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A field evaluation of modified and unmodified alkylammonium compounds
1987 - IRG/WP 3436
Laboratory soil block studies of alkylammonium compounds (AAC's) at Forintek and other research establishments have shown that they can prevent decay by standard wood-destroying fungi. Their performance in field tests, however, has been disappointing. Following investigation of possible causes for this poor field performance, stakes treated with modified AAC's were installed at W...
J N R Ruddick


Partial characterization of inhibitors extracted from pine (Pinus sylvestris) sapwood active against germination of wood rotting fungi
1988 - IRG/WP 1351
Germination inhibitors in pine sapwood could be extracted and separated with the aid of solvent partitioning and chromatography on silicic acid. The inhibitory action was tested by three different bioassays. Active fractions have been characterized by TLC and HPLC. Inhibitory activity could be correlated with phenolic compounds. The minimum active concentration of inhibitors have been determined....
J Bjurman


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


A substantively bonded water repellent treatment based on chromium carboxylates
1985 - IRG/WP 3344
Chromium carboxylates soluble in toluene have been synthesised and applied to Scots pine (Pinus sylvestris) sapwood. Without any further treatment, the compounds may be readily leached from wood surfaces with toluene. After a period of heating however, they become fixed to the cell wall, substantial amounts being resistant to leaching even under reflux conditions for several hours. Treatment of wo...
J K Wright, W B Banks, W J Eilbeck


Uptake by grape plants of preservatives from pressure-treated posts not detected
1975 - IRG/WP 350
Leaf and stem tissue and fruit of grape plants (Vitis rotundifolia Michx. cv. Magnolia) were analyzed for copper, chromium, and arsenic, 1, 2, and 3 years after planting 3 inches from copper-chrome-arsenate or fluor-chrome-arsenate-dinitrophenol-treated southern pine posts. Quantities of copper in leaf and stem tissue and fruit of plants next to posts treated with copper-containing preservatives r...
M P Levi, D Huisingh, W B Nesbitt


Measurement of electrokinetic potential to evaluate adsorption of quaternary ammonium salt
1991 - IRG/WP 3672
Measurement of z-potential in the wood treated with preservatives is suggested as a method for determination of the adsorption of preservative to wood. It has been found that measurement of z-potential of wood treated with quaternary ammonium salt type preservatives can be a useful method to determine the adsorptives phenomena of preservatives and by which there is a remarkable differences in the ...
Yeong Suk Kim


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


Soft rot - Soil burial - Tests. Influence of the addition of nitrogen compounds to the soil on wood decay by soft rot
1972 - IRG/WP 213
The decay of wood specimens buried in soil is influenced by various factors. Decisive are the water content, the content of organic substances, the pH-value, the content of mineral nutritive salts, nitrogen content, etc. of the soil. These tests were carried out in order to investigate if the decay of wood in the soil will be influenced by additions of various nitrogen-compounds in different conce...
O Wälchli


Changes of copper and chromium content after leaching in wood impregnated with the CCB and CB preservatives
2000 - IRG/WP 00-50147
The objective of the study was impregnated with CCB and CB preservatives pine wood of moisture content varying from 12% to 55% subjected to leaching. Losses of copper and chromium were determined for individual layers of wood up to 3 cm from the girth. The results were compared to the total amount of metals determined in water extracts. The degree of leaching of metal ions from wood of 55% moistur...
B Mazela


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Wood preservation in Canada - Regulation and Registration
2001 - IRG/WP 01-50166-02
The Canadian wood preservation industry is at a critical juncture now as a number of initiatives converge on the industry over the next few years. Issues facing the industry include: Re-evaluation of the conventional wood preservative chemicals - inorganic arsenicals, creosote and pentachlorophenol targeted for July 2001. Delayed registration of new actives as a result of re-evaluation activity an...
P A Cooper


