IRG Documents Database and Compendium


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Quantitative determination of Chromium: A comparison of three instruments
1995 - IRG/WP 95-50053
A comparison is made between three instruments for measuring levels of chromium in the leachate of copper-chrome-arsenic (CCA) treated timber. These include an atomic absorption spectrophotometer, an inductively coupled plasma spectrometer and the RQflexâ. The RQflexâ is a new hand-held instrument which measures chromium by dipping a ReflectoquantÒ strip into the leachate and inserting the stri...
S Walley, P R S Cobham, P Vinden


The 1999-2000 annual report for the IRG - Wood Preservation in Egypt
2000 - IRG/WP 00-40188
The wood destroying insects in Egypt are belonging to several families of Coleoptera, Lepidoptera and Isoptera. Imported woods are treated by The Agricultural Quarantine or the authorized companies. The materials used for protection as pre-treatment are the same of the treatment. They are Bromide methyl, copper or fluoride salts, organo-phosphorus compounds, pyrethroides, creosote or creosodial. A...
S I M Moein


Report of meetings of remedial treatments Sub-group held in Madrid, Spain during 27-28 April 1988
1988 - IRG/WP 3502
J N R Ruddick


Proposed test procedure to determine the effect of timber substrate on the effectiveness of a copper/chrome/arsenic preservative in seawater
1975 - IRG/WP 411
R A Eaton


X-ray analysis of selected anatomical structures in copper/chrome/arsenic treated wood
1973 - IRG/WP 320
Application of analytical electron microscopy to problems in wood preservation has been very limited. Indeed, less than ten workers appear to have published their results using the technique, and of these' only two papers deal with energy dispersion procedures in the scanning electron microscope; the others employ the more familiar wavelength dispersive methods of the electron probe....
H Greaves


Improved PEC preservatives with added biocides
1985 - IRG/WP 3322
Biocidal chemicals have been incorporated into formulations within the broad framework of pigment emulsified creosote (PEC) to provide novel potential multi-purpose preservatives. Preparations of PEC plus TCMTB, Boracol 40, copper ethanolamine nonanoate, Quatramine 80, arsenic trioxide, Troysan Polyphase, and CCA have been formulated and assessed for preserving ability in soil-jar and Accelerated ...
H Greaves, C-W Chin, J B Watkins


Leaching of Active Components from Preservative Treated Timber. Stage 1: Semi-Field Testing
2004 - IRG/WP 04-20302
The project is aiming at finding realistic leaching rates from preservative-treated wood in use class 3 (above ground). The project focuses on developing a field trial method for investigating leaching. Panels are subjected to outdoor exposure under natural weather conditions at a test field at the Danish Technological Institute. The leachate is collected and monitored by chemical analysis of the...
N Morsing, B Lindegaard


Comparative performance of pentachlorophenol and copper naphthenate in a long term field stake test
2000 - IRG/WP 00-30243
In this study the performance of copper naphthenate (Cu-Nap) and pentachlorophenol (Penta) treated pine stakes against decay and termite attack were compared at two test sites in Mississippi. Four different petroleum oils meeting AWPA Standard P9-A were used as carriers for these wood preservatives. After ten years exposure, the efficacy of Cu-Nap at a retention level of 0.05 pcf Cu was equivalent...
D D Nicholas, M H Freeman


Evaluation of wood treated with copper-based preservatives for Cu loss during exposure to heat and copper-tolerant Bacillus licheniformis
1999 - IRG/WP 99-20155
Copper-based wood preservatives need to be effective against exposure to all types of microorganisms. Wood treated with six copper-based preservatives was exposed to 121°C and 20 psi pressure for 15 minutes under standard autoclave conditions and the copper-tolerant bacterium, Bacillus licheniformis CC01, for 10 d at 28°C and 150 rpm. Sixteen to 37 percent of the copper was released from the woo...
D M Crawford, C A Clausen


A wood preservative for the future: Copper dimethyldithiocarbamate
1994 - IRG/WP 94-30045
The development of a new wood preservative, copper dimethyl-dithiocarbamate (CDDC) is reviewed in this paper. CDDC is formed in situ by dual pressure treatments. Laboratory and field efficacy trials, physical and chemical properties of the preservative solutions and treated wood, and plant handling characteristics of the system are examined....
D K Stokes, M H Freeman, T L Woods, R D Arsenault


Soil-bed studies (Part 3): A cause of failure of multisalt preservatives following soil-bed exposure
1983 - IRG/WP 3261
P Vinden, J F Levy, D J Dickinson


Rapid leaching test
1991 - IRG/WP 2367
An accelerated test which is suitable for measuring the extent of metal fixation in both chromium and non chromium containing preservatives is described....
J A Cornfield, M Bacon, A Lyman, C Waldie, M R Gayles


