IRG Documents Database and Compendium


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Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


Marine trial progress report
1980 - IRG/WP 453
In May 1977 and May 1978, tests of new chemical formulations for the protection of timber in the sea were installed in Mt. Maunganui Harbour. Investigation into new preservatives for such usage was urgently required since it had been found that there was progressive leaching of copper from copper-chrome-arsenate treated marine piles which could lead to a reduction in their service life. Hochmann (...
A F Preston, C M Chittenden


Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao


Preservative treatment and field test monitoring of spruce pole stock: Pressure and diffusible chemical treatments
1990 - IRG/WP 3605
One hundred and forty four spruce (test species) and southern yellow pine (reference species) poles were variously treated by center boring, incising, or kerfing, followed by pressure treatment with CCA and/or diffusible preservatives. The diffusible preservatives included NaF/creosote, borax and ammonium bifluoride. The poles were set at a test site and evaluated for preservative distribution and...
B Goodell, A J Pendlebury


A study of the colonization of wood blocks in a laboratory unsterile soil test
1988 - IRG/WP 2318
CCA treated and untreated beech blocks were exposed to a defined horticultural loam using the method proposed for the collaborative soft rot test in the soft rot sub-group of Working Group Two. At intervals during the incubation wood samples were removed and fungal isolations were made using selective media. Fungi were identified and tested for their cellulolytic ability and their decay capacity i...
M T De Troya, S M Gray, D J Dickinson


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Discoloration of pressure impregnated wood caused by Amorphotheca resinae
1990 - IRG/WP 1438
Amorphotheca resinae Parbery with the anamorph Cladosporium resinae (Lindau) von Arx & de Vries is a cosmopolitan fungus known from aviation kerosene, hydrocarbon contaminated soil and creosoted timbers. In Denmark it causes heavy discoloration on wood treated with waterborne chromate-containing preservatives e.g. CCA-oxide type. The teleomorph produces small spherical fruitbodies widespread o...
F Rune, A P Koch


Pentachlorophenol: The non-emotional approach. Second draft: A discussion document
1995 - IRG/WP 95-50040-07
Regulations on PENTA start from a strange story. Often initiated as pure ban in certain countries to provide satisfaction to pressure groups, the increased knowledge of the toxicology has contributed to one of the best documented file concerning a substance widely used as wood preservative. The accumulated documentation on its contaminants and its potentialities as dioxin and furan precursor in ce...
G Ozanne


A laboratory technique to measure the performance of preservative treated hardwoods in ground contact
1982 - IRG/WP 2172
A laboratory technique to measure the performance of preservative treated timber in ground contact is described. It uses partially sealed blocks of timber which are treated, leached and sawn into small stakelets for soil exposure in a fungal cellar. Performance is monitored by the loss of static bending strength with time, and a simple apparatus for measuring the deflection of a stakelet under a l...
E F Baines


Effects of two wood preservatives and one water repellant on the settlement of fouling communities in a tropical marine environment
2002 - IRG/WP 02-30293
Observations made on recruitment of fouling organisms on treated panels exposed at an Indian harbour, Krishnapatnam on the east coast (Lat: 13028’ to 13059’ N; Long: 80010’ to 80016’ E) during November, 1997 to October, 1999 are reported and compared with fouling communities on control panels. Wooden panels of Erythrina variegata, Paraserianthus falcataria, Tetrameles nudiflora an...
B Tarakanadha, K S Rao


The field performance of CCA-C treated sawn refractory softwoods from North America
1997 - IRG/WP 97-40085
Approximately 15% of the total volume of wood treated in the United States consists of difficult to treat softwoods known as "refractory softwoods". The long term positive performance record of CCA treated sawn material is based upon the testing of yellow pine sapwood stakes with only limited field data available for sawn refractory softwoods. As a result, the existing North American wood preserva...
M J Richards, W S McNamara


Pentachlorophenol, its salts and esters; UK review of its uses in wood preservation and surface biocides
1995 - IRG/WP 95-50040-27
The review on pentachlorophenol was undertaken by the Health and Safety Executive on behalf of the independent Advisory Committee on Pesticides in response to the 9th Amendment to the Marketing and Use Directive. The high toxicity to man and the environment was noted and the associated risks were assessed. The Cornmittee concluded that the potential carcinogenicity was probably via a non-genotoxic...
M Fitzpatrick, C Mackie


Premature failure of treated timber in wharfs in Papua New Guinea, attributed to defects in design
1991 - IRG/WP 4158
The performance of timber in wharfs in Papua New Guinea has been monitored for a number of years. Premature failure of wharf structures was found in many cases to be due to defects in design rather than ineffective preservative treatment. Above-water timbers were found to be prone to severe checking followed by decay. Protection for the end grain of pile tops and the limiting of radial checking in...
S M Cragg


