Your search resulted in 564 documents. Displaying 25 entries per page.
Leaching properties of copper and triazole
2009 - IRG/WP 09-30509
The leaching rate of copper and triazole (such as tebuconazole and propiconazole) in different preservative formulations was determined according to AWPA E11-06. Of all copper triazole and ACQ formulations, copper fixation rate of ammonia based was higher than that of ethanolamine based and the mixture of them. Copper fixation rate at relatively higher retention was slight higher than that at lowe...
Zhiqiang Li, Xiaowen Li, Ying Zhang, Mingliang Jiang
The Form of Copper: Does It Really Matter?
2009 - IRG/WP 09-30513
In recent years, several micronized copper formulations for lumber treatment have supplanted the solubilized copper formulations that in turn replaced CCA after its voluntary relabeling in 2004. The micronized or dispersed copper systems use finely ground but solid copper particles and deposit those particles within the wood framework. In contrast, copper in the soluble formulations is relativel...
C R McIntyre, M H Freeman, T F Shupe, Q Wu, D P Kamdem
Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao
Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro
Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect.
Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans
Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung
Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe
Physical and Mechanical Properties of Bamboo Oriented Strand Board Treated with Copper-based Preservatives
2009 - IRG/WP 09-40482
Oriented strand board (OSB) has been gradually accepted, used and developed in China. Bamboo is a renewable and potential non-wood fibre resource for making OSB. But the nature of bamboo makes its products including bamboo OSB (BOSB) more prone to decay and mold. Protection BOSB from biodegradation is the key both to efficiently using bamboo resource and to improving the durability of the final pr...
Juwan Jin, Daochun Qin
Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal
Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan
Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper
A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick
Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su
Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris
Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper
Comparison of Micronized Copper Particle Sizes
2010 - IRG/WP 10-30538
The particle sizes of micronized copper formulations derived from treating liquids were compared with those deposited in wood treated with those liquids. The intent was to determine if agglomeration occurs in the liquids during the treatment process, if screening of the agglomerates occurs in the wood and if there are any apparent differences in the particle sizes in the wood. Three formulations...
C R McIntyre
A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure.
In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer
Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre
Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen
Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans
Studies on Effect of pH on Copper Availability in Copper-Based Preservatives
2010 - IRG/WP 10-30549
Laboratory methods have been employed to investigate the pH effect on the copper solubility of basic copper carbonate. The pH was controlled using two different approaches. One was with the adjustment of pH of the solutions by acid or base using sulfuric acid or sodium hydroxide until the solution equilibriums were obtained for each defined pH. A second approach was to control pH with buffer sol...
L Jin, P Walcheski, A F Preston
Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora
A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick
Copper distribution in soil leached from full scale decking boards during one year
2010 - IRG/WP 10-50265
The distribution of copper in the soil under exposed decking boards after one year has been analysed. The decking boards were impregnated with copper HDO, copper quat and copper triazoles. The decking boards were pine sapwood and pressure treated in a full cell process, fixed by heating and then dried. The samples were not surface treated. Each decking sample of five boards (0.25 m2) was placed on...
F G Evans
Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe