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The efficacy of boron preparations
1987 - IRG/WP 3400
The toxicity threshold of boric acid for egg larvae of Hylotrupes bajulus Linné is approx. 0.4 kg/m³ of wood (71 g B/m³) over a 12-week test period, and approx. 0.3 kg/m³ of wood (53 g B/m³) over a 6-month test period. The corresponding values for borax are 0.5-0.6 kg/m³ of wood (56-68 g B/m³) and 0.3-0.4 kg/m³ of wood (34-45 g B/m³). The values are somewhat lower in the case of the egg l...
J T De Jonge


Changes of copper and chromium content after leaching in wood impregnated with the CCB and CB preservatives
2000 - IRG/WP 00-50147
The objective of the study was impregnated with CCB and CB preservatives pine wood of moisture content varying from 12% to 55% subjected to leaching. Losses of copper and chromium were determined for individual layers of wood up to 3 cm from the girth. The results were compared to the total amount of metals determined in water extracts. The degree of leaching of metal ions from wood of 55% moistur...
B Mazela


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Redistribution of boric acid in radiata pine during drying after preservative treatment
1993 - IRG/WP 93-40010
Samples of 100 x 50 mm² radiata pine were processed with a variety of options to produce dry, boron-treated wood. Concentrations of boric acid in the central one-ninth and in the whole of the wood cross-sections were determined by chemical analysis and compared. Diffusion treated material was dried by air, conventional kiln (70/60°C), or high temperature kiln (120/70°C). Four different predryin...
A J Bergervoet, D R Page, J A Drysdale


Analysis of the boron content of preservative treated oak and pitch pine heartwood before and after leaching
1992 - IRG/WP 92-3697
Studies to determine the effects, if any, of a variety of boron formulations on heartwood of English oak and American Pitch pine have been previously reported (King et al (1991)). Small wood blocks were treated, at 10°C or 45°C, with borax, polybor or Boracol 20 for periods of 1 month or 4 months then analysed or continuously leached with tap water for a period of 1 month. Reported results showe...
S McCutcheon, G M Smith, J W Palfreyman, B King


A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Fixation of chromated wood preservatives through technical drying
1990 - IRG/WP 3623
Twin samples of sawn timber of Pinus sylvestris and Picea sp. were treated with copper-chromate-containing wood preservatives and subsequently kiln resp. air dried. After drying, the distribution of preservative and rate of fixation were determined. Drying of freshly treated wood in a condenser type kiln at temperatures of 60°C and 80°C and in a vacuum type kiln at 55°C with a pressure of about...
R-D Peek, H Klipp


The control and pretreatment decay in air seasoning Scots and Corsican pine poles in England
1990 - IRG/WP 1451
Previous work clearly showed that air-seasoned, British grown Scots and Corsican pine poles are subject to serious pretreatment decay. In order to control these infections a range of pretreatments are currently being investigated. One series of treatments is designed not only to control decay but also allow the development of mould and stain fungi in order to achieve the desired increases in poros...
D J Dickinson, A R Zahora, A P Dodson


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Upgrading the fungal resistance of OSB
1999 - IRG/WP 99-40138
There is a perception that oriented strand board (OSB) is less resistant to fungl than plywood under conditions of moderate exposure to moisture. Douglas fir-faced plywood (DFP) has been suggested as a benchmark for acceptable durability under such conditions. This project was initiated to determine the minimum level of low-toxicity chemical treatment needed to upgrade the fungal resistance of OSB...
P I Morris, J E Clark, D Minchin, R Wellwood


Influence of fungal exposure on the redistribution of copper in treated spruce wood
2002 - IRG/WP 02-10450
The redistribution of copper in treated wood after exposure to basidiomycete decay fungi is described. The micro-distribution of copper in copper(II) sulphate or copper(II) octanoate/ethanolamine treated Norway spruce wood before and after exposure to 3 different wood decay fungi was studied using transmission electron microscopy with X-ray microanalysis. The copper content of the mycelium and the...
M Humar, F Pohleven, R J Murphy, D J Dickinson, I Moris, M Zupancic, P Kalan, M Petric


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


The effect of stack height on the performance of preservatives used for the prevention of sapstain on seasoning wood
1997 - IRG/WP 97-10192
The performance of three anti-sapstain preservatives was investigated under field conditions in south east England. The preservatives under test were: copper-8-quinolinolate (Mitrol PQ8) trimethylalkylammoniumchloride and sodium hexanoate (Sinesto B) and chlorothalonil (Tuff Brite). The preservatives were tested on Corsican Pine grown in south east England. The field trial was set up to investigat...
J R Williams, D J Dickinson, J F Webber


Interactions between soft rot fungi and CCA preservatives in Betula verrucosa
1988 - IRG/WP 1367
Ultrastructural investigations were carried out to obtain information on the cell wall distribution of CCA elements during soft rot decay of 4% K33 CCA preservative treated birch (Betula verrucosa) wood. TEM observations on fibres at various stages of S2 cavity formation by mutabilis showed a distinct pattern of electron dense materials to occur within the S2 cell wall region. These materials (gra...
G F Daniel, T Nilsson


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


Effects of boron formulation on specific timber types used in ships of historical importance
1991 - IRG/WP 3676
This paper reports results of preservative treatment and leaching experiments, using borax, polybor and boracol 20, on small wood blocks of English oak and American pitch pine heartwood. Earlier experiments on the performance of various biocides as possible additives to bilgewater to prevent fungal decay of shipping timbers had suggested that some formulations of boron might be associated with phy...
B King, G M Smith, J W Palfreyman, S McCutcheon


Bioefficacy of Cunapsol® treated western cedar and southern yellow pine
1996 - IRG/WP 96-30120
Western red cedar and southern yellow pine sapwood were dip treated with a new formulation of waterborne copper naphthenate (Cunapsol®) which complies with VOC regulations. Cunapsol dip treated samples were oven dried at 50°C for 48 hours and then water leached for two weeks. Decay resistance and leachability of preservatives from dip treated specimens were evaluated according to AWPA (American ...
D P Kamdem, M H Freeman, T L Woods


The influence of UV and IR radiation on leaching of copper and chromium from preservative-treated pine and spruce
1992 - IRG/WP 92-3687
The influence of artifical UV- and IR-radiation on the leaching of copper and chromium components of a CCB-preservative from freshly treated pine and spruce was evaluated. On small pinewood samples it could be shown, that the leaching of copper and chromium can considerabely be reduced by UV-radiation. A Philips HPA lamp type reduced the leaching most effective. IR-radiation lead to higher leachin...
H Militz


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Diazenes and some organic complexes of boron as potential fungicides for preservation of wood
1999 - IRG/WP 99-30197
Screening for fungicidal activity represents the first step in searching for new active components with enhanced environmental profile in comparison with traditional wood preservatives. Diazenes, their salts, and the salts of the corresponding semicarbazides, as well as several complexes of boron, were screened for fungicidal activity against wood decay fungi Trametes versicolor, Coniophora putean...
M Petric, B Paradiz, J Stern, F Pohleven, S Polanc, B Stefane, R Lenarsic


Boracol 40 - A potential remedial and preservative treatment for lyctids
1983 - IRG/WP 1192
The paper reports on a preliminary assessment of the efficacy of a diffusion formulation, Boracol 40, when applied as a brush treatment: to the surface of Eucalyptus obliqua against the powder-post borer Lyctus brunneus. After a five month bioassay, Boracol 40 has severely retarded the progress of active infestations of Lyctus brunneus and has been 100 per cent effective as a preventative treatmen...
J W Creffield, H Greaves, C D Howick


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


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