IRG Documents Database and Compendium


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An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper-chrome-arsenic preservative
1981 - IRG/WP 3150
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. We have evaluated the influence of steaming on treatability with a waterborne CCA preservative....
C R Coggins


Electrodialytic remediation of creosote and CCA treated timber wastes
2002 - IRG/WP 02-50190
There is a growing concern about the environmental issue of impregnated timber waste management, since an increase in the amount of waste of treated wood is expected over the next decades. Presently, no well-documented treatment technique is yet available for this type of waste. Alternative options concerning the disposal of treated wood are becoming more attractive to study, especially the ones ...
E P Mateus, A B Ribeiro, L Ottosen


Leaching of copper, chromium and arsenic from CCA-treated Scots pine exposed in sea water
2000 - IRG/WP 00-50149
A laboratory leaching trial combining a static and a flowing seawater system was carried out to measure the leaching rates of copper, chromium and arsenic from the surface of Scots pine panels vacuum-pressure treated to 3, 6, 12, 24, and 48 kgm-3 CCA. Untreated and treated panels were exposed in flowing seawater for up to 8 weeks followed by 2 weeks submersion in static seawater which was taken fo...
C J Brown, R A Eaton


Improved PEC preservatives with added biocides
1985 - IRG/WP 3322
Biocidal chemicals have been incorporated into formulations within the broad framework of pigment emulsified creosote (PEC) to provide novel potential multi-purpose preservatives. Preparations of PEC plus TCMTB, Boracol 40, copper ethanolamine nonanoate, Quatramine 80, arsenic trioxide, Troysan Polyphase, and CCA have been formulated and assessed for preserving ability in soil-jar and Accelerated ...
H Greaves, C-W Chin, J B Watkins


Proposed test procedure to determine the effect of timber substrate on the effectiveness of a copper/chrome/arsenic preservative in seawater
1975 - IRG/WP 411
R A Eaton


X-ray analysis of selected anatomical structures in copper/chrome/arsenic treated wood
1973 - IRG/WP 320
Application of analytical electron microscopy to problems in wood preservation has been very limited. Indeed, less than ten workers appear to have published their results using the technique, and of these' only two papers deal with energy dispersion procedures in the scanning electron microscope; the others employ the more familiar wavelength dispersive methods of the electron probe....
H Greaves


An introduction to environmental aspects of groundwater arsenic and CCA treated wood poles in Bangladesh
1997 - IRG/WP 97-50081
The environment comprises biosphere, lithosphere, atmosphere and hydrosphere. Therefore, environmental science is a multi-disciplinary study, includes life sciences, physical sciences, chemical sciences, geology, geography, meteorology, forestry, agriculture, soil science, hydrology, ecology, public health, engineering etc. Tremendous industrial and mining activities, deforestation and population ...
A K Lahiry


Lignin-copper, a new wood preservative without arsenic and chromium
1992 - IRG/WP 92-3702
A more environmentally sound treatment for wood with preservatives containing no arsenic or chromium, has been developed and studied on a laboratory scale. The method involves a first step impregnation with an aqueous solution containing modified, water-soluble kraft lignin followed by a second step involving impregnation with a copper salt solution to give fixation of the lignin into a water-inso...
B Ohlsson, R Simonson


Assessment of contamination of soil and water at a CCA treatment plant: A demonstration project
1996 - IRG/WP 96-50067
Soil, sludge, dust and water samples were collected at a copper/chromium/arsenic wood preservation plant. Contamination of soil, sludge, dust and surface water with copper, chromium and arsenic was detected. Levels of contamination were sufficiently high to require remediation. Contamination originated from preservative solution dripping from recently treated wood. Migration of contaminants was vi...
P N Durrant, D C R Sinclair, G M Smith


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Fungi associated with groundline soft rot decay in copper/chrome/arsenic treated heartwood utility poles of Malaysian hardwoods
1992 - IRG/WP 92-1567
Copper-chrome-arsenic treated heartwood from Malaysian hardwood utility poles in service for 8-23 y at two localities in the wet tropical Peninsula Malaysia were surveyed for soft rot in the ground-contact region. Soft rot decay was detected in all the poles. Isolation studies indicated the ability of a variety of microfungi and basidiomycetes to colonize treated heartwood. Most isolates exhibited...
A H H Wong, R B Pearce, S C Watkinson


Water-borne preservative marine trials in Western Canada
1981 - IRG/WP 470
Red pine boards treated with chromated copper arsenate, ammoniacal copper arsenate, copper zinc arsenic additive, a modified ammoniacal copper arsenate, and zinc arsenic additive, have been installed in a marine field test at West Vancouver, British Columbia. After two and a quarter years exposure, all the test samples are in excellent condition with the exception of those treated with the zinc ar...
J N R Ruddick


Disposal of CCA treated waste wood by combustion - An industrial scale trial
1996 - IRG/WP 96-50068
Totally 272 m³ (62.7 t) of CCA treated utility poles were chipped and incinerated at Jalasjärvi Gasification Plant. In average the whole batch of chips contained 57 kg of elementary copper, 95 kg chromium and 76 kg arsenic. During the 56 h combustion trial the measured arsenic emission to the air was 76 g in total. Copper and chromium emission was less than 1 g. The condensing water from the coo...
A J Nurmi


