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Determination of ethanolamine in impregnated wood
2000 - IRG/WP 00-20198
Leaching of copper based preservatives from wood is usually prevented by adding chromium compounds to copper containing formulations. It seems that suitable substitutes for chromium fixation agents may be amines. In this paper, we report our results on interactions between copper(II) octanoate and ethanolamine (C2H7NO, 2-aminoethanole) with wood or its components. A part of ethanolamine from a woo...
M Humar, M Petric


Fungal remediation of CCA-treated wood
2004 - IRG/WP 04-50210
This study evaluates oxalic acid accumulation and bioremediation chromated copper arsenate (CCA) treated wood by three brown-rot fungi, Fomitopsis palustris, Coniophora puteana, and Laetiporus sulphureus and ten mold and staining fungi, Aspergillus niger, Aureobasidium pullulans, Gliocladium virens, Penicillium funiculosum, Rhizopus javanicus, Ceratocystis pilifera, C. peceae, Alternaria alternata...
S N Kartal, Y Imamura


SEM investigation of the production of extracellular mucilaginous material (ECM) by some wood inhabiting and wood decay fungi when grown on inert surfaces
1997 - IRG/WP 97-10194
A range of wood inhabiting and wood decay fungi have been studied for their production of extracellular mucilage when grown on inert surfaces, for comparison with their growth on wood. The species tested were: Coniophora puteana, Coriolus versicolor, Chaetomium globosum, Trichoderma harzianum, Ceratocystis coerulescens, Ophiostoma piceae, Mucor sp. and Penicillium sp. They were grown on plastic me...
A R Abu, R J Murphy, D J Dickinson


Recycling of treated timber by copper smelter
1994 - IRG/WP 94-50030
A preliminary trial was carried out to see whether copper smelting process is able to recycle CCA treated timber. As a result of the first trial almost a full recovery of both copper and arsenic was achieved. Recovered metals were utilized in manufacturing CCA preservatives. The energy bound in wood is utilized in the flash smelting process and the burning gases are fed to the sulphuric acid plant...
A J Nurmi, L Lindroos


The non-uniform uptake of chromium and copper during the impregnation of wood using the example of a CCB-salt
1998 - IRG/WP 98-20137
The correct impregnation of wood requires among other things a regular control of the concentration of the treating solution as this and/or its stoichometric composition can change as a result of the impregna-tion process and the treated wood. The preferential uptake of individual wood preservative components by the wood is of particular importance in this connection. Dipping and vacuum impregnat...
P Jüngel, E Melcher, R-D Peek


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


Wood colonizing fungi as a human pathogen
1992 - IRG/WP 92-1523
Today we recognize some 174 "pathogens" among the approximately 100000 species of fungi, which cause different diseases on man. 24 fungi which are well known as wood colonizing fungi have been identified as opportunistic human pathogen. Some of them have been found on the surface of the human body, causing superficial mycoses, or cutaneous infection, like dermatophytosis or dermatomycosis. Other c...
R Benko


Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils. A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens


Comparative study of lignocellulolytic activities of Pleurotus spp. and white rot and brown-rot fungi
1997 - IRG/WP 97-10210
In this work, the in vitro species of Pleurotus (P.eringii, P. cornucopiae and P. ostreatus), from structures of degraded wood have been studied. This degradative activity was compared to those presented by Trametes versicolor (fungus characteristic of white rot) and Gloeophyllum trabeum (fungus representative of brown rot). The activities studied were the following: cellulase, xylanase, pectinase...
D Muñoz-Mingarro, F Llinares, M T De Troya, F Rubio, M Yuste, C Rodríguez-Borrajo, J E Garcia de los Rios, F Alvarez, P Jiménez, A Rojas, A Navarrete, P Reche


The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren


Marine trial progress report
1980 - IRG/WP 453
In May 1977 and May 1978, tests of new chemical formulations for the protection of timber in the sea were installed in Mt. Maunganui Harbour. Investigation into new preservatives for such usage was urgently required since it had been found that there was progressive leaching of copper from copper-chrome-arsenate treated marine piles which could lead to a reduction in their service life. Hochmann (...
A F Preston, C M Chittenden


Isolation of soil borne bacteria and fungi from treated timber
2001 - IRG/WP 01-50174
Most research in the last few decades has focused on the development of new strategies to control biological attack and the means to quantify this. Comparatively little work has been done to examine the effect that treated timber might have on its surrounding environment. This presentation will describe a methodology that attempts to detect any changes which might occur in the soil microflora foll...
I Stephan, A Stegemann, G Heidrich


Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 21: Report of eighth inspection (7 years) in Australia
1985 - IRG/WP 4119
This report tabulates the seven year (86 month) inspection results, obtained on 28 Fabruary l985, of the IRG/COIPM International Marine Test at Goat Island, Australia. This test was installed in December 1977. The results are given in Tables 1-6. Table 7 lists the number of marine borers identified from blocks (2 cm and 6 cm long respectively) cut from the ends of specimens removed at the previous...
L J Cookson, J E Barnacle


