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CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Potential use of an emulsified tar oil fraction as a wood preservative: Preliminary technological and environmental assessment
1994 - IRG/WP 94-50028
In order to meet the recent environmental concern specifications of creosote are altered, the B[a]P content is limited and restrictions on the emission of volatile organic compounds (VOC) and higher polyaromatic hydrocarbons (PAH) are expected in some countries. Research has been conducted on an emulsion of a selected tar oil fraction. Using a waterborne formulation opens new perspectives for targ...
G M F Van Eetvelde, R Leegwater, M Stevens


A determination of the toxic level of ACQ2100 wood preservative for the powder post borer Lyctus brunneus (Stephens)
1994 - IRG/WP 94-20029
The sapwood of two Lyctus susceptible Australian hardwoods, messmate (Eucalyptus obliqua L'Herit.) and black bean (Castanospermum australe A. Cunn. et Fraser ex Hook) were pressure impregnated with ACQ2100, a wood preservative, to produce replicates of a range of retentions. Preservative retentions were determined by solution weight uptake at treatment and chemical analyses of selected sa...
A R Moffat


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Use of the enzyme-linked immunoassay (ELISA) and immunocytochemistry to detect soft rot in preservative treated and untreated wood
1990 - IRG/WP 2347
A polyclonal antibody was raised against mycelial extracts from the soft rot fungus Phialophora mutabilis. In ELISA assays, the antibody showed strong reactions with its own antigen and strong to moderate cross reactions with 6 other Phialophora soft rot species. With the exception of Ceratocystis albida, the antibody gave only weak or negative reactions with 11 other mold, blue stain and rot fung...
G F Daniel, T Nilsson


Acoustic technique for assessing decay in preservative treated wood
1998 - IRG/WP 98-20138
This study investigated the suitability of vibration techniques to assess the performance of wood preservatives in ground contact. Small stakes (10 x 5 x 100 mm3) of treated and untreated Scots pine sapwood were exposed to decay in lab-scale terrestrial ecosystems. Tests were conducted using three different soils including a garden compost soil, and soils obtained from a test field and a conifer f...
L Machek, M-L Edlund, R Sierra-Alvarez, H Millitz


Changes in transverse wood permeability during the drying of rimu and radiata pine
1990 - IRG/WP 3636
When softwoods are dried and subsequently impregnated with waterborne preservatives two problems frequently occur, preservative screening of multi-salt preservatives and difficult re-drying. To study the causes, the permeability of rimu and radiata pine wood has been measured along the three principal directions. The radial and tangential permeabilities of the green sapwood of the two species were...
R E Booker


Boracol 40 - A potential remedial and preservative treatment for lyctids
1983 - IRG/WP 1192
The paper reports on a preliminary assessment of the efficacy of a diffusion formulation, Boracol 40, when applied as a brush treatment: to the surface of Eucalyptus obliqua against the powder-post borer Lyctus brunneus. After a five month bioassay, Boracol 40 has severely retarded the progress of active infestations of Lyctus brunneus and has been 100 per cent effective as a preventative treatmen...
J W Creffield, H Greaves, C D Howick


New research data confirming the suitability of bifenthrin as a wood preservative
1996 - IRG/WP 96-30116
Bifenthrin has been further tested against wood destroying insects, and its behaviour in wood has been extensively studied. Bifenthrin proved to be highly effective as a curative and preventative treatment against Anobium punctatum and Hylotrupes bajulus, after both leaching and evaporative ageing. Results of penetration tests with water and solvent based formulations, applied by brushing, dipping...
S Shires, P Héloir, B Chen, G Rustenburg


Efficacy of a novel copper-based organic solvent preservative in laboratory and fungus cellar tests
1995 - IRG/WP 95-30071
The efficacy of Chemicca 4, a novel copper-based organic solvent preservative, was compared with that of other LOSP in pure culture laboratory decay tests and with that of CCA and TBTO in a fungus cellar exposure. It was markedly superior to copper and zinc naphthenates at equivalent metal retentions in laboratory decay tests, and similar in activity to TBTO. After 60 months' fungus cella...
M E Hedley, P N Maynard


Laboratory evaluation of disodium octaborate tetrahydrate (TIM-BORÒ ) as a wood preservative or a bait-toxicant against the Formosan and eastern subterranean termites (Isoptera: Rhinotermitidae)
1991 - IRG/WP 1513
A no-choice bioassay indicated that termite feeding was significantly reduced when wood was treated with TIM-BORÒ at retentions of >3600 ppm and >900 ppm (w/w) for Coptotermes formosanus and Reticulitermes flavipes, respectively, and thus these wood preservative retention rates may be considered for these termite species. Results of a choice bioassay suggested retention rates of 450-1800 pp...
N-Y Su, R H Scheffrahn


The Use of Modulus of Elasticity and Modulus of Rupture to Assess Wood Decay in Laboratory Soil-Bed Test
2006 - IRG/WP 06-20338
The efficacy of wood preservatives were determined in a soil-bed test. Samples of alder wood sapwood (Alnus glutinosa subsp. barbata) (5x10x100 mm) were treated with Solutions of CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Modulus of Elasticity, modulus of rupture, mass loss and decay rate according to AWPA E7 wer...
A Temiz, Ü C Yildiz


Measuring Soil Respiration as a New Approach to Describe the Interaction Between Wood (Treated and Untreated) and Microbiologically Active Soil
2006 - IRG/WP 06-20344
Soil respirometry was employed to examine the relationship between both the performance of copper organic preservatives in contact with and the amount of carbon dioxide evolved from soil and the effect of wood treated with preservatives on carbon turnover in soil. Wood was treated with a range of copper organic preservatives intended for use in ground contact as well as an organic preservative in...
I Stephan, W Mierke


How to win friends and influence the market — Service Life Prediction and performance-based durability assessments of wood products in construction
2006 - IRG/WP 06-20348
Due to direct and implied demands from the market and from e.g. the EU Construction Products Directive, the need to supply service life estimates for building products is growing. For several years, a development of Service Life Prediction (SLP) methodologies has been going on, but the awareness of this development has hitherto reached only a very limited extent in the wood sector. For materials w...
F Englund


Water analysis in chemicals, wood or chemically treated wood using a new analytical method for selective water detection
2006 - IRG/WP 03-30391
Water or moisture content analysis can be a challenging task in many applications. However, knowing accurately the type of water which can be found in a given sample or product can provide important information about a chemical compound used for wood treatment and especially about the treated wood sample. Moisture content in wood plays an important role in fungal growth and it needs to be extensi...
R Craciun, D Taylor


Investigation of new wood preservation formulations based on synergies between antioxidant, 2-HPNO and Propiconazole
2006 - IRG/WP 06-30401
Wood degradation by fungi is a complex phenomenon taking place in part through oxidative reactions involving many oxidizing agents like free radicals and hydroperoxide. In order to develop novel and more environmentally benign preservative systems, mixtures of Propiconazole and antioxidants with different stabilization mechanisms were investigated to detect possible synergies allowing to reduce th...
B Bakhsous, S Dumarçay, E Gelhaye, P Gérardin


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


The Development of a novel method to preserve reeds using an environmentally friendly timber preservative and a unique engineering design.
2006 - IRG/WP 06-40335
Reeds are used in the construction of bush lodges in Northern Kwa- Zulu Natal, South Africa. Fungal, insect and ultra-violet damage to these reeds is posing a severe problem. Within a space of two years, the reeds are attacked and have to be subsequently replaced; a time consuming and costly exercise. A novel method has been used to successfully preserve these reeds with an environmentally friendl...
K Govender, K G Moodley


Paintability and gluability of wood treated with arsenic-free and chromium free preservative treatments
2006 - IRG/WP 06-40342
The objective of this project was to study, in comparison with traditional CCA treatment, the paintability and gluability of wood treated with arsenic-free and chromium-free preservative treatments. Four formulations, all certified CTB P+, were selected in accordance with their representativeness of the preservative product market: one CCA reference formulation and three chromium and arsenic free...
L Podgorski, G Legrand


Corrosiveness of metal by copper-based preservatives
2006 - IRG/WP 06-40329
The corrosive rates of 4 types of metal as well as epoxy-coated metal by a variety of preservatives derived from different copper source and ingredients were conducted in this paper. The main results shown that: CCA is less corrosive to red brass and Q235A steel than other copper formulations; Copper-based preservatives such as ACQ and copper azole derived from basic cupric carbonate or cupric hyd...
Ying Zhang, Mingliang Jiang


Assessment of the ease of preservative treatment in the less-valuable Nigerian-grown Ceiba pentandra wood
2006 - IRG/WP 06-40330
The hardwood Ceiba pentandra locally known as “araba“ in Nigeria is rarely used for structural and construction works due to its high dimensional instability, low strength and durability values. Samples (25 x 50 x 600mm) were removed from four green boards (25 x 200 x 3000mm) of this species originating from a natural forest stand in Nigeria. The sapwood and heartwood were differentiated by me...
L Awoyemi, A J Pitman


Furfurylated wood - An alternative to Preservative-treated wood
2006 - IRG/WP 06-40349
Chemically modified wood is currently being marketed as a non-toxic alternative to traditional preservative treated wood (wood impregnated with biocides). Over the last decade the authors have developed modernised processes for wood modified by furfurylation. These new systems do not add metals or halogens to the product, which is important for an environmentally acceptable product. This presentat...
S Lande, M H Schneider, M Westin, J Phillips


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