micro-flora before remedial treatment and 6 months after as well as the spread of chemicals in the poles were reported in Document No: IRG/WP/3388. In this progress report...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Rapid fixation of Chromated Copper Arsenate (CCA) wood preservatives by microwave treatment
2000 - IRG/WP 00-40184
Rapid microwave heating of freshly chromated copper arsenate (CCA) treated timber indicates that rapid preservative fixation is possible within approximately 40 seconds. The leaching of CCA was evaluated using simulated rainfall. Cost analyses indicates that microwave fixation using an on-line conveyor belt fixation process with an output of 4m3/hour using a microwave power supply of 230 kW costs ...
G Torgovnikov, P Vinden, E Mapanda, P R S Cobham


Microwave treatment to Accelerated fixation of copper-ethanolamine (Cu-EA) treated wood
2004 - IRG/WP 04-40271
This study evaluated the use of microwave post-treatment to accelerate fixation of copper-ethanolamine (Cu-EA) treated 19 mm southern yellow pine sapwood cubes. Cubes were pressure treated at 3.2 and 6.4 kg/m3 Cu retention target, after which they were microwave post treated during different duration periods. An accelerated AWPA leaching test was conducted during 300 hours to determine the amount...
Jinzhen Cao, D P Kamdem


Commercial antisapstain chemicals in New Zealand
1980 - IRG/WP 3142
Almost all sawn timber of exotic softwoods (principally Pinus radiata) and a large proportion of indigenous sawn timber receives an antisapstain chemical treatment to prevent fungal degrade during subsequent seasoning, storage, or transportation (if exported). Antisapstain chemicals are also widely used to protect freshly peeled round produce during drying. A further, specialised, use is as the fu...
J A Butcher


Fungicidal effectiveness of amended alkylammonium compound
1987 - IRG/WP 3421
Amendment of didecyldimethylammonium chloride was attempted to improve its fungicidal effectiveness and properties of treating solutions. Addition of copper definitely increased effectiveness in controlling wood decay fungi, although metal corrosiveness and stability of treating solutions was unsatisfactory. Further amendment with stabilizer(s), anticorrosive agent(s) and sequestering agent(s) res...
K Tsunoda, K Nishimoto


Effect of species, retention and conditioning temperature on copper stabilization and leaching for ACQ-D
2004 - IRG/WP 04-30342
The time to stabilization or equalization of the copper component of ACQ-D was highly dependent on treating solution concentration (preservative retention) and post treatment temperature. Stabilization was rapid for low preservative retentions but extended times were needed for wood treated with higher concentration solutions. The extent of stabilization was also concentration dependent with a h...
Y T Ung, P A Cooper


Diffusion and interaction of components of water-borne preservatives in the wood cell wall
1988 - IRG/WP 3474
This study investigates the rates of diffusion and ultimate distributions of copper and arsenate components of wood preservatives in wood cell walls following vacuum treatment. Adsorption studies of copper on red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) wood confirm the importance of cation exchange reactions on the ultimate distribution of copper in the wood substance and i...
P A Cooper


Characterization of Poria indoor brown-rot fungi
1995 - IRG/WP 95-10094
The heterogeneous group of "Poria" fungi causing brown rot in buildings and also of wood in ground contact comprises Antrodia vaillantii, Antrodia serialis, Antrodia sinuosa, Antrodia xantha and Tyromyces placenta. These fungi have similar morphological appearance and biology. Their nomenclature has a confusing history and is still not uniform. As a consequence, misinterpretations may occur. SDS p...
O Schmidt


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


Efficacy of waterborne copper naphthenate as preservative for northern hardwood species
1995 - IRG/WP 95-30091
Northern red oak (Quercus rubra) and red maple (Acer rubrum) cubes pressure treated with waterborne formulation of copper naphthenate were evaluated for resistance to attack by brown fungi Gloeophyllum trabeum (Pers. ex Fr.) Murr. (Madison 617 ATCC 11539) and Poria placenta (Fr.) Cooke (Madison 698, ATCC 11538), white rot fungi Trametes versicolor (L. ex Fr.) Pilat (R-105 from Jeff Morrell), Irpex...
D P Kamdem, R Fair, M H Freeman


Chromated copper arsenate preservative treatment of hardwoods. Part 2: leaching performance of seven North American hardwoods
1997 - IRG/WP 97-30132
Seven North American hardwood species were treated with 2% CCA-C solution and fixed at temperatures of 21°C and 50°C and conditions of high relative humidity (95%) as described in Part 1 of this presentation. Red pine (Pinus resinosa) was included as a softwood for comparison. Adequately fixed wood blocks (99.9% chromium fixation) were exposed to leaching tests according to AWPA E11-87 test. Par...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


Marine performance of preservative treated Southern pine panels. - Part 1: Exposure in Newport, Oregon
2000 - IRG/WP 00-10368
The ability of selected wood preservative to protect southern pine sapwood against marine borer attack was evaluated over a 6 year period in Yaquina Bay, Oregon. The site exposed the wood to potential attack by both Teredo navalis and Limnoria spp. Both creosote and CCA provided excellent protection at moderate retentions, while ACQ produced slight differences in performance depending on the coppe...
R G Rhatigan, J J Morrell, A R Zahora


Basilit CCFZ. Further studies on ecotoxicological behaviour
1992 - IRG/WP 92-3722
Basilit CCFZ is a new developed water based preservative for the protection of timber in hazard class 4 and 5 (ground-, fresh- and salt-water contact). The active components of this salt are copper, chromium, zinc and fluorine. In addition to primarily studies on the acute toxicity against organisms of the aquatic food chain a long term ecotoxicological study was performed. In a prolonged toxicity...
H W Wegen


Fouling assemblage development on copper-chromium-arsenic-treated timber submerged in European waters
2002 - IRG/WP 02-50181
The effect of the anti-marine-borer timber preservative CCA on community development of non-target marine fouling animals was investigated. Panels of Scots pine treated to target retentions of 12, 24 and 48 kg CCA per m3 of wood, plus untreated controls were submerged at seven coastal sites (Portsmouth, UK; La Tremblade (2 sites), France; Ria Formosa, Portugal; Sagres, Portugal; Kristineberg, Swed...
C Brown, R J Eaton, S M Cragg, P Goulletquer, A Nicolaidou, M J Bebianno, J Icely, G F Daniel, T Nilsson, A J Pitman, G Sawyer


Wood and filter paper degradation, phenol oxidase and one-electron oxidation activities by the white rot fungus Ceriporiopsis subvermispora
2003 - IRG/WP 03-10486
The activities of one-electron oxidation and phenol oxidase during incubation of cultures of the white-rot basidiomycete Ceriporiopsis subvermispora containing either glucose or wood were periodically measured. Further, the degradation activities against wood and filter paper were examined during the course of cultivation. Weight losses of Japanese beech wood and Japanese cedar wood after 12 wee...
H Tanaka, S Itakura, A Enoki


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