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Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton
Performance of copper treated poles and posts after three to fifteen years of exposure
2016 - IRG/WP 16-20595
Copper based wood preservatives are one of the most important wood preservatives for heavy-duty applications. Wood treated with copper-based preservatives performs excellent if applied according to preservative specifications. If used improperly premature failures might appear. In order to elucidate properties of copper treated wood in use, utility poles and posts treated with copper-based preserv...
M Humar, N Thaler
Moisture monitoring in WW2 partisan hospital Franja
2016 - IRG/WP 16-20596
Material climate of wood used for construction of WW2 Partisan hospital Franja was monitored for approximately one year. Partisan hospital is located in the bottom of tiny gorge Pasice in Slovenia. Hence, wood moisture content on eight respective location and wood temperature was determined twice per day with Scanntronik equipment Gigamodul and Thermofox. The results clearly showed that despite of...
M Humar, N Thaler, B Lesar, A Žagar
Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick
Superhydrophobic treatment of Norway spruce wood for improvement of its resistance against brown rot and moulds
2016 - IRG/WP 16-40734
Water repellence of wood can be increased and its some other properties influenced by introduction of hydrophobic chemicals into and on cell walls without affecting the wood’s bulk density due to lumen filling. Herein, a simple dipping method to insert octadecyltrichlorosilane (OTS) into cell walls and to deposit the self-assembled hydrophobic monolayers (SAMs) of OTS is reported. It was found o...
A Kumar, P Ryparová, P Hajek, B Kričej, M Pavlič, A S Škapin, M Šernek, J Tywoniak, J Žigon, M Petrič
Role of cell wall specific moisture content on the brown-rot fungal attack on wood
2016 - IRG/WP 16-40736
Wood is a hydroscopic resource because the cell wall polymers contain hydroxyl and other oxygen-containing groups that attract moisture through hydrogen bonding. Moisture content varies with changing moisture content in its environment. The moisture content in wood is responsible for many of the performance properties we observe. The strength properties of wood are dependent on the moisture con...
R M Rowell
Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs
Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen
Case study: “Riesenbühlturm”
2017 - IRG/WP 17-20599
In this case study four 7 m long Douglas fir crossbeams were investigated regarding the remaining metal and moisture content. The crossbeams were replaced from a timber tower after 10 years of service in the Black Forest region (South Germany) due to fungal decay. From each of the crossbeams five stem discs were taken and relevant parameters (density, moisture and remaining metal content) were de...
E Melcher, J Müller
The sorption behaviour of wood
2017 - IRG/WP 17-20605
The use of dynamic vapour sorption to determine the sorption properties of wood has become an increasingly popular technique. The method has many advantages when compared with many other gravimetric methods. However, it is necessary to set an equilibrium condition in order to obtain data for an isotherm in a reasonable amount of time. An important recent finding has been that multiple sorption cyc...
C Hill
Modelling of moisture content in timber bridge details
2017 - IRG/WP 17-20613
The design of details is an important aspect in durability design of timber bridges. Details are often considered the weakest points in bridges due to their tendency to trap and accumulate moisture and thus facilitate decay. When designing maintenance plans and inspection intervals, it is important to know how design choices will come to influence the service life. Moreover, service life and wood ...
J Niklewski, C Brischke, E Frühwald Hansson, L Meyer-Veltrup
Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin
COST FP 1303 Cooperative Performance Test – Results after two years outdoor exposure
2017 - IRG/WP 17-20620
COST Action FP 1303 ‘Performance of Bio-Based Building Materials’ started in October 2013 and an ambitious program was set up for four years. Among this a collaborative field test was planned. The idea of the cooperative performance test was to distribute a fairly simple test set up to as many places in Europe as possible in order to collect performance data reflecting the full range of climat...
B Lesar, M Humar, C Brischke, L Meyer-Veltrup, D Jones, N Thaler, J M Abascal, G Alfredsen, B Brunnhuber, E Grodås, M Irle, J Kers, M Klamer, K-C Mahnert, E Melcher, S Palanti, M Noël, E Suttie, N Pfabigan, M Touza
Moisture performance of wood determined in laboratory and field trials
2017 - IRG/WP 17-20621
It is widely accepted that wood moisture content (MC) is the key factor when it comes to durability of wooden structures exposed to weathering. The moisture performance of wood and wood-based products has been recognized as key element in wood durability and wood protection. Actually, it should be considered as major component of the material-intrinsic resistance of wood, but never found its way i...
D Kržišnik, N Thaler, B Lesar, M Humar
Moisture content as a quality control parameter in thermally modified timber production
2017 - IRG/WP 17-20622
Quality assurance (QA) or factory production control (FPC) is necessary to ensure a proper production process. The requirements of QA/FPC can result from EN and national standards, quality assurance systems, or producer-specific rules.
TMT producers must ensure that the process was correct, and to ensure traceability of products. In addition to the electronic records, the material should be che...
W Scheiding, H Turkulin, S Stein
Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl
Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris
Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang
Treatability of beechwood railway sleepers with potential creosote substitutes
2017 - IRG/WP 17-40790
Maintenance of an efficient railway infrastructure still requires the use of wooden railway sleepers, particularly because wooden sleepers have more favourable properties for intensified vibrations than concrete or steel sleepers. Creosote, used for decades for the impregnation of railway sleepers, will possibly no longer be available for this application due to European legislation. This reveals ...
N Pfabigan, E Habla, R Gründlinger
Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd
Dual Borate and Copper Naphthenate Treatment of Bridge Timbers:- Potential Performance Enhancements and Cost Savings
2017 - IRG/WP 17-40797
Dual treatment technology combining diffusible preservatives with oil borne preservatives, widely used for crossties in the USA, has now also been commercialized with bridge ties/timbers. In order to understand the implications of these changes, the historic service life of creosote treated bridge timbers in northern and southeastern USA were considered as well as field test data for both creosote...
J Lloyd, C Brischke, R Bennett, A Taylor
A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel
Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele
Uncertainty in life cycle assessment of preservative treated wood – copper and freshwater ecotoxicity
2017 - IRG/WP 17-50331
Life cycle assessment (LCA) is a method for quantifying the environmental impacts of a product over the life cycle. In the last years, there have been a growing application of LCA in developments of environmental product declaration (EPD), which is utilised by professional procurement of materials for buildings. For legislative issues, LCA have also been used to assess application of creosote to t...
L G F Tellnes
Influence of sea water on timber and metal joints
2017 - IRG/WP 17-40818
In the Great East Japan Earthquake that occurred in March 2011, many buildings suffered from seawater immersion caused by the tsunami. Saito's study revealed that corrosion progresses on metal plate that experienced seawater immersion 1). However, the detailed mechanism of corrosion progresses has not yet been clarified. Therefore, in this study, salinity which is one of causes of corrosion w...
T Nishimura, H Ishiyama, F Hirose, N Wada