Your search resulted in 725 documents. Displaying 25 entries per page.
FTIR characterization of copper ethanolamine - wood interaction
1999 - IRG/WP 99-20154
The interaction of copper ethanolamine (Cu-EA) and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735±5 cm-1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595±5 cm-1. The same observation was made ...
Jun Zhang, D P Kamdem
Changes of EPR spectra of wood, impregnated with copper based preservatives, during exposure to Antrodia vaillantii
2000 - IRG/WP 00-10355
Spruce wood (Picea abies) samples were impregnated with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1,0 x 10-2 mol/l). Impregnated and unimpregnated test pieces were exposed to wood rotting fungus Antrodia vaillantii. Some strains of this fungus are known as copper tolerant. After four weeks of exposure to A. vaillantii, we could not detect ...
M Humar, M Petric, F Pohleven, M Šentjurc
Influence of water-borne preservatives on water repellency and the impact of addition of water repellent additives
1992 - IRG/WP 92-3704
The primary goal of a desirable wood preservative system is to effectively control decay fungi and other biodeteriogens in service. The water repellent nature of a given system may play an important role in the protection of wood. In this study, the water repellency of several water-borne preservative systems has been evaluated by measurements of tangential swelling during immersion. The systems i...
L Jin, D M Roberts, A F Preston
Thickened boron treatment
1990 - IRG/WP 3632
Commercial trials with thickened boron preservatives "Diffusol™" indicate a number of advantages when compared to traditional methods of dip-boron preservative treatment. These include: (i) more even uptake and distribution of preservative on and within the timber; (ii) faster diffusion times; (iii) the treatment of gauged timber (though improved retention); (iv) saving in energy costs (heating ...
P Vinden, J A Drysdale, M Spence
The development of a new boron-based wood preservative
1995 - IRG/WP 95-30085
The paper describes a new boron based wood preservative for the treatment of green timber. The product offers many benefits over conventional boron diffusion treatment including: 1. high viscosity, high concentration formulation; 2. permits dip treatment of a wide range of sawn board and pole sizes at ambient temperatures; 3. permits full cross section diffusion of borates without block stacking a...
P Turner, D Conradie
Treatment of wood with boron esters
1995 - IRG/WP 95-30087
The treatment of wood and wood products with boron esters is reviewed. The physical and chemical characteristics of boron esters affecting the treatability of wood are discussed, in particular thermal decomposition and rates of hydrolysis. The uses and methods applying boron esters as wood preservatives include: (i) Solutions of boron esters for remedial and diffusible treatment of wood; (ii) soli...
J Romero, P Vinden, J A Drysdale
Gaseous preservative treatment of wood
1990 - IRG/WP 3631
A recent development in processing wood with a gaseous preservative means that dry, treated wood can be produced in under 30 hours with the benefits of product diversification, faster stock turnover and the ability to respond to short term demand. About 400,000 m³ of wood are treated each year in New Zealand with boron salts to protect from borer infestation. Traditionally this treatment is effec...
R Burton, A J Bergervoet, K Nasheri, P Vinden, D R Page
The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie
Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi
The movement of iron into field test stakes
1987 - IRG/WP 2284
Failed and sacrificial stakes recovered from the Westham Island field test site were examined for their iron content. Varying amounts were recorded, which were greatest in the failed stakes. The possible role of the iron taken up by the below ground portion of the stakes, in accelerating the decay process and/or the preservative leaching is under investigation. The reaction of the iron with the ch...
J N R Ruddick, P I Morris
Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek
Impact of leachates from CCA- and copper azole-treated pine decking on soil-dwelling invertebrates
2002 - IRG/WP 02-50183
This study assessed the short-term effects on non-target soil invertebrates of leachates from a naturally durable hardwood and timber treated with two copper-based wood preservatives. Natural rainwater leachates from kwila decking, and radiata pine-decking treated with CCA or copper-azole, were collected and applied on mown lawn soil in Brisbane, Queensland. The soil study consisted of 5 treatment...
N Crumière, A House, M J Kennedy
Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon
Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen
A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick
A technique for determining the efficacy of water diffusible preservative plugs for implanting in joinery in service
1987 - IRG/WP 2291
A technique is described for determining the efficacy of soluble, diffusible preservative plugs for eradicating decay in joinery. It uses blocks of Scots pine sapwood or heartwood adjusted to known moisture contents prior to the establishment of the test fungus Coniophora puteana, from a single longitudinal dowel and the subsequent introduction of the preservative plugs. Prevention of decay, eradi...
J K Carey, A F Bravery
Termite resistance of treated wood in an above-ground field test
1985 - IRG/WP 2241
A field test method has been developed for evaluating the susceptibility of wood products to termites in protected situations above ground. In this method fungal attack on the wood products is minimal, though decay has been observed in conjunction with termite attack in some specimens. Preliminary results from exposure of replicate wood samples treated with preservatives in Florida to Reticuliterm...
A F Preston, P A McKaig, P J Walcheski
Protection of cellulose string with biocide/water repellent mixtures
1997 - IRG/WP 97-30148
Protecting cellulosic materials in soil contact poses a formidable challenge. Many soil inhabiting bacteria and fungi that cannot degrade wood can nevertheless rapidly depolymerize cellulose once its protective lignin matrix is removed. As a result, cellulose based materials are rarely used in direct contact with soil. One exception, however, is the use of cellulose string to support climbing vine...
A B Chang, J J Morrell
A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis
The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield
Copper tolerance of various Antrodia vaillantii isolates
2001 - IRG/WP 01-10406
Copper based preservatives have been extensively used in the field of wood preservation. However, several brown-rot fungi to be tolerant to copper and consequently, efficacy of copper based wood preservatives may not be sufficient. Copper tolerance is especially by some fungi that are closely aligned to or included in genus Antrodia. The highest copper tolerance was found at some strains of wood r...
F Pohleven, A Malnaric, M Humar, C Tavzes
The influence of timber species and preservative treatment on spore germination of some wood-destroying Basidiomycetes
1988 - IRG/WP 2300
Basidiospores from six wood decay fungi exhibited varying germination rates on untreated softwood and hardwood blocks. Germination inhibition of all test fungi was recorded on pine sapwood. No preference for a certain timber species by a particular fungus was evident. Whereas almost complete inhibition of germination occurred on wood treated with a quarternary-ammonium based wood preservative, mos...
B M Hegarty, G Buchwald
Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem
The microbial ecology of treated birch stakes in a soil-bed
1983 - IRG/WP 1209
The microbial ecology of small birch stakes exposed in soil beds in two Fungus Cellars was investigated. Patterns of fungal colonisation and decay initiation are described in untreated birch and copper fluosilicate-treated stakes. Results are based on fungal isolation onto selective media and direct light microscopical observations of decay features. In untreated stakes there was a rapid build-up ...
C P Clubbe
Limnoria quadripunctata Holthuis - a threat to copper-treated wood
1983 - IRG/WP 4100
This paper presents the first reported attack by the crustacean marine wood-borer Limnoria quadripunctata Holthuis of CCA treated eucalypt piles. The attack occurred after 12 years service of the piles in the River Derwent at Hobart, Tasmania. Attack by both this borer and Limnoria tripunctata Menzies is also reported in CCA treated softwoods and hardwoods over periods ranging from 5 to 22.9 years...
J E Barnacle, L J Cookson, C N McEvoy