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Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris


Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang


Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd


Penetration behaviour of different hydrophobic carrier substances for oily wood preservatives in Beech and Scots pine sapwood
2017 - IRG/WP 17-40804
The use of creosote as a wood preservative has a long history. Current areas of application are railway sleepers, transmission poles, timber bridges and marine applications. If the approval for creosote will not be prolonged, alternative wood preservatives will be needed. As the penetration behaviour after pressure impregnation of different alternative oily products in this fields of application i...
M Starck, A Gellerich, H Militz


Review on protection of timber bridges in Norway and other countries
2017 - IRG/WP 17-40809
Wood plays a major role in design and construction of modern bridges in Norway. Typical elements of those bridges are double impregnated glued laminated members, stress laminated timber decks, slotted-in steel plates, metal cladding of the surfaces of loadbearing members, and cross girders made of steel. Selected examples of timber bridges in Norway are presented. This review paper gives an overvi...
K-C Mahnert, U Hundhausen


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Biodegradation of creosote by white rot fungus Phanerochaete chrysosporium and a strains of Pseudomonas
2017 - IRG/WP 17-50329
The aim of this study was to determine degradation effectiveness of polycyclic aromatic hydrocarbons (PAH) contained in creosote by white rot fungus and bacteria. The following two species of bacteria Pseudomonas putida and Pseudomonas sp. as well as Phanerochaete chrysosporium fungus characterised by the ability to decompose aromatic compounds were selected for experiments. Bacterial strains were...
J Zabielska-Matejuk, A Stangierska, A Kropacz, E Kaczorek


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Uncertainty in life cycle assessment of preservative treated wood – copper and freshwater ecotoxicity
2017 - IRG/WP 17-50331
Life cycle assessment (LCA) is a method for quantifying the environmental impacts of a product over the life cycle. In the last years, there have been a growing application of LCA in developments of environmental product declaration (EPD), which is utilised by professional procurement of materials for buildings. For legislative issues, LCA have also been used to assess application of creosote to t...
L G F Tellnes


Can CCA be substituted as reference preservative?
2018 - IRG/WP 18-20641
While field testing of wood protective formulations remains probably the best method to find out the effective preservative concentration, the use of chrome-copper arsenate (CCA) as reference becomes debatable due to environmental and legislative reasons. This emerges from the European standardization bodies who have discussed reference alternatives that can omit the use of CCA. The present debate...
N Terziev, M Jebrane, P Larsson Brelid, N Morsing, P-O Flaete, P Torniainen, J S Kim, G Daniel


Degradation of Eucalyptus transmission poles varies across regions in Zambia
2018 - IRG/WP 18-30727
Evidence from literature shows that Eucalyptus poles treated with creosote last over 30 years before replacement. However, in Zambia, the life span of such poles has reduced to 5-10 years. The aim of this study was to investigate factors associated with degradation of treated Eucalyptus poles and how these varied across regions in the country. A total of 1200 poles were assessed in three differen...
P Ng’andwe, D Chungu, E Ncube


Influence of different triazoles as co-biocides in wood preservatives on efficacy and the environmental impact
2018 - IRG/WP 18-50333
In this study we investigated the efficacy and impact on the environment of different co-biocide triazoles in wood preservatives. Four different formulations (all containing 9.5% Copper) contained individual and combinations of cyproconazole, tebuconazole, propiconazole as co-biocides. Four formulations were tested according to EN 113 and EN 84 (ageing) to determine the brv for each formulation. T...
M Klamer, T Jensen, S Bang-Achton, E Morsing


The biodegradation of creosote oil by various species of white rot fungi and bacteria isolated from the contaminated soil
2018 - IRG/WP 18-50334
The aim of the study was to determine biodegradation effectiveness of the selected polycyclic aromatic hydrocarbons (PAHs) contained in creosote oil, by two white rot fungal species (Bjerkandera adusta and Irpex lacteus) and three bacterial species (Pseudomonas putida, Pseudomonas sp. OS4 and Rahnella aquatilis). Bacteria were isolated from the soil contaminated with petroleum hydrocarbons from th...
M Sydow, J Zabielska-Matejuk, E Kaczorek, AStangierska, A Kropacz


Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Relative efficacy of various oxine copper formulations against brown-rot fungi
2019 - IRG/WP 19-30741
This paper investigates the relative resistance of three different oxine copper formulations (oil-borne, water-borne, water-borne with pH-adjustment) as a preservative treatment for wood against brown-rot fungi. Impregnated southern pine sapwood cubes were exposed to R. placenta and G. trabeum cultures in a soil-block test. After eight weeks, the weight losses of the cubes were examined in relatio...
M Petruch, J Lloyd, A Taylor


Effect ofNano-Copper Oxide on Decay Resistance of Pistachio Twig-Plastic Composite
2019 - IRG/WP 19-30750
The goal of our study was to investigate the decay resistance of pistachio twig-plastic composite treated with nano-copper oxide against the white rot fungus Trametes versicoloer and the brown rot fungus Coniophora puteana. For this purpose, wood–polypropylene composites (WPCs) containing different loadings of nano-copper oxide, namely 0, 1, 2 and 3 percent (W/W), were made from pistachio (Pista...
M R M Farahani,S Pourabdollah


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Effect of pretreatment of wood surfaces with a copper monoethanolamine solution on the natural weathering performance of semitransparent stains
2019 - IRG/WP 19-40881
Semitransparent stains for wood products are favored for outdoor applications in Japan because these finishes do not hide the wood grain. However, the photoprotective effects of wood surfaces are low, therefor there is a need to improve the weathering performance. We examined the natural weathering performance of semitransparent stains on wood pretreated with a copper monoethanolamine solution (Cu...
S Isaji, H Shibui, Y Hirabayashi


2018 Railway Tie Survey and the Non-Hazardous Secondary Materials Rulemaking Activities
2019 - IRG/WP 19-50352
This presentation will discuss a survey AAR recently completed on the management of used crossties in the North American rail industry. Approximately 23 million new wood ties are purchased and installed in the North American rail network every year. The presentation will show the number and percentage of ties which are managed by reused in track, reuse in commercial, agricultural or residential la...
R Fronczak, S Smith


Impregnation of railway sleepers - Investigation of a system-sleeper as an alternative for creosote treated sleepers
2020 - IRG/WP 20-40896
For nearly 200 years wooden railway sleepers are impregnated with creosote. After initially using vacuum pressure processes for impregnation, empty-cell processes have been developed quickly and are used until today. Because of political developments, creosote will probably be banned on the European market in the near future. The Fürstenberg-System-Sleeper, which combines for Europe innovative as...
M Starck, A Heidel, C Brischke, H Militz


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


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