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Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Diffusion treatment of gauged radiata pine timber using "Boracol 20"
1987 - IRG/WP 3437
Green gauged 100 x 50 mm radiata pine timber was preservative treated by brush application of "Boracol 20" followed by diffusion storage. Preservative retention analyses indicated that retention requirements in the core could be achieved within a six week diffusion period, thus representing a time saving of 25% over conventional boron treatment of rough-sawn radiata pine. Similar treatment of kiln...
D R Page, P Vinden, S Retter


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


The influence of cement and calcium compounds on the performance of CCA preservatives
1983 - IRG/WP 3221
The influence of cement and calcium compounds on the durability of untreated and CCA treated wood is considered. Calcium compounds were found to reduce the toxicity of a CCA preservative to a soft rot fungus at copper to calcium ratios of 1:1 and 1:10 using a cellulose filter paper technique. Further studies are outlined and some possible mechanisms by which cement and calcium compounds may affect...
R J Murphy


Efficacy of a novel copper-based organic solvent preservative in laboratory and fungus cellar tests
1995 - IRG/WP 95-30071
The efficacy of Chemicca 4, a novel copper-based organic solvent preservative, was compared with that of other LOSP in pure culture laboratory decay tests and with that of CCA and TBTO in a fungus cellar exposure. It was markedly superior to copper and zinc naphthenates at equivalent metal retentions in laboratory decay tests, and similar in activity to TBTO. After 60 months' fungus cella...
M E Hedley, P N Maynard


The role of oxalic acid in short fiber formation by the brown-rot fungus Postia placenta
1993 - IRG/WP 93-10028
The mechanism by which brown-rot fungi depolymerize wood and cellulose remains a perplexing problem. Current evidence favors oxidation by low-molecular weight, non-enzymatic fungal metabolites. During attack of cotton cellulose by Postia placenta MAD-698, the degree of polymerization (DP) decreases to limit of degree of polymerization (LODP) over a period of 5-6 weeks with relatively low weight lo...
F Green III, J M Hackney, C A Clausen, M J Larsen, T L Highley


Correlation between modulus of elasticity, mass losses and FTIR spectra of copper treated decayed wood
2006 - IRG/WP 06-10580
The composition of copper-based preservatives will change from copper-chromium to copper-ethanolamine, due to environmental demands. The most important drawback of copper-impregnated wood is the presence of tolerant fungal organisms that have developed an ability to degrade such preserved wood. In order to elucidate these processes, specimens (0.5×1.0×15 cm) made of Norway spruce (Picea abies) w...
M Humar, B Bucar, F Pohleven


Is Field Test Data from 20 x 20mm Stakes Reliable? Effects of Decay Hazard, Decay Type and Preservative Depletion Hazard
2006 - IRG/WP 06-20327
Effects of decay hazard, decay type and preservative depletion hazard on the performance of variously preservative treated 20 x 20 x 500 mm Radiata pine and Fagus sylvatica test stakes across 13 field test sites in New Zealand and Queensland Australia were determined. Radiata pine treated with an ammoniacal copper quaternary preservative (ACQ) (1.56% m/m a.i.) and copper chrome arsenate (CCA) (...
R Wakeling


The Use of Modulus of Elasticity and Modulus of Rupture to Assess Wood Decay in Laboratory Soil-Bed Test
2006 - IRG/WP 06-20338
The efficacy of wood preservatives were determined in a soil-bed test. Samples of alder wood sapwood (Alnus glutinosa subsp. barbata) (5x10x100 mm) were treated with Solutions of CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Modulus of Elasticity, modulus of rupture, mass loss and decay rate according to AWPA E7 wer...
A Temiz, Ü C Yildiz


Measuring Soil Respiration as a New Approach to Describe the Interaction Between Wood (Treated and Untreated) and Microbiologically Active Soil
2006 - IRG/WP 06-20344
Soil respirometry was employed to examine the relationship between both the performance of copper organic preservatives in contact with and the amount of carbon dioxide evolved from soil and the effect of wood treated with preservatives on carbon turnover in soil. Wood was treated with a range of copper organic preservatives intended for use in ground contact as well as an organic preservative in...
I Stephan, W Mierke


Water analysis in chemicals, wood or chemically treated wood using a new analytical method for selective water detection
2006 - IRG/WP 03-30391
Water or moisture content analysis can be a challenging task in many applications. However, knowing accurately the type of water which can be found in a given sample or product can provide important information about a chemical compound used for wood treatment and especially about the treated wood sample. Moisture content in wood plays an important role in fungal growth and it needs to be extensi...
R Craciun, D Taylor


Above and Below-Ground Depletion of Copper, Chromium and Arsenic from Pinus radiata and Fagus sylvatica at Thirteen Test Sites in New Zealand and Australia
2006 - IRG/WP 06-30402
The objective was to determine the significance of site and wood species on preservative depletion for a copper chrome arsenate preservative (CCA) from 20 x 20 x 500 mm field test stakes after 5.5 and 4.5 years for pine and beech respectively. At least 5 sacrificial stakes were used to produce site means. Site and wood species had a major effect on copper, chromium and arsenic loss from CCA treate...
R Wakeling


Long term marine performance of ACZA treated Hem fir in Krishnapatnam harbour, east coast of India
2006 - IRG/WP 06-30409
The performance of Hem fir (Tsuga heterophylla) and Southern pine (Pinus sp.) treated with ammoniacal copper zinc arsenate (ACZA) and copper dimethyldithio carbamate (CDDC) at two retention levels of each preservative was assessed in tropical marine waters at Krishnapatnam harbour on the east coast of India. Panels treated with ACZA of lower loadings (23.1 Kg/m3) had failed in 38 months while the ...
B Tarakanadha, K S Rao, J J Morrell


