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Tests with ammoniacal copper and alkyl ammonium compounds as wood preservatives
1984 - IRG/WP 3299
Formulations based on copper and alkyl ammonium compounds in ammonia solution have been tested in a fungus cellar on Pinus radiata and Fagus sylvatica. This type of products gives promising results as wood preservatives, especially on hardwood and are safe to destroy by e.g. combustion. The best results were achieved with a dialkyl ammonium compound, Cu/octyldecyl dimethyl ammonium chloride (NH3)....
C-E Sundman


Lignin degradation by a non-enzymatic system supposed to be active in white rot fungi
2000 - IRG/WP 00-10340
Electron microscopic investigations have shown that ligninolytic enzymes of white-rot fungi are only able to penetrate the wood cell wall in late stages of degradation. Thus, the selective degradation of lignin of certain white-rot fungi can only be explained on the basis of a low molecular weight, highly diffusible system. A system, consisting of copper, a coordination compound and either H2O2 or...
P Lamaipis, W Gindl, T Watanabe, K Messner


Tolerance of Wood Decay Fungi to Commercial Copper Based Wood Preservatives
2002 - IRG/WP 02-30291
Due to the use of copper based preservatives like CCB or CCA for more than a century, copper tolerant fungi have appeared in some European countries in recent times. It is therefore important to find out whether this phenomenon is specific for only classical copper ingredients, or generally for all copper based formulation. Thus, we tested the tolerance of three commercial copper based pres...
F Pohleven, M Humar, S A Amartey, J Benedik


Effect of vapour boron treatment on mechanical properties of wood based board materials
1992 - IRG/WP 92-3727
The mechanical properties of Medium density fibre board, Chipboard and Oriented strand board were investigated after treatment to two retention levels of boric acid applied as a vapour phase system. A range of mechanical properties were investigated. The vapour boron treatment does not have any significant effect on most of the mechanical properties of the boards. The exception is a reduction in i...
R Hashim, D J Dickinson, R J Murphy, J Dinwoodie


A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


Surface accumulation of copper on CCA-impregnated Pinus patula stakes during marine preservative trials in the southern hemisphere
1992 - IRG/WP 92-4181
Pinus patula stakes treated with CCA to target retentions of 30 kg/m³ salts were exposed to sea water in marine and estuarine ecosystems off the coast of Southern Africa for two years. Samples were then analysed for copper and arsenic. Analysis of samples from the marine ecosystem showed (IRG/WP/4167) that arsenic was longitudinally and transversely leached from the wood, whereas the copper was r...
G D Shelver, C D McQuaid, M Tarin, A A W Baecker


New boron-based biocides for the protection of wood
2002 - IRG/WP 02-30283
Boric acid and other simple inorganic oxides of boron are amongst the oldest wood preservatives currently in use. Their relatively low toxicity and broad-spectrum activity are just some of their desirable characteristics. The primary disadvantage associated with conventional boron-based preservatives is their lack of permanence in exposed applications. A collaborative project between CSIRO and the...
D G Humphrey, P J Duggan, E M Tyndall, J M Carr, L J Cookson


Field evaluation determining the toxic effect and diffusion properties of Impel, Improsol and TBTO-capsules in L-joints (spruce) for pretreatment application
1991 - IRG/WP 3641
Bonded joints (L-joints and T-joints) are especially at risk from water absorption (rain, condensation) over bare, unprotected radial wood surfaces (joggle joints). It is therefore quite certain that lasting protection against fungi attack cannot be guaranteed in the long term if the surface of coating is damaged. Therefore, in a field investigation, using L-joints (spruce) over a total period of ...
R Gründlinger, K Messner, O Janotta


The emission of boron compounds from treated particleboard
2000 - IRG/WP 00-40179
The emission of chemical vapours can be harmful both during treatment and service of wood and wood products. Samples of Standard particleboard (for interior use) were treated with trimethylborate, and a number of modified organo-boron compounds. Treated samples were placed immediately under a desiccator lid and air was drawn across each samples to 3 water traps. Water samples were taken after 30, ...
K M Filcock, P Vinden


Non leachability of arsenic, copper and chromium from 15 years old CCA-C treated southern pine poles used in brackish water as jetty piles in Bangladesh
1998 - IRG/WP 98-50103
Revealed that chromated copper arsenate type C (CCA-C) treated southern pine poles used in Central Warehouse Jetty of REB, Khulna are stable and resistant to chemical and biological attack without loss of any component from outer 0-12.5 mm zone after 15y of use. Slightly reduced retention (4.44% less) was noted in above water location of piles (bottom end of tree) which would be due to continuous ...
A K Lahiry


Emissions from the combusting of boron and fluoride containing wood
1995 - IRG/WP 95-50040-18
The combustion properties of waste wood and wood residues containing wood preservatives were investigated in several test series after having been blended with untreated wood at a ratio of 1:4. The results for CFB, SF and boric salt show that, provided an optimized combustion, the concentrations of the stack pollutants correspond approximately with those found for untreated wood. Only during the c...
T Salthammer, H Klipp, R-D Peek


The effect of pretreatments on the impregnation of air-dried sawn Belgian spruce
1988 - IRG/WP 3490
In general the impregnation of airdried spruce results in a variable treatment and limited penetration. This is the result of pit aspiration that occurs during drying of the spruce sapwood and heartwood. Spruce timber is becoming of greater importance in Belgium and hence research for better treatment of this vulnerable wood species is needed. Squared airdried timber of different dimensions were e...
J Van Acker, M Stevens


Water-Borne Copper Naphthenate: An Emerging Wood Preservative
2002 - IRG/WP 02-30280
Waterborne copper naphthenate (WB Cu-N) was used to treat southern yellow pine (Pinus spp) and red maple (Acer rubrum) stakes. The treated stakes were exposed in test sites located in Florida, Michigan and Mississippi for 3 to 6 years. Copper Chromium Arsenate (CCA), Ammoniacal Copper Quat (ACQ) and Oil-borne Copper Naphthenate (OB Cu-N) were also used to treat some stakes for comparison. Results...
P Nzokou, D P Kamdem, M H Freeman


Borate-treated food affects survival, vitamin B12 content, and digestive processes of subterranean termites
1990 - IRG/WP 1448
Toxicity of boron compounds was studied by analyzing survival rates and vitamin B12 contents in Formosan subterranean termites, Coptotermes formosanus Shiraki, that were exposed to dietary treatments for 10 days. The dietary treatments applied in moistened cellulose were (a) 0.05% boric acid equivalent (BAE) of disodium octaborate tetrahydrate, (b) 0.05% BAE of anmonium pentaborate plus sodium sul...
L H Williams, S I Sallay, J A Breznak


Laboratory and field trials of novel antisapstain formulations
1997 - IRG/WP 97-30146
This document covers the results of laboratory and field trials of combinations of fungicides formulated using a patented technology (PCT NZ 96/00143). A 3 week laboratory trial that uses radiata pine (Pinus radiata D. Don) branch discs as a substrate was used to determine which combinations possessed a suitable spectrum of fungitoxicity against key sapstain, mould and decay fungi. In particular f...
R N Wakeling, P N Maynard, D R Eden, C M Chittenden, B Carpenter


Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell


Laboratory evaluation of copper naphthenate pressure treatments against the Formosan subterranean termite
1993 - IRG/WP 93-10005
Southern pine wafers and Douglas-fir cubes pressure treated with copper naphthenate in AWPA P9 Type A oil or in toluene were evaluated for resistance to attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Wood samples were pressure treated to target copper retentions of 0.040, 0.075, 0.095, or 0.150 pcf, conditioned to simulate field exposure, a...
J K Grace, R T Yamamoto, P E Laks


Effects of cyproconazole and copper sulphate on the length of the hyphal growth unit (HGU) of the white-rot fungus Coriolus versicolor
2003 - IRG/WP 03-10473
Wood decay basidiomycetes have been shown to produce appreciable quantities of extracellular mucilaginous materials (ECMM). The relationship between ECMM and total biomass production has been investigated in the white-rot fungus Coriolus versicolor (CTB 863 A). Differences in the amount of ECMM produced by the fungus proportionally to the total biomass, were observed under a range of physiological...
D Vesentini, D J Dickinson, R J Murphy


Chromium in wood preservation: Health and environmental aspects
1978 - IRG/WP 3120
The majority of water-borne salts in current use contain hexavalent chromium, usually as dichromate or chromium trioxide. In about 1913 it was suggested that chromates, phosphates or borates could be added to the sodium fluoride and dinitrophenol mixtures then in use in order to inhibit corrosion. Dichromates were found to be most suitable and the resulting mixture known as Thriolith and later Tri...
T R G Cox, B A Richardson


Wood surface pretreatments with metal tannates
1989 - IRG/WP 3552
The sequential application of aqueous solutions of tannins derived from radiata pine bark and water-soluble metal salts was examined as a means of improving the water repellency of wood surfaces. Nine metal salts were screened in combination with tannin solutions and, based on water repellency of pretreated filter paper, four were selected for further study. The two-step application of tannin solu...
D V Plackett, D R Cronshaw


A study of poplar LVL durability improvement:
1999 - IRG/WP 99-40148
The aim of this study was to optimise the durability of LVL panels by adding boron during the gluing process. Poplar veneers (2,6 mm thickness ) were selected by ISORY a French company . Two types of glue were tested : Phenol resorcine and Melamine Urea Formaldehyde. Each of them was mixed with various concentrations of borax (for the first one) and Boric acid(for the second one). Mechanical prope...
B Charrier, V Bridaux, N Fauroux, F Charrier


Recovery of copper chromium and arsenic from old CCA treated commodities
1998 - IRG/WP 98-50118
Due to the expected increase in spent treated wood over the next several decades, numerous means to reuse and recycle preserved wood have been proposed. Burning this wood for cogeneration or recycling of CCA treated wood into reconstituted composites are possible methods, but they are limited to laboratory scale because of environmental air emission issues and the manufacturing process. In the av...
D P Kamdem, Wanli Ma, Jun Zhang, J Zyskowski


Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven


Performance of preservative-treated wood not in ground contact
1975 - IRG/WP 254
Experimental sash units of Pinus strobus L. and Pinus resinosa Ait. wood were removed from a test fence at Ottawa, Canada after outdoor exposure of over 20 years. The units were superficially treated, prior to painting, with preservatives containing either copper naphthenate, pentachlorophenol or a combination of zinc naphthenate and pentachlorophenol. Results indicated that all treatments were ef...
J K Shields, J Krzyzewski


Field evaluation of the above-ground susceptibility of Pinus heartwood and untreated or treated sapwood to two species of Australian subterranean termites
1996 - IRG/WP 96-10147
Plantation-grown Pinus elliottii, Pinus caribaea and Pinus radiata specimens containing heartwood and untreated or preservative-treated sapwood were exposed above ground to the subterranean termites Coptotermes acinaciformis or Mastotermes darwiniensis near Sydney (NSW), Brisbane and Townsville (Qld), and Darwin (NT), using a variety of exposure techniques. Heartwood of Pinus elliottii and Pinus c...
M J Kennedy, J W Creffield, R H Eldridge, B C Peters


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