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Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Australian trials on the efficacy of micronized copper
2008 - IRG/WP 08-30480
Alkaline copper quat (ACQ) is an established wood preservative that is formulated with solubilised copper in amine solvent. This paper describes three separate trials in Australia that investigated whether substituting soluble copper with micronized copper affects performance. ACQ and micronized copper quat (MCQ) gave similar performance in Pinus radiata against four brown-rotting fungi in a soil-...
L J Cookson, J W Creffield, K J McCarthy, D K Scown


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


Performance of Wood Protection Systems at Multiple Field Test Sites Using the Ground Proximity Test Method
2012 - IRG/WP 12-20499
A series of preservative systems were used to treat southern pine ground proximity test samples which were then exposed at a range of test sites located throughout the world. The sites were chosen on the basis of having vastly different Scheffer Climate decay indices. After almost 14 years exposure, distinct differences are apparent in how different preservative systems perform at the different ...
A Zahora, A Preston, L Jin


KERUING and APITONG: A Timely Review of the Perfect Choice Wood Species for Crossarms and Brace Arms, Including Data on Copper Naphthenate Treatments
2012 - IRG/WP 12-40603
Apitong or the wood species more commonly known as Keruing is an important tropical hardwood known for its high strength to weight ratio and its reasonable durability and preservative treatability. This wood has been exported from managed permanent forest estates in Malaysia into the United States for over 4 decades for its widespread use in wooden utility industry brace arms and crossarms, yet cu...
A Wong, M Freeman


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


40 year results from the largest preservative in-ground stake trial conducted in Australia
2013 - IRG/WP 13-30624
The final results from Australia’s largest preservative in-ground stake trial are listed. There were eight test sites, six in Australia and two in Papua New Guinea. The preservatives tested include low and high temperature creosotes, PCP and various water-borne preservatives including CCA and copper chromate. The main timbers examined were sawn Pinus radiata sapwood, sawn Eucalyptus regnans hear...
L J Cookson


Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


Ammoniacal Copper Zinc Arsenate Preservative Treated Wood Ties Their Performance in Testing and Track
2014 - IRG/WP 14-30636
While not a new preservative system, Ammoniacal Copper Zinc Arsenate (ACZA), had not previously been used to protect crossties. Its performance in treating difficult or refractory species of wood has been documented through its wide range of uses approved in AWPA. The establishment of appropriate testing for railroad material use was put in place and includes laboratory, field as well as commercia...
T Carey


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


COPPER NAPHTHENATE: A Product for All Seasons: Protecting the Americas’ Infrastructure for Over 100 Years and Potential for Expanded Usage in Europe
2019 - IRG/WP 19-30738
This paper is a brief review of the history and use of the wood preservative Copper Naphthenate, with a focus on use patterns within the USA and opportunities for expansion in Europe and Canada. This paper reviews how copper naphthenate has performed to preserve and protect cellulosic and wooden items essential to critical infrastructure, and why it is the ideal choice for use in the replacement o...
M H Freeman, J A Brient, M Manning


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Copper-octanoate - a potential reference preservative replacement for CCA in field test standards?
2022 - IRG/WP 22-20688
Finding a CCA reference replacement for use in standardised test methods is of high priority since this chemical is being phased out and may in the near future be banned also for experimental and approval purposes. In this paper we assess the possibility to replace CCA reference preservative with an historical copper octanoate product. There is a huge amount of lab and field test data available fo...
R Ringman, M Westin, M Klamer, A Christof, F Friese


A six-year ground proximity trial of TRU-CORE treatments at Innisfail, Queensland
2023 - IRG/WP 23-30775
This article describes an H3 (above ground outdoor) ground proximity field trial that compares the performance against decay fungi of TRU-CORE (also known as the Buffered Amine Oxide Enhancement System) Copper Quat (CQ) with CCA and commodity Alkaline Copper Quat (commodity-CQ) treatments, all in Pinus radiata. The retentions achieved reflected commercial practice, where higher mean retentions are...
L Cookson


A comparison of soft rot, white rot and brown rot in CCA, CCP, CCF, CCB, TCMTB and benzalkonium chloride treated Pinus radiata IUFRO stakes, after 9-15 years exposure at five test sites in New Zealand
1991 - IRG/WP 1485
The aim of this study was to determine if decay type varies significantly between five field trial test sites of different soil type, aspect and climate in 9-15 year old, replicate CCA, CCF, CCP. CCB, TCMTB and AAC treated IUFRO stakes. A visual on-site assessment of decay type on every test stake was made and observations confirmed by microscopical examination. Regression analyses were used to de...
R N Wakeling


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 2: Report of treatment and installation in Australia
1978 - IRG/WP 440
The purpose of this test and the procedures to be followed have been fully set out in documents distributed by the International Research Group on Wood Preservation and numbered IRG/WP/414 and IRG/WP/420. The prescriptions set out in these two documents have been closely followed....
J Beesley


Performance of treated fence posts after 6 years in five test plots in the State of Sao Paulo - Brazil
1976 - IRG/WP 376
Fence posts treated with creosote, pentachlorophenol and creosote/ pentachlorophenol mixtures showed good performance after 6 years of exposure in five test plots located in the State of Sao Paulo - Brazil. Good results were also achieved with copper sulphate/sodium arsenate and copper sulphate/potassium dichromate mixtures. Fungi and termites were the main destroying agents found attacking the po...
M S Cavalcante


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