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Proposal for further work on fixation of CCA-preservatives in wood
1988 - IRG/WP 3493
Many studies on the fixation and fixation-mechanism of CCA-preservatives in lignocellulose materials have been published but few on the practical consequences of this knowledge. For the wood preserving industry and the user of treated wood it is important to know what is meant by the word fixation, when fixation is complete and how fixation can be recorded in an easy way according to a non-destruc...
M-L Edlund


Fungus cellar testing as an evaluation method for performance of treated timber in ground contact
2001 - IRG/WP 01-20227
A fungus cellar method for the accelerated evaluation of performance of treated wood in ground contact is described. The test soil comprised of sandy loam, vermiculite and Japanese horticulture soil "Kanumatsuchi" in a ratio of 6:2:2 by volume. The soil was inoculated with the dominant test fungus isolated with selective medium from decayed wood samples. Pairs of treated and untreated wood specime...
Y Nagano


Diffusion of a copper naphthenate/boron paste through Douglas fir heartwood
1991 - IRG/WP 3671
Groundline wraps are an important portion of the remedial treatment strategies for protecting utility poles in North America from surface decay. The compositions of these wraps have recently shifted away from pentachlorophenol and creosote to formulations containing copper naphthenate and boron. These formulations have not yet been extensively tested, although the chemicals have been used for many...
P G Forsyth, J J Morrell


Wood Preservatives Science Issues: US EPA’s Perspective
2005 - IRG/WP 05-50224-2
The USEPA Office of Pesticide Programs (OPP), Antimicrobials Division (AD), regulates the use of chemicals registered as wood preservatives in the United States. An overview of the registration and re-registration process is presented. The wood preservatives data requirements include toxicological, human exposure, ecological, and environmental fate data. A detailed discussion of wood preservati...
N Elkassabany


Serviceability of copper naphthenate-treated poles
2000 - IRG/WP 00-30214
Copper naphthenate-treated poles in service were inspected for deterioration, penetration, retention, and serviceability. The study to date has included poles in all hazard zones in the United States. Poles installed by 12 different utilities and eight different treating companies are included in the survey. Both southern pine and Douglas-fir poles and distribution and transmission poles are inclu...
H M Barnes, M H Freeman, J A Brient, C N Kerr Jr


Assessment of the toxicity of some copper-, zinc- and boron-based wood preservatives to the cellar fungus Coniophora cerebella Schröet
1974 - IRG/WP 242
This article reports the use of a method based on the determination of the probability of the protection of timber against destruction by fungi. By converting the probability values to probit values and plotting them as a function of the amount of preservative retained in the timber, curves of the toxic effect are obtained, enabling any timber protection probability to be assessed....
V N Sozonova, D A Belenkov


Effectiveness of copper/chromium salts as wood preservatives against Limnoria tripunctata Menzies in laboratory tests
1977 - IRG/WP 431
During the last joint meeting of IRG and COIPM a co-operative programme of tests with copper/chromium salts as wood preservatives against marine borers was discussed and agreed. In this connection the results of a laboratory test in the BAM with Limnoria tripunctata Menzies will be of interest. But as the respective paper is written in German (H. Kühne; G. Becker: Laboratoriumsversuche über die ...
H Kühne


Safe application of copper-chrome-arsenate preservatives
1975 - IRG/WP 377
All wood preservatives contain biologically active substances and must, by design, be in some measure toxic to man. There is nothing fundamentally difficult, however, about using a wood preservative with complete safety. It depends on knowing the risks to health and/or the environment, which the preservative may present, and planning application accordingly. In this paper we examine these and othe...
I N Stalker, P B Cornwell


Experiences with penetration of copper-based wood preservatives
2001 - IRG/WP 01-20233
In the Nordic countries there is a long tradition of result type based specifications for preservative-treated wood. A common Nordic standard for treated pine (Pinus sylvestris) wood was published in 1976. After a revision in 1989 this standard, then named INSTA 140, defined four classes of treated wood: M, A, AB and B. Treaters producing according to this standard had to be affiliated to a qualit...
J Jermer, F G Evans, I Johansson


Susceptibility of CCB treated wood to fungal colonization
2003 - IRG/WP 03-10492
CCB treated wood is generally resistant to all wood decay fungi. However, like CCA impregnated wood, susceptibility of CCB treated wood to copper tolerant fungi have been observed. The ability of various brown rot fungal hyphae to penetrate and overgrow the wood samples was investigated. Samples made of Norway spruce (Picea abies) were impregnated with 5 % CCB solution according to the EN 113 proc...
F Pohleven, U Andoljsek, P Karabegovic, C Tavzes, S A Amartey, M Humar


Report on the burning of wood treated with wood preservatives containing copper, chromium and arsenic
1976 - IRG/WP 379
Mixtures of copper, chromium and arsenic salts are used extensively in the UK to preserve timber. This report is concerned with the fate of these metals when timber treated with these salts is burned. A large percentage of the arsenic present in the timber is shown to be volatilised during combustion and the potential environmental implications of this are assessed by comparison with the release o...
A J Dobbs, C Grant


Fixation and leaching of selected Malaysian tropical hardwood after treated with CCA
2001 - IRG/WP 01-40207
The objective of this study is to investigate the fixation and leaching properties of selected Malaysian tropical hardwood (sentang wood (sapwood and heartwood) and rubberwood) after being treated with copper chrome arsenate (CCA) type-C preservative. The samples were treated with retention level of 0.5%, 2.0% and 5.0%. The samples were leached and the leachate were analyzed by AAS and the amount ...
R Hashim, O Sulaiman, Tan Siew Ching, K Yamamoto


