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Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Comparison of laboratory and semi-field tests for the estimation of leaching rates from treated wood
2010 - IRG/WP 10-50274
The authorization of wood preservative formulations in the European Union according to the Biocidal Products Directive (BPD) includes the assessment of environmental risks by the emission of active ingredients. This risk assessment includes scenarios for preserved wood (e.g. house scenario, noise barrier), in which the predicted environmental concentration (PEC) for soil and water is calculated, u...
N Morsing, M Klamer, B Seidel, J Wittenzellner, M Maier, J Habicht


Fungal biodegradation of CCA-treated wood wastes
2011 - IRG/WP 10-50276
Fungal biodegradation could be employed as a pretreatment method to alleviate problems caused by landfill disposal of CCA-treated wood wastes (e.g. a shortage of landfill space and a release of leacheate). It could be used to decrease the volume of waste and to remove metals from waste simultaneously. We have screened hundreds of decay fungi, including fungi isolated from CCA-treated wood in servi...
Gyu-Hyeok Kim, Yong-Seok Choi, Jae-Jin Kim


Decay resistance attributes of teak (Tectona grandis L. f.) wood: comparison of the fungicidal activities of quinones
2011 - IRG/WP 11-10752
The implication of quinones in decay resistance of teak wood is controversial. To better understand the role of individual quinone in this property, we studied the correlations between this latter and the content of 2-(hydroxymethyl)anthraquinone, tectoquinone, anthraquinone-2-carboxylic acid, 1,4-naphthoquinone, lapachol and the new compound 4’,5’-dihydroxy-epiisocatalponol found in teak wood...
F B Niamké, N Amusant, N Lemenager, G Chaix, M-F Thévenon, C Baudassé, S Kati-Coulibaly, A Amissa Adima, I Gossan Ado, C Jay-Allemand


Measuring fungal cellulolytic enzyme activity in degrading wood
2011 - IRG/WP 11-10753
An enzyme assay which measures enzyme activity directly from wood will assist in the fundamental understanding of the enzyme components of the decay mechanism of rot fungi and any changes in the presence of wood protectants. At present, to measure fungal carbohydrate degrading enzyme activity in the presence of wood, two methods are used: either 1) the enzyme is measured in the growth media contai...
S M Duncan, J S Schilling


Quantification of four dark colored mould fungi by real time PCR
2011 - IRG/WP 11-10754
Coated wooden claddings in building facades are widely used in the Scandinavian countries, and are often preferred to other materials. Wood is facing increasing competition from other materials that are less labor intensive at the construction site and materials with less demand for maintenance thru service life, and makes further development of wooden claddings essential. Growth of discoloring mo...
E Larnøy, L Ross Gobakken, A M Hietala


Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


Sample Origin Influencing the Leachability of Wood Preservatives
2011 - IRG/WP 11-20474
The aim of this study is to see if the raw material influences fixation and leachability of wood preservatives. Moving towards more eco-friendly and –concious society, the wood industries must adjust itself to new rules and regulations. Greener solutions in wood protection are being tested and introduced, older systems are being improved, but questions still arise concerning some elements curren...
K Kängsepp. E Larnøy, P Meier


Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives
2011 - IRG/WP 11-30556
Copper ethanolamine based preservatives are currently the most important solutions for impregnation of wood in ground contact in Europe. One of the issues related to those and similar water based solutions is insufficient penetration to refractory wood species like Norway spruce. In order to elucidate this issue, commercial copper ethanolamine based solution was supplemented with five different wo...
M Humar, N Thaler, B Lesar


Characterisation and evaluation of various chitosan oligomers, and decay resistance
2011 - IRG/WP 11-30562
Chitosan, a polymer of D-glucosamine, is known for its antimicrobial activity. However, the physicochemical properties of chitosan depend upon three principal factors, i.e. source of raw material, molecular weight and degree of deacetylation. Here, we report synthesis and characterization of chitosan oligomers prepared by deaminative depolymerization of chitosan (s) obtained from Sigma Aldrich and...
I Hussain, C Chittenden, T Singh


Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The potential for using CuO nanoparticles as a wood preservative
2011 - IRG/WP 11-30569
The potential for using nano-copper particles for wood protection was investigated using mini-agar slant and wood block tests with Gloeophyllum trabeum or Trametes versicolor. Nano-copper was more effective against G. trabeum than T. versicolor, although neither of these fungi would be considered copper tolerant. Nano-copper solutions were stable over a 17 week storage period, but precipitated w...
I S Weitz, K Knani, M Maoz, C Freitag, J J Morrell


The resistance to Basidiomycetes fungi of chipboard 35 years after their industrial preservation with wood preservative on fluoroborate basis
2011 - IRG/WP 11-40546
The research on wood-based panels’ (WBP) behaviour towards fungi impact demonstrated rather low resistance of wood-based materials to wood rotting fungi. However, these materials are used in construction under conditions favourable to fungi growth. In such conditions WBP treated with wood preservatives should be used. Preservation durability is of great importance in such cases. The resistance o...
A Fojutowski, A Kropacz


Study of the durability of the Maderon® against wood decay fungi and insects
2011 - IRG/WP 11-40548
Many industries produce residues that are not easily degradable. One of these is nut husks which, due to their high level of resistance to biological and environmental degradation, have become an ecological problem. Maderón® is a material invented and patented in Spain employed as an ecological substitute and a modern alternative to certain uses of wood. At present, Maderón® is commercialized ...
M T Troya, F Llinares, P Jiménez, J I Fernández-Golfín, M Conde, R Díaz


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Evaluation of an optimized industrial process aiming to improve the natural durability and mechanical behavior of bamboo for outdoor use
2011 - IRG/WP 11-40554
Mao Bamboo (Phyllostachys pubescens) is characterized by high contents of sugar and starch and by high hygroscopicity, which makes it susceptible to biodegradation, and specifically to fungal decay. Still, many bamboo based products regularly enter the European wood construction market, competing with traditional solid wood products used for outdoor decking and cladding. The performance of a heat ...
F Simon, M Kutnik, I Le Bayon, G Moisset, V Gatimel


Challenges and new developments in testing electro osmotic pulsing technology (PLEOT) by means of conventional laboratory methods
2011 - IRG/WP 11-40555
A new wood protection system, electro-osmotic pulsing technology, called PLEOT, is tested in lab trials using different test setup. The technology is tested on Scots pine sapwood and beech wood samples exposed to brown- and white rot fungi. Mass loss and moisture content is calculated after testing and a chitin analysis are performed on the sample powder. Two different electrodes are used in ord...
A Treu, E Larnøy


Performance of Zinc Borate-Treated Oriented Structural Straw Board against Mold Fungi, Decay Fungi and Termites–A Preliminary Trial
2011 - IRG/WP 11-40571
The performance of zinc borate (ZB)-treated oriented structural straw board (OSSB) against mold fungi, decay fungi and termites was examined in standard laboratory evaluations. OSSB was fabricated with split wheat straw and diphenylmethane diisocyante (pMDI) resin. The ZB was added during panel manufacture to achieve preservative levels (wt.%) of 1.0%, 1.5%, 2.0%, and 3.0%. Untreated (0.0% ZB) OSS...
Guangping Han, M Manning, Wanli Cheng, E Pierre, W Wasylciw


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Laboratory evaluation of the natural durability and treatability of Cryptomeria japonica grown in La Reunion Island
2012 - IRG/WP 12-10772
The Japanese cedar Cryptomeria japonica is the main resource for timber construction in La Reunion Island, an overseas territory belonging to France. The natural durability of C. japonica originating from East-Asia has been considered so far as quite poor and the European standard EN 350-2 classifies this species ‘not durable’ with regard to its resistance to termites, xylophageous beetles and...
M Kutnik, J Vuillemin, I Paulmier, I Le Bayon, S Legay, E Raphalen, M Jequel, N Farnier, T Glandut


Connecting fungal genomic variations to wood chemical composition: A way to understand the adaptation of wood decaying fungi
2012 - IRG/WP 12-10776
The development of new sequencing methods allows now exploring the detoxication systems of wood-decaying fungi. These systems, called xenome, are mainly composed of oxidative enzymes (phase I) and of conjugation enzymes (phase II). These enzymes belong to superfamilies, which are extended in the plant cell-wall interacting fungi. From different approaches coupling in particular comparative genomic...
E Gelhaye, Y Mathieu, E Meux, A Thuillier, M Mélanie


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


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