Leaching of copper, chromium and arsenic from CCA-treated slash pine heartwood
1994 - IRG/WP 94-50020
Drying green slash pine with any of three high temperature drying schedules produced a product in which both the sapwood and the heartwood could be penetrated with CCA using a modified Bethell treatment schedule. Required H3 retentions were achieved in both sapwood and heartwood, from 200 litres per m³ charge uptake. Post-treatment fixation/drying was accomplished by three different regimes, incl...
M J Kennedy, G Palmer


The course of fixation of Cu-Cr-As wood preservatives
1972 - IRG/WP 307
Copper-chrome-arsenic (CCA) preservatives in contact with wood result in an instant extensive increase of pH, because of ion-exchange and adsorption reactions with the wood. During precipitation of the active elements the pH continuously increases but reaches a maximum, when all chrome is consumed. Some of the early reaction products are unstable and slowly convert via dissolution into stable comp...
S-E Dahlgren


Chemical analyses of IRG/COIPM INTERNATIONAL MARINE TEST (to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water) samples
1987 - IRG/WP 4114
Chemical analysis of CCA and CCB treated timber was carried out after exposure at tropical and temperate marine sites. Results indicated that losses of all elements had occurred. In particular, losses of boron were severe. Arsenic and copper were also lost. The chromium components in both formulations was the most dominant metal remaining. The results suggest that chromium modification was importa...
L E Leightley


Retention and distribution of copper/chrome/arsenic (CCA) in pressurised sap-displaced UK grown spruce and pine
1986 - IRG/WP 3366
Increment cores were taken from UK grown Scots pine (Pinus sylvestris L.), Corsican pine (Pinus nigra var. maritima Ait), Sitka Spruce (Picea sitchensis (Bong) Carr), and Norway spruce (Picea abies (L) Karst) distribution poles treated by pressurised sap-displacement using a 1.8% copper, chrome, arsenic (CCA) solution. Each increment core was sectioned radially and the copper, chrome, and arsenic ...
P D Evans, G M Smith, B King


The volatilization of arsenic on burning copper-chrome-arsenic (CCA) treated wood
1978 - IRG/WP 3111
Small scale burning experiments are described involving copper-chrome-arsenic treated wood. Approximately 20 per cent of the arsenic was volatilised when the wood was burned in air but 60 per cent when burned in an oxygen-enriched atmosphere, this increase is attributed to an increase in combustion temperature. Although a small increase in arsenic evolution was found with an increased concentratio...
A-J Dobbs, C Grant


A comparative study of CCA type C and B treated poles in service
1993 - IRG/WP 93-50001-05
CCA K33 type B and C treated utility poles, 9 pieces of each treatment type, were analyzed for preservative retention after 11 years in use. Borings were taking 1 m above and 0.3 m below the ground line. Also total amount of copper, chromium and arsenic was determined in soil surrounding the poles. The solubility of these active components in soil was monitored by using different leaching procedur...
A J Nurmi


Preliminary study on relation of wood structure to copper/chrome/arsenic (CCA) distribution in kempas (Koompassia malaccensis)
1995 - IRG/WP 95-40054
Kempas had been treated with copper/chrome/arsenic (CCA) preservative using full cell process. Analysis of preservative distribution at the micro level in relation to wood structure was carried out using scanning electron microscope (SEM) and energy dispersive X-ray (EDXA) analysis. The results showed that CCA elements were detected in all wood tissues at different ratios. Distribution of chemical...
S Ani, S Salamah


Sampling variation in a copper chrome arsenic treated power transmission pole
1990 - IRG/WP 2351
The Queensland Forest Service routinely samples poles treated at all treatment plants throughout the State. Each treatment plant is issued with a Certificate of Registration and the accompanying documents list the different levels of preservative retention required for performance in various service conditions. The posted levels represent the.minimum permissible, and it is to these concentrations ...
J Norton


Soil-bed studies. Part 2: The efficacy of wood preservative
1983 - IRG/WP 2205
Various methods of decay assessment were investigated. Three stages or phases of decay were identified which could be used to describe the efficacy of a preservative system or virulence of a soil-bed testing medium. These included the lag, decay, and senescent phase. Premature senescence could arise if wood samples became waterlogged. It was concluded that time to failure was unsuitable as a metho...
P Vinden, J F Levy, D J Dickinson


Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg


CCA modifications and their effect on soft rot in hardwoods. Part 2
1983 - IRG/WP 3244
The work outlined in this document is a continuation of that presented in Document No: IRG/WP/3201. The findings described in the previous paper are summarised below: a double treatment of CCB followed by arsenic (CCB+A) is more effective than a double treatment of boron followed by CCA (B+CCA) or a single treatment of CCA, CCB or CCAB in controlling soft-rot due to Chaetomium globosum in birch. C...
S M Gray, D J Dickinson


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