Migration of active ingredients from treated timber into fresh water
1991 - IRG/WP 3669
Spruce roundwoods and segments were treated with three different wood preservatives. Two of them containing copper and chromium the other one free of chromium. After fixation (3 weeks, 20°C) the specimens were leached by using artifical rain or by shaking the segments for one hour in contact with demineralized water. The water was analysed for the relevant elements of the preservative tested. Lea...
H Klipp, H Willeitner, K Brandt, A Müller-Grimm


Wood preservation in the Australian beekeeping industry
1988 - IRG/WP 3473
This paper reports the results of a survey of Australian commercial beekeepers working 200 or more hives in June/July 1985. Nine hundred and forty seven apiarists were asked to participate and to provide information on their wood preservation methods, painting procedures and maintenance of bee boxes. Three hundred and eighty-four apiarists returned completed questionnaires (41%). The main wood pre...
P J Robinson, J R J French


Protecting wooden structures
1980 - IRG/WP 392
Chromium-containing chemicals that effectively retard weathering of wood improve performance of subsequently applied finishes. Current work is focusing on the performance of wood-derived products (plywood, hardboard, fiberboard, particle board) after surface treatment with inorganic chemicals. The overall objective of the continuing research is to investigate new environmentally safe procedures to...
W C Feist


CCA fixation experiments. Part 2
1989 - IRG/WP 3505
CCA fixation in wood was measured by both squeezing solution from treated wood that had not been dried and analyzing the solution for copper, chromium and arsenic, as well as using a chromotropic acid test to detect the presence of chromium VI. Both methods provide useful information on the CCA fixation process and illustrate that chromium VI disappears as CCA becomes fixed within wood....
W S McNamara


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


Use of the Pilodyn to assess deterioration of treated aspen waferboard after 30 months of outdoor exposure
1986 - IRG/WP 2254
Samples of preservative treated aspen waferboard exposed outdoors for 30 mo. were compared using pin penetrations of the 6 Joule Pilodyn. These results correlated well with rankings of treatment performance based on more laborious standard mechanical tests, and demonstrate the potential for use of the Pilodyn as a tool to evaluate wood composites in test exposures with minimal destruction....
E L Schmidt, M G Dietz


Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


Copper based water-borne preservatives: The biological performance of wood treated with various formulations
1987 - IRG/WP 3451
Wood samples treated with the various components of CCA preservative singly and in combination were tested against a soft rot organism, a copper tolerant brown rot organism and in soil burial both unleached and after leaching. The results suggest that, of the elements tested, fixed copper is essential for preventing soft rot attack and fixed arsenic is essential for preventing attack by a copper t...
S M Gray, D J Dickinson


A field test with anti-sapstain chemicals on sawn pine timber in Finland
1986 - IRG/WP 3368
Fourteen formulations, each in two concentrations, were tested for effectiveness against sapstain, mould and decay on Scots pine (Pinus sylvestris L.) in a field test in South-Finland. The trial was commenced in June 1985 and finished in October 1985. During the test the boards were infected mainly by mould fungi. In kiln dried boards the protective effects of nine and in green boards of four trea...
L Paajanen


Recycling of impregnated timber: Part 2: Combustion trial
1999 - IRG/WP 99-50132
Totally 270 m3 (61,3 t) of CCA impregnated wood was chipped and incinerated at the combustion plant of Jalasjärvi. After the normal gas cleaning venture scrubbers were tested. After the trial a metal balance was calculated. Ash was treated at the copper smelter of Outokumpu Harjavalta Metals Oy. Condensate waters were transfered to the Outokumpu's CCA production plant and utilized by the...
L Lindroos


Contribution of wood components on the absorption of copper amine
2000 - IRG/WP 00-30216
The contribution of wood components on the absorption of copper amine was investigated. Holocellulose, lignin and xylan absorbed significant amount of copper. The amount of copper absorbed by cellulose was almost negligible. The removal of extractive also decreased the amount of copper absorption. This study clearly indicates the importance of lignin, hemicellulose in the absorption of copper amin...
D P Kamdem, Jun Zhang


Investigation of the fixation in wood of chromated zinc chloride and copperised chromated zinc chloride preservatives
1976 - IRG/WP 372
A biological method of evaluating the extent to which CZC and CCZC preparations are retained in wood in terms of the potential protection which they afford against destruction by Merulius lacrymans (dry rot) is given. CCZC is recommended for protection of wood under moderate leaching conditions, while the use of CZC under such conditions is not recommended....
V N Sozonova, D A Belenkov


The use of chlorothalonil for protection against mold and sapstain fungi. Part 1: Laboratory evaluation
1989 - IRG/WP 3515
Laboratory screening of chlorothalonil alone and in combination with other fungicides was conducted against six mold and sapstain fungi. The most promising treatments appear to be chlorothalonil supplemented with CCA or copper-8-quinolinolate. Field tests have been implemented....
J A Micales, T L Highley, A L Richter


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