Some data on the activity of alternative fungicides for wood preservation
1985 - IRG/WP 3333
Data from laboratory tests against basidiomycete fungi are presented for 9 alternative fungicides in organic solvent formulations and also in water for one product. Results are compared with data for reference preservatives, tributyltin oxide, copper and zinc naphthenates and pentachlorophenol. Of special interest is the apparently better than additive effect of mixing tributyltin naphthenate and ...
A F Bravery, J K Carey


Comparative performance of several ammoniacal copper preservative systems
1997 - IRG/WP 97-30151
The efficacy of several ammoniacal copper-based wood preservative systems was evaluated in this study. The selection of potential co-biocides was based on the results of an agar plate test. Following this, the most promising systems were evaluated in a standard field stake test. Good correlation was found between the agar plate and field stake test results. Of the preservative systems tested, copp...
D D Nicholas, T Schultz


Evaluation of the corrosivity of the treated wood - Laboratory vs field test methodologies
2000 - IRG/WP 00-20211
The corrosivity of treated wood to fasteners has been evaluated using laboratory test procedures, including AWPA Standard E12-94. The standard method was modified in order to allow detailed study of commercial metal fasteners in terms of sample types, installation configuration and exposure conditions. Parallel field tests were also performed. The experimental results generated from these tests su...
L Jin, A F Preston


Copper leaching from Kemwood ACQ and Embalit CBC treated wood products
2000 - IRG/WP 00-50150
TNO has performed a study on the leaching of copper from Kemwood ACQ and Embalit CBC treated wood products, further referred to as ACQ and CBC. The sawn dry wood has been impregnated using an industrial vacuum-pressure process with ACQ (with or without Ultrawood 4) or with CBC, under supervision of Flexchemie B.V. After treatment samples have been transported and subjected to leaching tests at TNO...
P Esser, W L D Suitela, H Trompetter


Effectiveness of CCA fixation to avoid hexavalent chromium leaching
2002 - IRG/WP 02-50187
It is generally assumed that hexavalent chromium in chromated copper arsenate wood preservative is substantially reduced to trivalent chromium during fixation and that the potential to leach the more toxic CrVI is minimal. However, there are occasional claims some hexavalent chromium remains in wood after fixation and that small amounts of CrVI are available for leaching. One problem is that ot...
P A Cooper, D Jeremic, Y T Ung


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Evaluating the natural durability of native and tropical wood species against Reticulitermes flavip
2004 - IRG/WP 04-10539
Environmental pressures to eliminate arsenate from wood preservatives has resulted in voluntary removal of CCA for residential applications in the United States. A new generation of copper organic preservatives has been formulated to replace CCA for decking and in-ground applications but there is no guarantee that these preservatives represent a permanent solution to all related problems. There...
R A Arango, F Green III, K Hintz, R B Miller


A suggestion for the improvement of the chemical protection of wooden poles
1987 - IRG/WP 3445
Insufficient drying of white poles in Sweden causes inadequate penetration of the impregnation compounds, CCA salts and creosote, in a varying proportion of the treated poles, and with pretreatment decay present, sooner or later, internal fungal attack in the ground-line zone of the standing poles is the result. The application of a diffusing fungicide in the ground-line zone in connection with th...
H Friis-Hansen


The multi-phase pressure (MPP) process. One stage CCA treatment and accelerated fixation process - Concepts proved by repetitive pilot plant treatments
1997 - IRG/WP 97-40079
Twenty-four charges of radiate pine roundwood or sawn timber were treated using the MPP Process and hot CCA solution. Treated timber met the CCA retention and penetration requirements of the NZ Timber Preservation Council for Hazard Classes H3 to H5. The objectives of the trials were: (1) To "stress" CCA solution by repetitive heating, treating and cooling to determine its stability in the process...
A J Pendlebury, J A Drysdale, K Nasheri, H Pearson, M E Hedley


The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara


Effects of surfactants and ultrasonic energy on the treatment of wood with chromated copper arsenate
1977 - IRG/WP 3108
Sugar pine stakes 1'' x 1" x 16" were treated by a hot-water bath followed by soaking in cold CCA solution for 10 to 30 minutes. A similar number of stakes were treated by a cold-cold bath. Half of the stakes were subjected to ultrasonic energy during the CCA bath. The mean absorption for stakes given the hot-cold bath was 18.52 pcf (297 kg/m³) and 4.64 pcf (74 kg/m³) for those...
C S Walters


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers
1991 - IRG/WP 2381
Standardized heartwood blocks of kempas (Koompassia malaccensis), keruing (Dipterocarpus sp.) and tualang (Koompassia excelsa) were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicola grisea, Petriella setifera and Trichurus spiralis in a containerized vermiculite-burial decay system according to draft CEN/TC 38 WG 4....
A H H Wong, R-D Peek


Investigation of temperature effect on fixation of Celcure preservative (ACC) in beech (Fagus orientalis)
2001 - IRG/WP 01-40200
In this research, the fixation speed of Celcure 2% (ACC) preservative salt, under temperature of 17°C, 27°C and 50°C, on intact and stained wood specimens of beech was investigated. For this purpose, blocks of wood with 5x5x7 cm dimensions were prepared and saturated with 2% ACC concentration by full-cell process. The specimens were put in three incubators at the above-mentioned temperatures. F...
A Karimi, M Ghorbani


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