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On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


CCB Preservative treatment of split muli (Melocanna baccifera ) bamboo by soaking process
2006 - IRG/WP 06-40336
This study was carried out in order to investigate the retention of chemicals inside the split muli ( Melocanna baccifera ) bamboo after preservative treatment by soaking process. Treatment with 10% aqueous solution of CCB (copper-chrome-boron) was applied in split bamboo of two sizes (1/4 part and 1/8 part) at three different moisture contents and five time periods (24, 48, 72, 96, 120 hours). It...
K Akhter, M H Chowdhury


Non-pressure preservation technique of five less durable timber species – Kadam (Anthocephalus cadamba), Shimul (Bombax ceiba), Pithalu (Trewia nudiflora), Am (Mangifera indica) and Boroi (Ziziphus jujube) of Bangladesh
2006 - IRG/WP 06-40322
Wood is a versatile renewable resource, which has been extensively used as a reliable construction material as well in furniture ever since the beginning of civilization. The Major disadvantage of wood is its susceptibility to biodeterioration by fungi, insects and bacteria. In tropical countries like Bangladesh, fungi is the most significant of these biodeterioration agents. Kadam (Anthocephalus...
G N M Ilias, A H Kabir, F Begum, M F Alam


Preservative treatment of Golla cane (Daemonorops jenkinsiana) by pressure process
2007 - IRG/WP 07-40379
The feasibility of preservative treatment of golla cane (Daemonorops jenkinsiana (Griff) Mart). by pressure process has been studied using water borne preservatives CCB (copper-chrome-boron). Cane samples of three different lengths 1m, 2m and 3 m. were treated at different pressure and time period to evaluate the extent of penetration and retention of preservative chemicals. It was observed that t...
K Akhter, M Hoque Chowdhury


Influence of Polyvinyl acetate emulsion (PVA) on boron leaching and fungicidal properties
2008 - IRG/WP 08-30451
Boron compounds are very effective fungicides, but unfortunately they leach from wood. In order to improve boron fixation, boric acid, borax were combined with polyvinyl acetate emulsion (PVA). For comparison copper salts were included into this research as well. Selected preservative solutions were chosen for impregnation of Norway spruce wood specimens (Picea abies). Wood blocks were exposed to ...
M Humar, B Lesar, P Kralj


Preliminary evaluation of efficacy of copper in combination with boron and NHA (N'-N-(1, 8-naphthalyl) hydroxylamine) against wood decay
2008 - IRG/WP 08-30452
In this study, efficacy of various combinations of copper sulfate with either boric acid or calcium precipitating agent, NHA-Na (N'-N-(1, 8-naphthalyl) hydroxylamine) was evaluated. Wood specimens were treated with either 1%, 0.5%, or 0.1% concentrations of copper sulfate, boric acid, NHA-Na, copper sulfate + boric acid, or copper sulfate + NHA-Na mixtures. Treated specimens were subjecte...
E Terzi, C Köse, S N Kartal


Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali


Comparison of laboratory and semi-field tests for the estimation of leaching rates from treated wood
2010 - IRG/WP 10-50274
The authorization of wood preservative formulations in the European Union according to the Biocidal Products Directive (BPD) includes the assessment of environmental risks by the emission of active ingredients. This risk assessment includes scenarios for preserved wood (e.g. house scenario, noise barrier), in which the predicted environmental concentration (PEC) for soil and water is calculated, u...
N Morsing, M Klamer, B Seidel, J Wittenzellner, M Maier, J Habicht


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Brief introduction to a research project on preparations of various paste formulations from boron, fluoride and copper for supplemental treatments
2022 - IRG/WP 22-30759
Wood preservatives to be used for supplemental purposes are present in various forms such as powders, liquids, rods, pastes, or gels. Boron compounds have been receiving a lot of attention in supplemental treatments since they have good mobility in wood. Application of boron compounds via internal treatments is vital to stop decay to be occurred inside the wood since large wood elements are too th...
E E Soytürk, D Bakır, E Terzi, C Köse, S N Kartal


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


Aspects of diffusion of boron through wood
1984 - IRG/WP 3298
Boron compounds have been shown to be toxic to a wide range of wood destroying insects and fungi. They are cheap, have low mammalian toxicity and their application in the treatment of wood does not demand specialized equipment. These attributes make them specially attractive to developing countries. Currently, however, little is known about the mechanism of diffusion of boron through wood. Effecti...
S Iddi


Utilization of curcumin for detection of presence of boron in wood
1982 - IRG/WP 3191
It has been shown that curcumin is not a reliable reagent for detecting boron in wood that has been attacked by fungi...
M-L Edlund


Influence of different fixation and ageing procedures on the leaching behaviour of copper from selected wood preservatives in laboratory trials
2003 - IRG/WP 03-20264
The paper focuses on the role of different parameters, such as fixation, sample size, wood species, and leaching in internationally standardized ageing procedures for wood preservatives from Europe, Japan and the United States. The leaching protocols used were EN 84, JIS K 1571 and AWPA E11 protocols. The wood species were Scots pine, Sugi and Southern Yellow Pine respectively. Three types of com...
J Habicht, D Häntzschel, J Wittenzellner


Strength loss associated with steam conditioning and boron treatment of radiata pine framing
1987 - IRG/WP 3438
The combined effect of included defects and wood moisture content on the strength loss of second rotation radiata pine framing following conventional steam conditioning is investigated. The green Modulus of Elasticity (MOE) is reduced by approximately 13% after steaming. When dried after steaming, however, neither the MOE nor MOR is significantly different from unsteamed dried controls....
M J Collins, P Vinden


Non-pressure treatability of plywood by CCA, CCB and boron
2005 - IRG/WP 05-40295
Study on diffusibility and absorbability of CCA, CCB and boric acid in 3 mm thick 3-ply hardwood plywood at water saturated and air-dry conditions and dipped at same concentration (5%) and same duration of time (12 hours) revealed complete diffusion of all the preservatives at water saturated condition. Only the CCA-C was found absorbed by the plywood at air-dry condition. The rate of absorption a...
A K Lahiry


Types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand
1984 - IRG/WP 1226
The few reported failures of 11-12-year-old horticultural posts in New Zealand in 1982 were caused by brown-rot. A subsequent survey of CCA-treated posts in all the major horticultural areas has revealed decay of many posts. A microscopic examination of these posts has shown decay by brown-rot, white-rot, soft-rot and bacteria. Several types of bacterial decay have been observed....
J A Drysdale, M E Hedley


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Third update and first report
1996 - IRG/WP 96-10174
At the 24th annual meeting of IRG in Orlando, USA, in May 1993 an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives, copper-chrome-arsenic (CCA) and copper naphthenate (Cu-Na) against the subterran...
J R J French


Synergistic effect of boron on Streptomyces rimosus metabolites in preventing conidial germination of sapstain and mold fungi
1992 - IRG/WP 92-1565
We evaluated the synergistic effect of boron (4% BAE solution of Tim-Bor or 4% boric acid) on Streptomyces rimosus metabolites in preventing spore germination of sapstain and mold fungi using plate bioassay, Southern yellow pine and sweetgum block tests, and green pine log sections: sapstain -- Ceratocystis coerulescens, Ceratocystis minor, and Aureobasidum pullulans; mold fungi -- Aspergillus nig...
S C Croan, T L Highley


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