Evidence for the participation of the osmiophilic particles in the enzymatic demethylation of lignin
1984 - IRG/WP 1239
Transmission electron microscopic observations of the white-rot fungi Trametes hirsuta and Phanerochaete chrysosporium grown on a series of wood pulp with a graded lignin content and mycelium from the clarified centre of an agar-medium containing lignin (E1-effluent from the bleaching process) showed that osmiophilic particles are only induced by native lignin. Taking into account that the osmioph...
K Messner, H Stachelberger


Microbial decomposition of salt treated wood
1993 - IRG/WP 93-50001-22
Specialized microorganisms which are able to convert fixed inorganic preservatives from treated wood into water soluble components are investigated. A number of brown rot fungi like Antrodia vaillantii have been isolated from cases of damage and examined under unsterile conditions with CCA-, CCB-, CCF- and CC-treated wood at retention levels of at least 50% higher than recommended for wood in grou...
R-D Peek, I Stephan, H Leithoff


A study of the colonization of wood blocks in a laboratory unsterile soil test
1988 - IRG/WP 2318
CCA treated and untreated beech blocks were exposed to a defined horticultural loam using the method proposed for the collaborative soft rot test in the soft rot sub-group of Working Group Two. At intervals during the incubation wood samples were removed and fungal isolations were made using selective media. Fungi were identified and tested for their cellulolytic ability and their decay capacity i...
M T De Troya, S M Gray, D J Dickinson


Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher


Contribution to the knowledge of wood-rotting fungi in Brazil. Part 1: Occurrence and distribution of fungi on different substrates from the Manaus region, Amazonas State
1995 - IRG/WP 95-10096
A total of 945 spezimens of fungi were studied with regard to their distribution on ditterent substrates, abundances and economic importance. The samples came from the collection ot the Wood Pathology Laboratory of CPPF/INPA in Manaus, Brazil. Altogether, 163 spezies and 87 genera were identified. The following genera Trametes, Auricularia, Panus, Rigidoporus and Hymenochaete were represently by m...
M Aparecida de Jesus


Copper storage in the digestive caecae of Limnoria tripunctata and Limnoria quadripunctata (Crustacea: Isopoda) tunnelling in CCA treated and untreated wood in laboratory cultures
1998 - IRG/WP 98-10257
Digestive tract tissues of Limnoria quadripunctata Holthuis and Limnoria tripunctata Menzies, tunnelling untreated and CCA treated Scot's pine sapwood under laboratory conditions were examined using X-ray microanalysis and transmission electron microscopy. Populations of both Limnoria species tunnelling treated and untreated wood stored copper within their digestive caecae in the form of ...
C Wykes, A J Pitman, S M Cragg


Preservative-efficacy of boric acid-triethanol amine solution against wood-decay fungi
1994 - IRG/WP 94-30050
Laboratory preservative-efficacy tests were conducted using boric acid-triethanol amine (BTEA) solution in accordance with the JIS A 9201 (1991) test method excluding the standard weathering process. Sapwood specimens of Picea jezoensis or Fagus crenata to achieve nominal retentions of 0.40-41.2 kg/m³ of boric acid were exposed to Tyromyces palustris, Coriolus versicolor, Serpula lacrymans or Cha...
S Doi, M Mori, Y Mineki


Association of contents of nitrogen and sugars in rubberwood (Hevea brasiliensis) clones with susceptibility to sapstain by Botryodiplodia theobromae, Aureobasidium pullulans and Aspergillus niger
1999 - IRG/WP 99-10307
The purpose of this study was to determine if nitrogen and sugar contents in rubberwood from three selected varieties (clones) rubber trees would affect the rate of colonisation by Botryodiplodia theobromae (a tropical sapstain fungus), Aureobasidium pullulans (a temperate sapstain fungus) and Aspergillus niger (a common mould fungus). Sapstain growth was rated daily until at least 50% mycelial co...
A J Ashari, J W Palfreyman, A H H Wong


Laboratory aquaria evaluation of CDDC (copper dimethyldithiocarbamate) against marine borers
1998 - IRG/WP 98-10262
The performance of CDDC (copper dimethyldithiocarbamate) and CCA (copper chrome arsenic) treated timber blocks was examined in a 1.5 year aquaria bioassay against the marine borers Limnoria tripunctata Menzies and Lyrodus pedicellatus (Quatrefages). Three timbers, southern yellow pine (SYP), Pinus radiata D. Don and Eucalyptus regnans F. Muell were treated with CDDC to retentions of 16, 32, 48 and...
L J Cookson, C R McIntyre, D Scown


Biological detoxification of wood treated with salt preservatives
1992 - IRG/WP 92-3717
The use of microorganisms that are capable to convert chemically fixed inorganic preservative complexes from impregnated wood waste into watersoluble components is investigated. A number of fungi were isolated from deteriorated and initially well-treated wood. They revealed an exceptionally high production of organic acids (pH 2). The fungi were identified and used together with others of the same...
I Stephan, R-D Peek


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