Comparative studies on the species effects of wood preservatives
1989 - IRG/WP 3521
For the examination of the resistance against fungal attack, wood blocks of 3 softwood species were treated with CCA (type 3), CFK, AAC and IF-1000 independently. The wood blocks were exposed to the fungal decay with Tyromyces palustris. The degradation of the wood blocks treated with these preservatives was quite widely different among wood species examined in this study. Hem-fir treated with CCA...
K Yamamoto, S Matsuoka


Leaching of active components from preservative-treated timber - Ongoing research: Status after approx. 4 months’ out-door exposure
2003 - IRG/WP 03-20276
The Danish Technological Institute is together with manufacturers of active ingredients and formulators of wood preservatives running a project aiming at finding realistic leaching rates from preservative treated wood in hazard class 3 (above ground). The project is focussed on developing a field trial method for investigating leaching. According to BPD hazard assessment has to be carried out f...
N Morsing


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Application of a novel strength evaluation technique during screening of wood preservatives
1986 - IRG/WP 2262
The effectiveness of CCA and ACA in treated aspen mini stakes tested using a novel bag procedure, with unsterile soil fortified with Chaetomium globosum and Ceratocystis albida, is reported. Good agreement between toxic limits determined using the standard weight loss procedure, and those determined by the strength technique were found, with some indication that the strength loss method is more se...
J N R Ruddick


Distribution of copper/chrome/boron preservative in light red meranti (Shorea leprosula) before and after exposure test for 72 months
1995 - IRG/WP 95-20073
Copper/chrome/boron (CCB) preservative at 6% w/w was impregnated into light red meranti (Shorea leprosula) by full cell process. The quantitative analysis for copper, chrome and boron contents in treated wood samples was carried out by Inductive Couple Plasma (ICP). Electron Probe Microanalyser (EPMA) was used to monitor the distribution of copper, chrome and boron in the various treated wood tiss...
S Salamah, S Ani


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 6: Report of third inspection (24 months) in Australia
1980 - IRG/WP 456
This report presents the results of the third inspection of the IRG/COIPM International Marine Test specimens installed at the Goat Island Marine Biological Station of the Maritime Services Board of New South Wales, in Sydney Harbour. The inspection was completed on 5th December, 1979, after 24 months exposure. As on previous occasions, this inspection was carried out in conformity with the provis...
J Beesley


The suitability of high pressure sap-displacement for the retention of UK grown spruce and pine
1990 - IRG/WP 3595
The concentration and radial distribution of copper, chrome, arsenic (CCA), and the moisture content and depth of radial checking in UK grown, field exposed spruce and pine poles treated by high pressure sap-displacement are examined. The concentration of CCA elements in samples obtained from increment cores is similar in Norway spruce, Scots pine and Corsican pine but is significantly lower in Si...
P D Evans, S D Hainey, A Bruce, G M Smith, B King


Why did Japan replace CCA by alternatives?
2004 - IRG/WP 04-50215
Since chromated copper arsenate (CCA) was technically introduced into Japan in 1963, CCA was used for extending service life of various wood commodities, especially sill plates (dodai) in Japanese houses. However, the problem on the disposal of CCA-treated wood waste became public and related industry concern, and questionnaire survey conducted by Japan Wood Preservers’ Industry Association ind...
H Ishida, T Ito, M Yamai, H Matsusaka, K Tsunoda


Multiple-Phase Pressure (MPP) Process: Pilot plant trials for disposal of kickback using reverse osmosis membrane filtration
2001 - IRG/WP 01-40202
The MPP Process (a one-stage CCA treatment and accelerated fixation process) generates ~ 250 litres of kickback per cubic metre of timber treated. Composition of kickback is mainly wood sugars and traces of copper, chromium and arsenic. In pilot plant scale trials, MPP process kickback was filtered through a Reverse Osmosis (RO) membrane of a type found from earlier small-scale trials to be the mo...
H Pearson, G Durbin, M E Hedley


Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals


Influence of clonal variability on the impregnability of poplar hybrids. (+ correction document of 23 April 1990)
1990 - IRG/WP 3614
The new Western European poplar clones (Populus nigra x deltoides and Populus trichocarpa x deltoides) were compared with the reference clone 'Robusta' and some old hybrids. Samples (5x5x50 cm³) with pure tangential/radial surfaces were sawn, including the transition zone between heartwood and sapwood. Treatment by a standard vacuum-pressure impregnation cycle with CCA showed a ...
J Van Acker Van, M Stevens, C De Haas


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