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Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The potential for using CuO nanoparticles as a wood preservative
2011 - IRG/WP 11-30569
The potential for using nano-copper particles for wood protection was investigated using mini-agar slant and wood block tests with Gloeophyllum trabeum or Trametes versicolor. Nano-copper was more effective against G. trabeum than T. versicolor, although neither of these fungi would be considered copper tolerant. Nano-copper solutions were stable over a 17 week storage period, but precipitated w...
I S Weitz, K Knani, M Maoz, C Freitag, J J Morrell


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Remediation of Pentachlorophenol (PCP) in Biodiesel versus Diesel Carriers
2011 - IRG/WP 11-50279
Biodiesel is believed to be more environmentally friendly than petroleum based diesel when used as a carrier for impregnation of PCP into wood products for protecting wood from decay. A six month study was conducted to evaluate the remediation of PCP in biodiesel versus diesel in soil. Different percentages of biodiesel, diesel and PCP were mixed with clean soil from a forested site and tested. Sa...
S Keshani Langroodi, H Borazjani, D Nicholas, L Prewitt, S V Diehl, S Kitchens


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Life Cycle Assessment Comparison of Treated Wood to Alternate Materials – Overview, Results and Lessons
2011 - IRG/WP 11-50282
Life Cycle Assessment (LCA) has proven useful in documenting the “green” benefits of various treated products compared to the commonly used alternates. To date, six LCA comparisons have been done or are nearing completion using ISO14040 and 14044 principles and data from US EPA databases. In almost all cases, the impact indicators for treated wood products show considerably smaller adverse e...
T Stephen, P E Smith, C R McIntyre


A survey on Bio-Resistance of Oak and Elm in Caspian Sea Water
2012 - IRG/WP 12-20483
Logs of Oak (Quercus castanifolia) and Elm (Zelkova carpinifolia) have been cut to lumbers with dimensions of 300×100×30 mm. The oven dried samples have been impregnated with CCA (Chrome–Cupper-Arsenic). Treated and untreated (natural as a control) woods have been established for 3, 6, 9 and 12 months in Amirabad beach of Behshare under fishing environment. The observation results shows that i...
S M Kazemi


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Performance superiority of CCA-C treated wooden jetty poles and piles used for 30 years in Bangladesh against marine borers
2012 - IRG/WP 12-30582
Observational study along with previous investigation and records revealed that chromated copper arsenate type C (CCA-C) impregnated southern pine poles and piles of jetty constructed in most vulnerable brackish water in Bangladesh are stable and resistant to attack of all types of marine borers after 30 years of use. It is evident from the service records of other construction materials that CCA-...
A K Lahiry


Effect of Biodiesel on the Efficacy of Pentachlorophenol Treated Wood
2012 - IRG/WP 12-30584
Pentachlorophenol (PCP) is widely used as a wood preservative for utility poles and other wood products. Recently, it has been proposed that a modified PCP carrier system based on a diesel/biodiesel mixture should be used in place of the conventional diesel/KB3 carrier, but there is some question as to whether or not this modified carrier system can provide the same service life for wood products ...
S Keshani Langroodi, H Borazjani, D Nicholas, L Prewitt, S V Diehl


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Mobilized copper(II) concentrations in earlywood and latewood of micronized copper treated red pine
2012 - IRG/WP 12-30596
Electron paramagnetic resonance (EPR) was used in conjunction with energy dispersive x-ray spectroscopy (EDX) to quantify total copper and mobilized copper retentions in MCQ and MCA treated red pine. The MCQ treated red pine was found to have higher copper retention than that of the MCA treated one. Earlywood in general had higher total copper content than latewood. The mobilized and complexed cop...
Wei Xue, P Kennepohl, J N R Ruddick


Environmental safeness of 60% and 72% concentrated CCA-C solution and paste for wood treatment
2012 - IRG/WP 12-50284
In this study 30-years practical and observational experience of the present author about using of 72% concentrated CCA-C paste for preparing treating solutions and for treating wooden poles, anchor logs and cross arms has revealed that the 60% concentrated CCA-C solution is superior to the 72% concentrated CCA-C paste regarding solubility, homogeneity, cleanliness, treatability, sludge formation,...
A K Lahiry


Biodegration of treated wood waste by native fungal communities of tropical soil in French Guiana
2012 - IRG/WP 12-50285
Woods have been protected with fungicides for a long time, and the effects of these fungicides on soil after being leached into the ground have turned out to be a true environmental issue. It is in this perspective that we are proposing to study fungal communities of these contaminated woods in a purpose of bioremediation. Most of precedent studies have focused on ability of some Basidiomycetes an...
A Zaremski, L Gastonguay, C Zaremski, F Chaffannel, J Beauchêne, G LeFloch


Fixation and leaching characteristics of Malaysian tropical hardwoods treated with CCA-C
2012 - IRG/WP 12-50289
The fixation and leaching characteristics of 8 Malaysian tropical hardwood (MTH) species treated with chromated copper arsenate (CCA-C) wood preservative were examined. The species evaluated were Acacia (Acacia mangium), Bintangor (Calophyllum sp.), Geronggang (Cratoxylon arborescens), Medang (Litsea sp.), Meranti rambai daun (Shorea acuminata), Putat (Planchonia sp.), Ramin (Gonystylus sp.) and S...
S Salim, S Shahomlail, Z Ashaari, Yong-Seok Choi, Gyu-Hyeok Kim


Copper naphthenate treatment for wood pols - a review and update
2012 - IRG/WP 12-30600
This paper reviews copper naphthenate (CuNap) and its utility as a treatment for wooden utility poles. One of the principal reasons that CuNap has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity. CuNap is a well-proven non-restricted use preservative, used extensively and specified for environmental reasons by ut...
J A Brient, M H Freeman


Effectiveness of CCA-C and CCB preservatives after a 30 years stake test
2012 - IRG/WP 12-30606
The objective of this experiment was to assess the durability of four pine species treated with waterborne preservatives. In order to determinate this, a stake field test, following the IUFRO (International Union of Forestry Research Organizations) recommendations, was installed at Experimental Station of Luiz Antonio (21º 32’ S and 47º 42’ W), State of São Paulo, Brazil. Species under t...
I PJankowsky, E S Lepage, C Salvela, J M Vidal, S Takeshita


A case study of investigating fungi that affect traditional Japanese shake roof with/without copper plates
2013 - IRG/WP 13-10810
A Japanese traditional shake roof is made from split logs. To keep the roof long, copper (Cu) plates are often inserted between the shakes. It has been thought that Cu elements from copper plates would flow out when a shake roof is exposed to rain and inhibit growth of wood rotting fungi. Actually there are some examples where the Cu plates seem to be effective in preventing fungal damage, but on ...
T Wada, Y Fujiwara, Y Fujii, R Kigawa


Accelerated H3 above-ground decay testing
2013 - IRG/WP 13-20520
An above-ground H3 fungal field trial was installed at two sites in Australia and one in New Zealand, as well as in two Accelerated Field Simulators. The aim was to find a method that would shorten the time required for evaluating new preservatives and protection systems. One-quarter H3 retentions were installed, as first results suitable for registration occur when these reach 70% soundness. Twel...
L J Cookson, D Page, T Singh


Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2013 - IRG/WP 13-20535
A round robin involving 15 European participants was set up in 2006. The round robin consists of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. When comparing EN 84 preconditioning (two weeks water leaching) with natural preconditioning (1 year in field, above ground) according to CEN/TS 15397, no significant difference...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, B Mazela, E Melcher, R Möller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre


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