Copper borate for the protection of engineered wood products
2006 - IRG/WP 06-40334
Copper borate was evaluated for use in protecting oriented strand board (OSB) from mould, decay, and termites. Aspen OSB bonded with either phenolic or isocyanate resin was treated with several formulations of copper borate at various loadings from 0.26 to 4 percent by weight. These panels were then tested to determine the impact of the preservative on mechanical properties as well as resistance ...
R Smart, W Wall


CCB Preservative treatment of split muli (Melocanna baccifera ) bamboo by soaking process
2006 - IRG/WP 06-40336
This study was carried out in order to investigate the retention of chemicals inside the split muli ( Melocanna baccifera ) bamboo after preservative treatment by soaking process. Treatment with 10% aqueous solution of CCB (copper-chrome-boron) was applied in split bamboo of two sizes (1/4 part and 1/8 part) at three different moisture contents and five time periods (24, 48, 72, 96, 120 hours). It...
K Akhter, M H Chowdhury


Non-pressure preservation technique of five less durable timber species – Kadam (Anthocephalus cadamba), Shimul (Bombax ceiba), Pithalu (Trewia nudiflora), Am (Mangifera indica) and Boroi (Ziziphus jujube) of Bangladesh
2006 - IRG/WP 06-40322
Wood is a versatile renewable resource, which has been extensively used as a reliable construction material as well in furniture ever since the beginning of civilization. The Major disadvantage of wood is its susceptibility to biodeterioration by fungi, insects and bacteria. In tropical countries like Bangladesh, fungi is the most significant of these biodeterioration agents. Kadam (Anthocephalus...
G N M Ilias, A H Kabir, F Begum, M F Alam


Performance evaluation of Borax: Boric Acid treated Green bamboo through new VAC-FRI and conventional processes
2006 - IRG/WP 06-40327
Amongst giant arborescent grass bamboo is the only versatile member containing lignocellulosic materials like wood. Therefore it offers almost parallel uses where wood is traditionally an established material. The wood scarcity, environmental role of our natural forests, longer rotation cycle of plantation species, ban in felling, the ever growing utilization demands of wood to the tune of 3.2 mil...
S Tripathi, S N Nautiyal


Corrosiveness of metal by copper-based preservatives
2006 - IRG/WP 06-40329
The corrosive rates of 4 types of metal as well as epoxy-coated metal by a variety of preservatives derived from different copper source and ingredients were conducted in this paper. The main results shown that: CCA is less corrosive to red brass and Q235A steel than other copper formulations; Copper-based preservatives such as ACQ and copper azole derived from basic cupric carbonate or cupric hyd...
Ying Zhang, Mingliang Jiang


Leaching of CCA from Paraserianthus falcataria panels exposed to field conditions at Krishnapatnam harbour, Andhra Pradesh
2006 - IRG/WP 06-50241
This study assessed the leaching of copper, chrome and arsenic (CCA) from Paraserianthus falcataria (=Albizia falcataria) panels exposed to marine condition at Krishnapatnam harbour on the east coast of India. Metal loss was assessed in test panels after 6, 12, 24 and 36 months of exposure using Atomic Absorption spectrophotometer (AAS). The metal loss was found slightly higher in panels treated ...
B Tarakanadha, K S Rao


Corrosion of metal fasteners in contact with copper preservative treated wood
2007 - IRG/WP 07-20370
The corrosion rates of metal fasteners in contact with alkaline copper quat (ACQ) treated wood with or without commercially available water repellent was compared to that of cedar. In this experiment, fasteners were sandwiched between two pieces of treated wood and exposed to a humid environment at a slightly elevated temperature. The use of a “sandwich” design allowed periodic examination of ...
BaekYong Choi, J N R Ruddick


Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Protection of wood for above ground application through modification with a fatty acid modified N-methylol/paraffin formulation
2007 - IRG/WP 07-40378
Hydrophobic chemical modification can be regarded as an alternative approach to conventional wood preservation using biocides in order to protect wood in hazard class 3 according the European Standard EN 335-1. A formulation containing fatty acid modified N-methylol/paraffin and an aluminium salt catalyst was used to change the material properties of wood in order to protect wood from fungal dec...
Nguyen Hong Minh, H Militz, C Mai


Preservative treatment of Golla cane (Daemonorops jenkinsiana) by pressure process
2007 - IRG/WP 07-40379
The feasibility of preservative treatment of golla cane (Daemonorops jenkinsiana (Griff) Mart). by pressure process has been studied using water borne preservatives CCB (copper-chrome-boron). Cane samples of three different lengths 1m, 2m and 3 m. were treated at different pressure and time period to evaluate the extent of penetration and retention of preservative chemicals. It was observed that t...
K Akhter, M Hoque Chowdhury


Influence of ethanolamine on lignin depolymerization and copper leaching from treated Norway spruce and beech wood
2007 - IRG/WP 07-30423
Copper-ethanolamine based wood preservatives are replacing several classical copper-chromium based solutions, due to foreseen ban of chromium. Fixation of copper-ethanolamine based wood preservatives is not as good as fixation of copper-chromium ones. The main object of this manuscript was to prove, that ethanolamine is the prime reason for insufficient fixation of copper-ethanolamine formulations...
M Humar, B Bucar, M Zupancic, D Žlindra, F Pohleven


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