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Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


Relative performance of copper/chrome/boron (CCB) and copper/chrome/arsenate (CCA) in ground contact
1992 - IRG/WP 92-3694
The performance of four retentions each of an oxide CCA formulation and a salt formulation of CCB in radiata pine and European beech was compared after 18 years' field exposure. In radiata pine CCA oxide was more effective (4 failures out of 40) than CCB (9 failures out of 40). However, in European beech CCB was substantially more effective (22 failures) than CCA oxide (all failed). Analy...
M E Hedley


Comparison of three methods for assessing the in-ground termite resistance of treated timber, durable timber and plastics at sites in Australia, USA and Thailand - First results
1998 - IRG/WP 98-20132
The in-ground resistance of materials to attack by subterranean termites is most commonly assessed with one form or another of the conventional graveyard method, despite the significant shortcomings of this method. In Australia, an alternative method, in which all samples of test materials are placed below-ground, has been in use for more than 10 years. The method provides reliable exposure of sam...
M Lenz, A F Preston, J W Creffield, K J Archer, B M Kard, C Vongkaluang, Y Sornnuwat


A method for the preliminary assessment of timbers for their treatability with preservatives under pressure
1977 - IRG/WP 3100
President Maurice Fougerousse has provided the following references to a IUFRO report, published in English, French and German, which may be of interest to IRG members: 'A method for the preliminary assessment of timbers for their treatability with preservatives under pressure', PANS Vol 23, No 2, 153 158, June 1977. 'Une methode d'evaluation preliminaire de l...
M Fougerousse


Ability of chitosans to limit wood decay under laboratory conditions.
2004 - IRG/WP 04-30339
Chitosans have recently been explored for controlling a number of plant pathogenic fungi and have shown some promise for controlling stain fungi on wood. The potential for using chitosans either alone or in combination with copper sulfate to protect wood from fungal decay was explored using maple veneers. Chitosan treatment reduce weight losses caused by two brown rot and one white rot fungi, howe...
M Maoz, J J Morrell


Remedial treatments of glulam = diffusion of active ingredients through glue lines from solid wood diffusable preservatives
1996 - IRG/WP 96-30117
Diffusable preservatives are very suitable for use in remedial treatments of laminated beams in which too high moisture content involves the development of wood destroying fungi. The diffusion of active ingredients (boric acid, disodium octoborate, bifluoride) is well observed in solid wood but in a composite wood, the glue lines may appear not only as a barrier for the diffusion but also, may be ...
D Dirol, S Mouras


Accelerated laboratory testing of preservatives on 13 North American wood species
1999 - IRG/WP 99-30201
The ability of selected water and solvent based biocides to protect wood against fungal attack was evaluated on 13 North American wood species using 7 decay fungi in a modified soil block test. Most preservatives were capable of providing protection at their recommended above ground and soil contact use levels. Many decay fungi caused substantial weight losses on blocks treated with chlorothalonil...
J J Morrell, C M Freitag


An appraisal of methods for environmental testing of leachates from salt-treated wood; part 1
1998 - IRG/WP 98-50115
The magnitude and diversity of leaching tests with salt-treated wood, performed by institutes as well as industry, strongly appeal for harmonisation towards one single method. That procedure should be well-defined, cost- and time-effective and moreover be extended with a clear detection and interpretation scheme. The paper(s) presented here tend to evaluate 2 existing leaching methods, the ENV 12...
G M F Van Eetvelde, M Stevens, F Mahieu, H-W Wegen, A Platen


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


Unsuitability of the limiting dose as a criterion for assessing the toxicity of preservatives to wood-destroying fungi
1974 - IRG/WP 243
In the majority of methods for investigating preservatives for wood-destroying fungi their toxicity is assessed by determining what is called the "limiting dose". This normally denotes a range of preservative solution concentrations or retentions of dry preservative in the timber, the lower value serving to indicate the amount of preservative at which is observed the expected effect, e.g. the grow...
D A Belenkov


The probable mechanism of action of boric acid and borates as wood preservatives
1990 - IRG/WP 1450
The tetrahydroxyborate ion [B(OH)4-] acts by complexation with poly-ols and probably attacks decay fungi through extracellular substrate sequestration; intracellular substrate sequestration; enzyme inhibition; and change in membrane function. Work was carried out to investigate this further and to try to explain certain phenomena observed in the area of boron preservation. The effect of Na borate ...
J D Lloyd, D J Dickinson, R J Murphy


Marine trials with ammoniacal wood preservatives
1980 - IRG/WP 423
Ammoniacal wood preservatives have been known for many years and are considered among the best water-borne systems for protecting wood in ground contact. In recent years attention has been increasingly focussed on these preservatives because of their ability to penetrate difficult-to-treat species better than most other fixed water-borne preservatives. This is particularly important for example, i...
M A Hulme, D P Ostaff


On-site test for indicative determination of leaching of components of preservatives from treated timber
1993 - IRG/WP 93-50001-12
In the late eighties the environmental concern about treated timber increased and it is still a hot issue in the Netherlands. From the environmental point of view three phases in the timbers life cycle can be distinguished: - the production phase - the service life - the waste phase. In the Netherlands at this moment much emphasis is laid on the production phase. In 1992 this has led to a new legi...
W J Homan, H Militz