A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi


The susceptibility to sludging of sulfate and oxide CCA
1990 - IRG/WP 3599
Radiata pine sapwood was treated separately with a sulphate CCA-C and an oxide CCA in a pilot scale pressure plant using a full cell process. CCA solutions were recovered from the final vacuum phase, placed in plastic tubes, and their susceptibility to sludging determined by examining changes in solution pH, time required for sludge to form and weight and chemical composition of sludge formed. Sul...
B T Mutandadzi, P D Evans


The influence of UV and IR radiation on leaching of copper and chromium from preservative-treated pine and spruce
1992 - IRG/WP 92-3687
The influence of artifical UV- and IR-radiation on the leaching of copper and chromium components of a CCB-preservative from freshly treated pine and spruce was evaluated. On small pinewood samples it could be shown, that the leaching of copper and chromium can considerabely be reduced by UV-radiation. A Philips HPA lamp type reduced the leaching most effective. IR-radiation lead to higher leachin...
H Militz


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


New method to find out the volatile organic compounds (VOC) of wooden material
2000 - IRG/WP 00-20189
Volatile organic compounds (VOC) of pine, spruce and larch wood were studied using a new technique developed at VTT Chemical Technology. 50 mg of crushed wood material was placed into glass tubes. The tubes were closed with a glass wool, which is pressed with a tube cap. Wood samples were analysed with a gas chromatograph after thermal desorption using four different temperatures (50°C, 100°C, 1...
H Viitanen, K Villberg, K Saarela


Diazenes and some organic complexes of boron as potential fungicides for preservation of wood
1999 - IRG/WP 99-30197
Screening for fungicidal activity represents the first step in searching for new active components with enhanced environmental profile in comparison with traditional wood preservatives. Diazenes, their salts, and the salts of the corresponding semicarbazides, as well as several complexes of boron, were screened for fungicidal activity against wood decay fungi Trametes versicolor, Coniophora putean...
M Petric, B Paradiz, J Stern, F Pohleven, S Polanc, B Stefane, R Lenarsic


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


The influence of cement and calcium compounds on the performance of CCA preservatives
1983 - IRG/WP 3221
The influence of cement and calcium compounds on the durability of untreated and CCA treated wood is considered. Calcium compounds were found to reduce the toxicity of a CCA preservative to a soft rot fungus at copper to calcium ratios of 1:1 and 1:10 using a cellulose filter paper technique. Further studies are outlined and some possible mechanisms by which cement and calcium compounds may affect...
R J Murphy


The role of chromium in wood preservatives - The situation and new results concerning biological efficacy
2006 - IRG/WP 06-30397
A heavy discussion about the status of chromium-containing compounds in wood preservatives has ensued in the European Union since the Biocidal Product Directive 98/8/EG has come into force.The origin of this discussion is the fact that according to the Biocidal Product Directive chromium trioxide and sodium dichromate have been identified as active ingredients and therefore the placement of wood p...
P Jüngel, H Härtner, E Melcher


Above and Below-Ground Depletion of Copper, Chromium and Arsenic from Pinus radiata and Fagus sylvatica at Thirteen Test Sites in New Zealand and Australia
2006 - IRG/WP 06-30402
The objective was to determine the significance of site and wood species on preservative depletion for a copper chrome arsenate preservative (CCA) from 20 x 20 x 500 mm field test stakes after 5.5 and 4.5 years for pine and beech respectively. At least 5 sacrificial stakes were used to produce site means. Site and wood species had a major effect on copper, chromium and arsenic loss from CCA treate...
R Wakeling


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


Paintability and gluability of wood treated with arsenic-free and chromium free preservative treatments
2006 - IRG/WP 06-40342
The objective of this project was to study, in comparison with traditional CCA treatment, the paintability and gluability of wood treated with arsenic-free and chromium-free preservative treatments. Four formulations, all certified CTB P+, were selected in accordance with their representativeness of the preservative product market: one CCA reference formulation and three chromium and arsenic free...
L Podgorski, G Legrand


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