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Potential for migration of boron from fused boron rods used as internal remedial treatments of utility poles
2014 - IRG/WP 14-50301
The distribution of boron in Douglas-fir utility poles and in the surrounding soil was assessed over a 54 month period following application of fused boron rods. Boron levels in the wood never reached the levels that might be predicted if diffusion were to produce a uniform chemical distribution, nor did levels in the soil suggest that boron was becoming more concentrated. The results suggest th...
M Konkler, C Freitag, C S Love, J J Morrell, J Renfroe


Migration of copper from copper naphthenate treated Douglas-fir poles during storage
2014 - IRG/WP 14-50302
Preservative migration from treated wood products has raised concerns among regulators, especially when the biocides move into surface waters. In most cases, chemical levels are well below the acceptable minimum level, but can become a concern if large quantities of treated wood are stored in one location. One such case would be a location where utility poles are stored for use in emergency repai...
C S Love, C M Freitag, J J Morrell


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Effects of thermal modification on properties of Douglas-fir heartwood
2014 - IRG/WP 14-40663
The flexural properties and mass losses of thermal modified Douglas-fir pretreated with boron or glycerol were examined. Pretreatments were associated with slight, but not significant, reductions in modulus of rupture (MOR) and modulus of elasticity (MOE)of Douglas-fir at different thermal treatment levels. Boron pretreatment had the greatest effect on MOR. MOR of non-pretreated and ...
Li Yan, J J Morrell


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Comparison of gauge and assay retention in crossties treated with copper naphthenate
2014 - IRG/WP 14-40667
Creosote has been the most widely used preservative for wooden railroad crossties or sleepers for over 100 years. Alternative preservatives such as copper naphthenate (CuN) have been shown to provide equivalent performance against decay fungi and wood destroying insects; however, the use and specification of CuN involves an education process for treaters and railroad customers alike. One differe...
J Brient, H Tomlinson, J Hughes


Buffered Amine Oxide Treatment Systems for Ammonical Copper Wood Preservatives
2014 - IRG/WP 14-40685
Wood is the most versatile, practical and sustainable building material in the world. In modern countries, wood is a well-managed renewable resource that has a small carbon footprint. Wood does suffer from a lack of durability against invasive organisms such as insects and fungi. Steel, aluminum and composites have emerged as viable alternative building materials. These sectors market the defi...
R W Clawson Jr


Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


Douglas-fir PSL Treated with Oilborne Copper Naphthenate – Treatment Experience & Efficacy
2014 - IRG/WP 14-40687
Treating characteristics, field stake efficacy and the results from treatment trials for oilborne copper naphthenate (CuNap) and Douglas-fir parallel strand lumber (PSL) are summarized in this paper. Treatment with a P9 Type-C based solution in laboratory tests showed full cross section penetration of large cross sections could be achieved. Commercial treatment trials using a P9 Type-A solution ...
G P Merrick


Evaluation of color and gloss in decorative applied to cases of Pinus radiata wood impregnated (D. Don) copper type C azole micronized
2015 - IRG/WP 15-20571
Six treatments (one control and five decoration coatings) were applied to radiata pine wood treated with micronized copper azole (uCA-C), for outdoor use (R3) at a rate of 3.08 kg/m3 retention (T2). One decoration coating was applied before impregnation treatment: Prestain P (T3), and two, were applied in mixture with the uCA-C preservative Black Cylinder (T5) and Red Cylinder (T4). Two varnish we...
R Garay, M Inostroza


Factors Affecting Performance of Preserved Wood Decking Against Decay Fungi
2015 - IRG/WP 15-30663
Decking is the largest market for residential preserved wood in the United States. Preserved decking must be resistant to colonization by decay fungi initiating from spores, and occasionally from mycelia due to elevated soil levels or adjacent untreated wood. The most vulnerable parts of a preserved wood deck are untreated, or under-treated, wood that becomes exposed by field cuts and checking. Fi...
R Stirling, P I Morris


Search for an anti-sapstain treatment for fresh radiata pine wood in compliance with European BPD norms: Field Tests
2015 - IRG/WP 15-30673
In response to the impending restrictions on the use of pesticide active ingredients developed to control the staining of fresh wood, as a result of regulation issued in 2009 by the European Union, a project was proposed to test an alternative anti-sapstain treatment that meets both the European restrictions and the performance required for an export-quality radiata pine fresh wood treatment. A se...
P Montes C, T Hanke W


