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A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


Studies on the fungicidal effectiveness of a petroleum derived product as a creosote alternative
1986 - IRG/WP 3384 E
This work, appears first because of the necessity to find out a profitable use for a residual product of the petrol pyrolisis, and second, because the lack of high natural durability wood used until now-a-days to build posts and sleepers in creosote lacking countries. Our main objective was pointed to the characterization of this new product and to find out the effectiveness against the wood-destr...
A M Navarrete, M T De Troya


Protection of cellulose string with biocide/water repellent mixtures
1997 - IRG/WP 97-30148
Protecting cellulosic materials in soil contact poses a formidable challenge. Many soil inhabiting bacteria and fungi that cannot degrade wood can nevertheless rapidly depolymerize cellulose once its protective lignin matrix is removed. As a result, cellulose based materials are rarely used in direct contact with soil. One exception, however, is the use of cellulose string to support climbing vine...
A B Chang, J J Morrell


The resistance of timbers to impregnation with wood preservatives
1979 - IRG/WP 3137
It is anatomical structure which determines liquid flow rate within different timber species. This cannot be deduced from properties such as density or rate of growth, and can only be found by experiment. A standard test has been in use at the Princes Risborough Laboratory for many years, employing a pressure-impregnation treatment, and a large number of timbers have been studied. The test consist...
Anonymous


A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis


The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield


Copper tolerance of various Antrodia vaillantii isolates
2001 - IRG/WP 01-10406
Copper based preservatives have been extensively used in the field of wood preservation. However, several brown-rot fungi to be tolerant to copper and consequently, efficacy of copper based wood preservatives may not be sufficient. Copper tolerance is especially by some fungi that are closely aligned to or included in genus Antrodia. The highest copper tolerance was found at some strains of wood r...
F Pohleven, A Malnaric, M Humar, C Tavzes


Performance of Copper-Chrome-Arsenic (CCA) and Copper-Chrome-Boric (CCB) treated panels of Bombax ceiba and Paraserianthus falcataria against bio-deterioration at Krishnapatnam harbour, east coast of India
2003 - IRG/WP 03-30310
Results of investigations on the durability of light weight timber species (Specific gravity below 0.4) i.e., Bombax ceiba and Paraserianthus falcataria in treated and untreated condition conducted at Krishnapatnam harbour (Lat 13o28’ to 13o59’ N; Long: 80o10’ to 80o16’E) along the east coast of India are reported in the paper. Exposure trails were conducted with panels (Size: 30 x 3.8 x...
B Tarakanadha, N R Raveendra Prasad, K S Rao


An audit of copper chrome arsenic timber treatment plants throughout Queensland
1995 - IRG/WP 95-50047
Thirty seven copper chrome arsenic (CCA) timber treatment plants in Queensland were assessed according to the operational criteria specified in Australian Standard 2843.2 - 1985, Timber Preservation Safety Code - Plant Operation. The criteria have been designed to provide information on the design and operational activities of a CCA plant. Design aspects that have an effect on the environment are ...
J Norton


Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem


The microbial ecology of treated birch stakes in a soil-bed
1983 - IRG/WP 1209
The microbial ecology of small birch stakes exposed in soil beds in two Fungus Cellars was investigated. Patterns of fungal colonisation and decay initiation are described in untreated birch and copper fluosilicate-treated stakes. Results are based on fungal isolation onto selective media and direct light microscopical observations of decay features. In untreated stakes there was a rapid build-up ...
C P Clubbe


Quantification of creosote migration down wooden poles and the prevention of its depletion during flood irrigation
1994 - IRG/WP 94-50032
Polyethylene field liners heat-shrunk onto soil-contact surfaces prevented decay of creosote-treated Eucalyptus grandis vineyard poles under flood-irrigation. The present work quantified losses of creosote from these poles after six and 24 months' service. After six months' service the mean creosote retention of unlined poles above the ground line was 12.62% (m/m dry wood), with ...
M Behr, A A W Baecker


A 53-year old field trial to evaluate the performance of a range of chemical treatments on eucalypt poles
1989 - IRG/WP 3526
Hardwood pole stubs of Eucalyptus maculata, Eucalyptus pilularis, Eucalyptus saligna and Eucalyptus paniculata were examined for termite attack and fungal decay after 53 years in ground contact. The trial compared eight different chemical treatments with untreated pole stubs of the four species investigated. Untreated Eucalyptus paniculata, a Class I durability species, performed particularly well...
R S Johnstone, R A Eaton