Establishing standard principles for laboratory bioassays of termiticides with subterranean termites - progress, problems and prospects
1993 - IRG/WP 93-10013
Laboratory bioassays of termiticides, including wood preservatives, aim to give an indication of the likely concentrations effective in preventing damage to timber products and other materials in the field. In laboratory bioassays field conditions should be simulated as closely as possible. With a wide range of procedures in use around the world it may often be difficult to compare results between...
M Lenz, J W Creffield, Zhong Yun-hong, L R Miller


Preservation of robinia wood (Robinia pseudoacacia L.) stakes by vintners
1982 - IRG/WP 3194
This work discusses decay resistance of robinia wood to fungi Trametes versicolor (L.ex Fr.) Pil. and Coniophora puteana (Schum. ex Fr.) Karst., and also the possibility of influencing its resistance by means of chemical protection. The results showed that natural resistance of robinia wood to these two different agents of wood decay is not the same. It is much less resistant to the fungus Conioph...
R Benko


Effect of mini-block test conditions on activity of Coniophora puteana
2000 - IRG/WP 00-20184
The influence of various factors of the mini-block test method on growth and activity of different strains of Coniophora puteana was studied. Decay rates of spruce samples in Petri dishes of different depths, at different wood fibre orientations and at various distances between growth medium and wood were compared. In deep Petri dishes, there were no significant differences between activity of the...
F Pohleven, M Petric, J Zupin


Remedial ground-line treatment of CCA poles in service. Results of chemical and microbiological analyses 6 months after treatment
1986 - IRG/WP 3388
CCA-treated poles in service with incipient internal soft rot were remedially treated by inserting borate rods, brushing with a boron/glycol solution and injecting boric acid paste, copper/creosote paste or a commercial product (DFCK paste). The spread of active chemicals in the treated zone as well as the change in microflora have been studied with time. After six months chemicals had spread to m...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Quality of timber impregnated with preservatives of class AB after three years in service
2002 - IRG/WP 02-20241
Quality of impregnated timber is most often expressed by penetration and retention of the preservative used. Relatively less information is available about the performance of the final product, e.g. decks, panels etc. regarding product’s surface checks, deformations and overall appearance. Together with the timber durability, the above mention features are of esthetical importance in the above g...
N Terziev


An Australian test of wood preservatives. Part 1: Preservatives, principles and practices
1978 - IRG/WP 2123
Between November, 1963, and July, 1964, a graveyard test of some 6000 preservative-treated stakes was installed at 8 sites equally distributed between Papua New Guinea in the tropics, through Queensland and New South Wales to Victoria. More than 40 different preservatives and preservative mixtures, mostly at several different levels of retention, were used to impregnate sawn specimens of Pinus rad...
J Beesley


Determination of ethanolamine in impregnated wood
2000 - IRG/WP 00-20198
Leaching of copper based preservatives from wood is usually prevented by adding chromium compounds to copper containing formulations. It seems that suitable substitutes for chromium fixation agents may be amines. In this paper, we report our results on interactions between copper(II) octanoate and ethanolamine (C2H7NO, 2-aminoethanole) with wood or its components. A part of ethanolamine from a woo...
M Humar, M Petric


Fungal remediation of CCA-treated wood
2004 - IRG/WP 04-50210
This study evaluates oxalic acid accumulation and bioremediation chromated copper arsenate (CCA) treated wood by three brown-rot fungi, Fomitopsis palustris, Coniophora puteana, and Laetiporus sulphureus and ten mold and staining fungi, Aspergillus niger, Aureobasidium pullulans, Gliocladium virens, Penicillium funiculosum, Rhizopus javanicus, Ceratocystis pilifera, C. peceae, Alternaria alternata...
S N Kartal, Y Imamura


Recycling of treated timber by copper smelter
1994 - IRG/WP 94-50030
A preliminary trial was carried out to see whether copper smelting process is able to recycle CCA treated timber. As a result of the first trial almost a full recovery of both copper and arsenic was achieved. Recovered metals were utilized in manufacturing CCA preservatives. The energy bound in wood is utilized in the flash smelting process and the burning gases are fed to the sulphuric acid plant...
A J Nurmi, L Lindroos


The non-uniform uptake of chromium and copper during the impregnation of wood using the example of a CCB-salt
1998 - IRG/WP 98-20137
The correct impregnation of wood requires among other things a regular control of the concentration of the treating solution as this and/or its stoichometric composition can change as a result of the impregna-tion process and the treated wood. The preferential uptake of individual wood preservative components by the wood is of particular importance in this connection. Dipping and vacuum impregnat...
P Jüngel, E Melcher, R-D Peek


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Proposals for further co-operative studies on determining toxic values against wood-destroying Basidiomycetes
1985 - IRG/WP 2247
Document IRG/WP/2194 reported the status of the programme of co-operative experiments up to and including December 1982. During discussions at IRG-13 in Turkey members endorsed the decision to complete the programme of tests and conduct repeat tests. At IRG-14 in Brisbane the report was noted but no further action agreed. At IRG-15 in Sweden a number of interested parties in the European/Scandinav...
A F Bravery


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