Remedial treatment of difficult to access timber in buildings
2015 - IRG/WP 15-40691
The quest to understand remedial treatment for timber framing begun following the ‘leaky building crisis’ in New Zealand which came to prominence in 2000. Several in-situ remedial treatment products are used in New Zealand. However, effectiveness of these treatments is still unclear particularly in situations where not all faces of the timber can be assessed. This research was conducted to det...
T Singh, I Simpson, D Page


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


Environmental Fate of Micronized Copper
2015 - IRG/WP 15-50310
The environmental fate of wood preservatives is an important aspect to estimate the health and environmental impact. Although biocides from treated wood may be released into the soil, water or air, the latter pathway is frequently neglected in favour of leaching studies. Nonetheless, wood dust is well known to cause a variety of adverse health effects, in particular diseases to the respiratory tra...
C Civardi, L Schlagenhauf, J Benz, C Hirsch, J Van den Bulcke, M Schubert, J Van Acker, P Wick,


Recycling of used railroad ties via two-staged pyrolysis for fractionation of wood preservatives and bio-oil: pyrolytic characterization by TGA and Py-GC/MS
2015 - IRG/WP 15-50311
Creosote and copper naphthenate (CuNap) (in an oil carrier) treated railroad tie materials (crossties or sleepers) were initially heat-treated at 200 – 300 oC and subsequently pyrolyzed via thermogravimetric analysis (TGA) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) to recover wood preservatives and produce a higher quality bio-oil. Preservative-desorptive temperatures at 200 a...
Pyoungchung Kim, J Lloyd, Jae-Woo Kim, N Labbe


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


The copper-transporting ATPase pump and its potential role in copper-tolerance
2016 - IRG/WP 16-10859
Copper-tolerant brown-rot decay fungi exploit intricate mechanisms to neutralize the efficacy of copper-containing preservative formulations. The production and accumulation of oxalate is the most widely recognized theory regarding the mechanism of copper-tolerance in these fungi. The role of oxalate, however, may be only one part of a series of necessary components required for this complex mecha...
K M Ohno, C A Clausen, F Green III, G Stanosz


Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton


Performance of copper treated poles and posts after three to fifteen years of exposure
2016 - IRG/WP 16-20595
Copper based wood preservatives are one of the most important wood preservatives for heavy-duty applications. Wood treated with copper-based preservatives performs excellent if applied according to preservative specifications. If used improperly premature failures might appear. In order to elucidate properties of copper treated wood in use, utility poles and posts treated with copper-based preserv...
M Humar, N Thaler


Moisture monitoring in WW2 partisan hospital Franja
2016 - IRG/WP 16-20596
Material climate of wood used for construction of WW2 Partisan hospital Franja was monitored for approximately one year. Partisan hospital is located in the bottom of tiny gorge Pasice in Slovenia. Hence, wood moisture content on eight respective location and wood temperature was determined twice per day with Scanntronik equipment Gigamodul and Thermofox. The results clearly showed that despite of...
M Humar, N Thaler, B Lesar, A Žagar


Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick


Evaluation of advanced tannin-boron preservative in unsterile soil-bed tests
2016 - IRG/WP 16-30693
In Europe, boron compounds are facing restrictions, and due to their natural solubility into water, the only way to keep using them for wood protection is to fix them into the wood, at very low level (Obanda et al. 2008). In the meantime, the idea of protecting wood with natural preservatives has been back into favour (Lotz and Hollaway 1988, Nakayama et al. 2001, Singh and Singh 2012). Tannin a ...
Jinbo Hu, Yiqiang Wu, Shanshan Chang, Guangming Yuan, G Tondi, M-F Thévenon


The durability of manufactured structural building materials
2016 - IRG/WP 16-40718
The projected market potential for Engineered Wood Products such as CLT (cross laminated timber) is very positive however, potential prolonged rain leakage or moisture exposure during construction and in-service could pose considerable concern for its durability and reputation. This research was conducted to assess the decay resistance of CLT and OSB (oriented strand board) in an accelerated trial...
T Singh, D Page


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


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