The effect of moisture content on the electrical resistance of timber as detected by a pulsed current reistance meter (Shigometer)
1984 - IRG/WP 2212
The literature concerning the use of the Shigometer® for detecting decay in standing trees and wood poles is reviewed and the differences of opinion over the effect of timber moisture content on electrical resistance are highlighted. A simple experiment designed to test this effect is described and the implications of the results for testing poles in service are discussed. There was a large diffe...
P I Morris, D J Dickinson


Limnoria quadripunctata Holthuis - a threat to copper-treated wood
1983 - IRG/WP 4100
This paper presents the first reported attack by the crustacean marine wood-borer Limnoria quadripunctata Holthuis of CCA treated eucalypt piles. The attack occurred after 12 years service of the piles in the River Derwent at Hobart, Tasmania. Attack by both this borer and Limnoria tripunctata Menzies is also reported in CCA treated softwoods and hardwoods over periods ranging from 5 to 22.9 years...
J E Barnacle, L J Cookson, C N McEvoy


Leaching of Copper from ACQ treated wood exposed above ground
2004 - IRG/WP 04-50219
The leaching of chemicals of ACQ Type C treated wood exposed above ground for 16 months was studied. Commercially treated Hem-fir boards (Tsuga heterophylla Raf. and Amabilis fir Forb) of 37.5 mm by 87.5 mm were used. The amounts of chemical leached monthly by the rainfall were determined and the leachate was collected and analyzed. Also, the environmental factors influencing the leaching were ...
P A Chung, J N R Ruddick


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


LCA examination of preservative treated timber products and alternatives; initial results
1995 - IRG/WP 95-50040-04
Co-operative development of an LCA methodology suitable for application to preservative treated products has been carried out, based on scoping assessments of two products, CCA treated fenceposts and creosote treated distribution poles. The general results of these scoping exercices are described, based on the CCA case study. These include the identification of critical stages in the life-cycle on...
W Hillier, R J Murphy, D J Dickinson, J N B Bell


The present status of wooden catamarans of the Indian Coast
1997 - IRG/WP 97-10231
Catamarans (a.k.a. kattumarams) are the most widely used fishing craft in India, and hundreds of thousands of poor, traditional fishermen depend on these vessels for their livelihood that are almost made entirely of wood. In recent years, acute shortages and phenomenal increases in prices of timber species used in catamaran fabrication have been reported, causing great hardship to the user communi...
K S Rao


Effectiveness of wood preservatives and treatments against marine borers in Philippine waters
1976 - IRG/WP 416
A 5-year exposure test was conducted on the effectiveness of wood preservatives and treatments against marine borers in Philippine waters. Air-dried heartwood samples of apitong (Dipterocarpus grandiflorus) 76.2 x 88.9 x 609.6 mm³ (3 x 3.5 x 24 in³) in size were pressure treated with coal tar creosote and two types of CCA (copper/chrome/arsenic) and CuCZA (copperized chromated zinc arsenate) wat...
F R Siriban, M G Laxamana, P G Mata


Effects of biocides on the extracellular mucilaginous material (ECMM) produced by two wood rotting basidiomycetes
2003 - IRG/WP 03-10469
Growth and production of extracellular mucilaginous material (ECMM) by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture, supplemented with the biocides CuSO4 and cyproconazole. The production of biomass in G. trabeum was significantly influenced by the concentration of CuSO4 in the medium. When CuSO4 was...
D Vesentini, D J Dickinson, R J Murphy


Leaching Characteristics of Alder Wood Treated with Copper Based Wood Preservatives
2005 - IRG/WP 05-50225
In this study, it was designed for determining leaching characteristics of CCA and alternatives wood preservatives. Alder wood blocks were treated with CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Leaching studies were conducted according to AWPA E11-97. Copper analyses of leachate were determined Atomic absorption...
A Temiz, Ü C Yildiz, E D Gezer, S Yildiz, E Dizman


The micro-distribution of copper/chrome/arsenate in Acer pseudoplatanus and Eucalyptus maculata
1973 - IRG/WP 319
The excellent field performance of copper-chrome-arsenate (CCA) treated timber has been accepted for many years. The preservative loadings used in practice have been based on field trial results, backed by service tests. The performance of treated hardwoods in trials and practice indicated that provided the required loading and penetration could be achieved the performance would be good. Recent un...
D J Dickinson


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