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Copper leaching from Kemwood ACQ and Embalit CBC treated wood products
2000 - IRG/WP 00-50150
TNO has performed a study on the leaching of copper from Kemwood ACQ and Embalit CBC treated wood products, further referred to as ACQ and CBC. The sawn dry wood has been impregnated using an industrial vacuum-pressure process with ACQ (with or without Ultrawood 4) or with CBC, under supervision of Flexchemie B.V. After treatment samples have been transported and subjected to leaching tests at TNO...
P Esser, W L D Suitela, H Trompetter


Effectiveness of CCA fixation to avoid hexavalent chromium leaching
2002 - IRG/WP 02-50187
It is generally assumed that hexavalent chromium in chromated copper arsenate wood preservative is substantially reduced to trivalent chromium during fixation and that the potential to leach the more toxic CrVI is minimal. However, there are occasional claims some hexavalent chromium remains in wood after fixation and that small amounts of CrVI are available for leaching. One problem is that ot...
P A Cooper, D Jeremic, Y T Ung


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Evaluating the natural durability of native and tropical wood species against Reticulitermes flavip
2004 - IRG/WP 04-10539
Environmental pressures to eliminate arsenate from wood preservatives has resulted in voluntary removal of CCA for residential applications in the United States. A new generation of copper organic preservatives has been formulated to replace CCA for decking and in-ground applications but there is no guarantee that these preservatives represent a permanent solution to all related problems. There...
R A Arango, F Green III, K Hintz, R B Miller


The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers
1991 - IRG/WP 2381
Standardized heartwood blocks of kempas (Koompassia malaccensis), keruing (Dipterocarpus sp.) and tualang (Koompassia excelsa) were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicola grisea, Petriella setifera and Trichurus spiralis in a containerized vermiculite-burial decay system according to draft CEN/TC 38 WG 4....
A H H Wong, R-D Peek


Investigation of temperature effect on fixation of Celcure preservative (ACC) in beech (Fagus orientalis)
2001 - IRG/WP 01-40200
In this research, the fixation speed of Celcure 2% (ACC) preservative salt, under temperature of 17°C, 27°C and 50°C, on intact and stained wood specimens of beech was investigated. For this purpose, blocks of wood with 5x5x7 cm dimensions were prepared and saturated with 2% ACC concentration by full-cell process. The specimens were put in three incubators at the above-mentioned temperatures. F...
A Karimi, M Ghorbani


The implementation of restrictions on the use of arsenic and chromium based wood preservatives in Sweden
1995 - IRG/WP 95-50062
In 1992 the Swedish National Chemicals Inspectorate introduced restrictions on the use of wood treated with arsenic and/or chromium based wood preservatives. Such wood is now in principle only allowed for use in ground contact or in water. These restrictions have had considerable influence on the use of wood preservatives for sawn timber for the Swedish domestic market. Thus only 35% of the preser...
J Jermer, M-L Edlund, K Nilsson


Fungicidal activity of some new water borne copper octanoate based formulations
1999 - IRG/WP 99-30198
Four new water borne formulations for preservation of wood were prepared: the composition of Cu(II) octanoate, 2-aminoethanol (ethanolamine) and water; the composition of complex of Cu(II) octanoate with nicotinamide, 2-aminoethanol and water; the one of Cu(II) octanoate, organic boron complex, 2-aminoethanol, dimethyl sulfoxide and water and finally, the mixture of Cu(II) octanoate, diazene, 2-am...
M Petric, M Pavlic, F Pohleven, P Segedin, B Kozlevcar, S Polanc, B Stefane, R Lenarsic


Laboratory evaluation of metallic naphthenates as wood preservatives
1991 - IRG/WP 3654
Fungicidal and termiticidal efficacy of copper and zinc naphthenates was appraised according to Japanese standardized laboratory testing methods. Copper and zinc naphthenates succeeded in protecting wood from decay fungi at retentions of 0.5 and 1.0 kg/m³ as metal, respectively. [JIS A 9302 (1976)] when they were applied to vacuum/soak impregnation [JIS A 9301 (1976)]. With respect to the fungici...
K Tsunoda, M Sakurai


The influence of copper (II) chemicals on the weathering of treated wood. Part 1: ACQ treatment of wood on its weathering
1994 - IRG/WP 94-30040
Wood weathering can be accelerated by alkylammonium compound (AAC) treatment, and slowed by ammoniacal copper quat (ACQ) treatment. This study aims at investigating the influence of ACQ treatment of wood, especially the present of copper (II), on its weathering. ACQ, CCA and DDAC treated microtomed sections of southern yellow pine earlywood were prepared and naturally weathered for five periods, t...
Ruiying Liu, J N R Ruddick, L Jin


An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper/chrome/arsenic preservative
1981 - IRG/WP 3180
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. The growth characteristics of spruces (Picea spp) make them attractive candidates for forestry schemes. In 1975 the UK Forestry Commission had about 400 000 hectares, about 20% of total UK forest area, planted with Sitka spruce (Picea sitchensis)...
C R Coggins


Determination of absorption, accumulation and transport of copper in mycelium of some wood decay fungi
1999 - IRG/WP 99-10323
Copper compounds are common wood preservatives. However, tolerance of some wood decay fungi to copper compounds has been observed recently. Therefore, we tried to elucidate possible causes of this phenomenon. We investigated uptake, accumulation and secretion of copper in the mycelium of potentially copper tolerant fungi (Antrodia sp.) and non tolerant fungus Trametes versicolor. We observed that ...
F Pohleven, S Breznikar, P Kalan, M Petric


Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


Serpula lacrymans, The Dry Rot Fungus and its Tolerance towards Copper-based Wood Preservatives
2005 - IRG/WP 05-10555
Serpula lacrymans (Wulfen : Fries) Schröter, the dry rot fungus, is considered the most economically important wood decay fungus in temperate regions of the world i.e. northern Europe, Japan and Australia. Previously copper based wood preservatives were the most commonly used preservatives for pressure treatment of wood for building constructions. Because of a suspicion about tolerance toward cop...
A C Steenkjær Hastrup, F Green III, C A Clausen, B Jensen


Selective chromate elimination from the storage-drainage-water of a wood impregnation plant
1980 - IRG/WP 3153
With the Enviro-Chrom-Ex process it is possible to eliminate ecologically and economically hexavalent chromium (chromate) from water selectively. The process which is based on the principle of selective ion exchange works with different chromate concentrations and under the presence of other ions, irrespective of the water hardness. The values of water-offtake reach 0.1 mg CrVI at maximum, causing...
O Wälchli, R Ott, R Hugener, E Graf, B Lieberherr


Ability of chitosans to limit wood decay under laboratory conditions.
2004 - IRG/WP 04-30339
Chitosans have recently been explored for controlling a number of plant pathogenic fungi and have shown some promise for controlling stain fungi on wood. The potential for using chitosans either alone or in combination with copper sulfate to protect wood from fungal decay was explored using maple veneers. Chitosan treatment reduce weight losses caused by two brown rot and one white rot fungi, howe...
M Maoz, J J Morrell


Observations on the performance of copper-based wood preservatives in fungal cellar (soil-bed) tests
1994 - IRG/WP 94-20047
Fungal cellar (soil-bed) tests are considered to be an important tool for the evaluation of the performance of ground contact wood preservatives. Facilities of this type have been established world wide although caution has been exercised in their introduction into standard testing methods for the approval of wood preservatives. This is the result of concerns over the variability in the biological...
G R Williams, D Rudolph, M E Hedley, J A Drysdale, R F Fox


Description of a trial with wood preservatives against marine wood boring organisms
1975 - IRG/WP 412
Wood situated in sea water along the Atlantic coasts of the Nordic countries is attacked by marine wood boring organisms. Timber constructions in these waters therefore must be preservative treated. In order to evaluate the effect of various preservatives against marine wood borers, the Nordic Wood Preservation Council (NWPC) organized a rather extensive trial in 1972. In the absence of and while ...
E Norman, B Henningsson


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


A marine borer test with water-borne preservatives
1980 - IRG/WP 452
The use of preservative treated timber in sea-water where marine borers are active is of great economic importance, since untreated wood immediately will be damaged. Vacuum/pressure treated timber has been tested in several marine exposure trials on the Swedish west coast since the 1930s (Hager 1941, Hultman 1949, Sandstrom 1951, Nylinder-Norman et al. 1974). Since new interesting materials or pre...
B Henningsson, E Norman


Preservation of robinia wood (Robinia pseudoacacia L.) stakes by vintners
1982 - IRG/WP 3194
This work discusses decay resistance of robinia wood to fungi Trametes versicolor (L.ex Fr.) Pil. and Coniophora puteana (Schum. ex Fr.) Karst., and also the possibility of influencing its resistance by means of chemical protection. The results showed that natural resistance of robinia wood to these two different agents of wood decay is not the same. It is much less resistant to the fungus Conioph...
R Benko


Remedial ground-line treatment of CCA poles in service. Results of chemical and microbiological analyses 6 months after treatment
1986 - IRG/WP 3388
CCA-treated poles in service with incipient internal soft rot were remedially treated by inserting borate rods, brushing with a boron/glycol solution and injecting boric acid paste, copper/creosote paste or a commercial product (DFCK paste). The spread of active chemicals in the treated zone as well as the change in microflora have been studied with time. After six months chemicals had spread to m...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Determination of ethanolamine in impregnated wood
2000 - IRG/WP 00-20198
Leaching of copper based preservatives from wood is usually prevented by adding chromium compounds to copper containing formulations. It seems that suitable substitutes for chromium fixation agents may be amines. In this paper, we report our results on interactions between copper(II) octanoate and ethanolamine (C2H7NO, 2-aminoethanole) with wood or its components. A part of ethanolamine from a woo...
M Humar, M Petric


Recycling of treated timber by copper smelter
1994 - IRG/WP 94-50030
A preliminary trial was carried out to see whether copper smelting process is able to recycle CCA treated timber. As a result of the first trial almost a full recovery of both copper and arsenic was achieved. Recovered metals were utilized in manufacturing CCA preservatives. The energy bound in wood is utilized in the flash smelting process and the burning gases are fed to the sulphuric acid plant...
A J Nurmi, L Lindroos


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