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Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal


A genomic sequencing approach to study wood decay and copper tolerance in the brown rot fungus, Antrodia radiculosa
2010 - IRG/WP 10-10720
We used Illumina paired-end short read sequencing (76 nt, 300 bp insert size) to produce a de novo assembly of the genome of Antrodia radiculosa, a copper-tolerant brown rot fungus that is capable of aggressive wood decay. Quality analysis of the base calls in the dataset (8.95 Gb) showed that the majority of the nucleotide sequence was of the highest quality with 5% in the lowest quality group. ...
J D Tang, T Sonstegard, S Burgess, S V Diehl


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Chemical mediated depolymerization of cotton cellulose for the understanding of non-enzymatic fungal decay
2010 - IRG/WP 10-10731
Small, low molecular weight non-enzymatic compounds have been linked to the early stages of brown rot decay as the enzymes involved with holocellulose degradation are found to be too large to penetrate the S3 layer of intact wood cells. The most pronounced of these which were analyzed in this study are hydrogen peroxide, iron, and oxalic. The compounds related to the Fenton reaction: the combinati...
A C Steenkjær Hastrup, B Jensen, F Green III


Toward an assessment of copper bioavailability in treated wood
2010 - IRG/WP 10-20445
Many modern wood preservative systems rely on copper (Cu). Some oxalate-producing fungi detoxify Cu by immobilizing it in crystals, and this may decrease its physiological availability (bioavailability). Cu bioavailability may also decrease during wood treatment. Cu retention in wood, however, is typically measured as a weight-to-volume concentration without an estimate of its bioavailability and ...
J S Schilling, J J Inda


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Photostabilization of Wood with Higher Molecular Weight UV Absorbers
2010 - IRG/WP 10-30524
Higher molecular weight UV absorbers were created by reacting the epoxy-functionalized UV absorber 2-hydroxy-4(2,3-epoxypropoxy)-benzophenone (HEPBP) with maleic, phthalic or succinic anhydride. The ability of the UV absorbers to photostabilize wood was then examined. FTIR-spectroscopy confirmed that HEPBP reacted with phthalic anhydride to create a polyester that preserved the UV-absorbing benzop...
P D Evans, M J Chowdhury


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su


Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Comparison of Micronized Copper Particle Sizes
2010 - IRG/WP 10-30538
The particle sizes of micronized copper formulations derived from treating liquids were compared with those deposited in wood treated with those liquids. The intent was to determine if agglomeration occurs in the liquids during the treatment process, if screening of the agglomerates occurs in the wood and if there are any apparent differences in the particle sizes in the wood. Three formulations...
C R McIntyre


A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure. In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer


Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Antifungal and wood preservative efficacy of IPBC is enhanced by α - aminoisobutyric acid
2010 - IRG/WP 10-30544
There is currently a need to reduce the biocide content of wood preservatives, without decreasing efficacy. The nonmetabolised amino acid analogue α-aminoisobutyric acid (AIB) acts as a translocated inhibitor of mycelial spread in basidiomycete wood decay fungi, although it does not kill the organism. Factorial combinations of AIB with either the azole fungicide tebuconazole, or 3-iodo-2-...
P Bota, E Baines, A Mead, S C Watkinson


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Studies on Effect of pH on Copper Availability in Copper-Based Preservatives
2010 - IRG/WP 10-30549
Laboratory methods have been employed to investigate the pH effect on the copper solubility of basic copper carbonate. The pH was controlled using two different approaches. One was with the adjustment of pH of the solutions by acid or base using sulfuric acid or sodium hydroxide until the solution equilibriums were obtained for each defined pH. A second approach was to control pH with buffer sol...
L Jin, P Walcheski, A F Preston


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Influence addition of boron compounds to adhesives on the bonding quality and fungicidal properties of glued wood
2010 - IRG/WP 10-40497
Wood is one of the most important construction materials. However, users of wood face two issues: limited dimensions and insufficient durability. These issues have been overcome with the development of bonding and wood preservation. The preservation of glued wood is elucidated in this paper. Through the addition of boric acid to adhesives, we tried to improve the fungicidal properties of glued woo...
M Humar, B Lesar, A Ugovsek, M Kariz, P Kralj, M Šernek


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick


Effect of borax-boric acid Treatment of simul (Bombax ceiba) Veneers on Glue-Bond Quality of Plywood
2010 - IRG/WP 10-40525
The glue-bond quality of plywood made of treated simul (Bombax ceiba) veneers was investigated. The veneers were treated with cold and hot water solution of borax-boric acid (BB) of different concentrations and treatment durations. The plywoods were made at three different pressures in hot press using urea formaldehyde glue. The glue-bond strength of untreated plywood in dry shear-test was found t...
K Akhter, Md Abul Hashem, S Akhter


Preservative Treatment of simul (Bombax ceiba) Veneers with Hot and Cold Water Solution of borax-boric acid by Soaking Process
2010 - IRG/WP 10-40528
Veneers of simul (Bombax ceiba) were treated with different concentrations of water- borne preservatives borax-boric acid (BB) by soaking process for different time periods. In the case of hot water treatment, it was found that the average retention of preservative chemicals increased gradually with the increasing treatment period from 20 minutes to 60 minutes. Similar trend was observed in the ca...
K Akhter, Md Abul Hashem, S Akhter


Copper distribution in soil leached from full scale decking boards during one year
2010 - IRG/WP 10-50265
The distribution of copper in the soil under exposed decking boards after one year has been analysed. The decking boards were impregnated with copper HDO, copper quat and copper triazoles. The decking boards were pine sapwood and pressure treated in a full cell process, fixed by heating and then dried. The samples were not surface treated. Each decking sample of five boards (0.25 m2) was placed on...
F G Evans


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