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Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


Remediation of a site contaminated with creosote and CCA - a case study
1998 - IRG/WP 98-50101-12
Over sixty years of wood preservation activity conducted by ImpregNor at Ilseng, Norway, has caused serious contamination of the soil. High concentrations of creosote have been found at two separate sites, one in connection to the creosote wood preservation plant, and one further downstream were residues from the creosote preservation have been deposited. High levels of chromium, copper and arseni...
T Rødsand, K Hellum, H Lillemaehlum


Leaching from CCA-treated wood submerged in seawater: Effect of high loadings, and a comparison between laboratory and marine conditions
1996 - IRG/WP 96-50080
This study of leaching examined the following variables: CCA loading; marine versus laboratory exposure and length of submergence. Blocks of Pinus sylvestris were treated to a range of nominal retentions from 15 to 50 kg/m³. Each block was then divided into three cubes and all transverse faces were sealed. All cubes were allowed to fix at ambient temperature for a minimum of one week. One set of ...
R M Albuquerque, S M Cragg, J D Icely


Growth of the copper tolerant brown rot fungus Antrodia vaillantii on different substrates
1995 - IRG/WP 95-10121
In recent years the copper tolerant brown rot fungus Antrodia vaillantii caused severe damages on impregnated wood in ground contact. The pattern of decay gave the impression that impregnated wood was even more severely attacked than unimpregnated. To investigate this question more closely laboratory tests were carried out. In a "choice test" Antrodia vaillantii grew preferably towards CC-impregna...
H Leithoff, I Stephan, M-T Lenz, R-D Peek


Do CCA treated support stakes cause increased arsenic level in crops?
2003 - IRG/WP 03-50204
Trial of using CCA-C treated eucalypts stakes for supporting banana plants in Guangdong Province, China, began in 1998 and later it was expanded as a demonstration program of a joint International Tropical Timber Organization–Chinese Government timber preservation project in 2000. The greatest concern was whether the crop would be contaminated by the preservatives, arsenic in particular. Data fr...
Li Zhaobang, Su Haitao, Liang Linqing


Preservative treatment of rubber wood (Hevea brasiliensis) to increase its service life
2005 - IRG/WP 05-40320
Rubber wood (Hevea brasiliensis) possess excellent properties for interior designing, wood working and furniture making. But it is very much susceptible to sap stain and mould fungi which decreases the service life. For profitable uses , it is necessary to increase the service life of rubber wood. To protect the rubber wood from wood degrading agents, the sawn timber were treated with Borax – b...
K Akhter


Ten Year Marine Borer Exposure Trial of Chlorothalonil and Emulsified Preservatives in Australia
2003 - IRG/WP 03-30314
Results of a ten-year marine exposure trial at Townsville and Port Stephens are presented. Sawn Pinus radiata and natural round Eucalyptus obliqua specimens were treated with preservatives including creosote (HTC), pigment emulsified creosote (PEC), chlorothalonil, and the oil emulsions of CCA called PROCCA and HYCON. Basic zinc chloride treatment was also exposed at Townsville. Some of the findin...
L J Cookson, D Scown


Field fencepost test of several species treated with water-borne preservatives by rural methods
1986 - IRG/WP 3385
Fencepost field results in ground-contact treated by rural methods: immersion-diffusion and sap displacement by evaporation are analyzed. Copper-chrome-arsenic and copper-fluor-chrome preservatives were used in two concentrations. The wooden species studied were: Pinus pinaster, Eucalyptus globulus and Quercus rubra. For each of the test units decay index evolution was analyzed after five years ex...
M V Baonza Merino


Which substrate to use in a laboratory test with soft rot micro-fungi: vermiculite or unsterile soil?
1991 - IRG/WP 2372
A draft European Standard is being proposed by CEN TC 38 in which a vermiculite-burial and a soil-burial test to be carried out in succession are required. Various experiments with both procedures were set up with CCA, CC and propiconazole-formulations. The results show that vermiculite and unsterile soil yield comparable threshold values against soft rot. This poses the question of whether a two-...
A R Valcke


Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Utilization of coconut timber from north Sulawesi, Indonesia. Part 2: Treatability
1994 - IRG/WP 94-40025
Under tropical conditions coconut wood is quickly degraded by mold and blue stain fungi. Low density wood in ground contact is commonly decomposed by wood destroying fungi within a period of only a few months, higher density wood from the outer stem regions within 24 to 30 months (MOSTEIRO, CASIN, SERIBAN 1976; McQUIRE 1975). Moreover, according to McQUIRE (1975) green wood of lower density is hig...
R-D Peek


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 5: Interim report
1980 - IRG/WP 454
Wood samples (15 x 2 x 2 cm³) were treated with one copper/chrome/arsenic (CCA) and one copper/chrome/boron (CCB) preservative using the following concentrations - O, 3, 6, 10%. Treated samples of three reference wood species - Alstonia scholaris, Fagus sylvatica, Pinus sylvestris were supplied to all participants. Additional local species were chosen by participants and included in the test at t...
R A Eaton


Fixation of CCA preservatives in cocos-, oil- and rattan-palm
1986 - IRG/WP 3371
In previous tests with jubaea-palm almost no fixation of a CCA-preservative Type B could be achieved, consequently, further leaching tests were carried out with samples of 1 cocos-, 1 oil- and 2 rattan-palms from Malaysia. A good fixation of chromium and copper took place in cocos-palm after 4 weeks storage at 28°C. Nevertheless the fixation was slower than in pine-wood and demanded an elevated t...
H Willeitner, K Brandt


The efficacy of polymer/preservative treatments in soil-bed exposure
1992 - IRG/WP 92-3729
Southern pine was treated with CCA, CCB, sodium borax/boric acid, or disodiumoctaborate, alone or in combination with an acrylic polymer system containing a water repellent. Treated samples were subjected to an unsterile soil burial test. The addition of polymer reduced the weight loss in borontreated samples at the lower retentions but not at the higher retention. Results with borates indicate th...
R J Murphy, H M Barnes, S M Gray


The evaluation of a survey of dry rot damages in Japan
1983 - IRG/WP 1179
The damage of wooden houses from Serpula lacrymans has increased in Japan, particularly in the northern area, Hokkaido Prefecture (See Figure 1). The weather conditions in Asahikawa have been recorded. The data obtained from the survey carried out over the five years from 1975 to 1980 were previously reported to the 5th International Biodeterioration Symposium which was held in Aberdeen, Scotland ...
S Doi


Environmental consequences of various materials in utility poles - A life cycle analysis
1992 - IRG/WP 92-3726
A model for environmental life cycle analysis, LCA, has been created to compare environmental impact from transmission poles, made alternatively of concrete, steel, aluminium and pine wood treated with CCA type B or creosote. The main pollution sources and energy use are included in the LCA. One pole size, 12 meters long, is presented in the study, a so called "45 kV" pole. Poles of different mate...
M Erlandsson, K Ödeen, M-L Edlund


Weathering of copper-amine treated wood
2000 - IRG/WP 00-40155
Copper ethanolamine (Cu-EA) treated southern pine (SP) were artificially weathered with a QUV Weathering Tester. The weathering regime was composed of a continuous UV-light irradiation for 2 hours followed by a water spray for 18 minutes for a total time of 1200 hours. The changes on the surface of the weathered samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis,...
J Zhang, D P Kamdem


Effect of a water repellent additive on the performance of ACQ treated decks
2000 - IRG/WP 00-40168
The performance of a water repellent (WR) additive formulated for use with ACQ has been evaluated. The water repellency of wood treated with this formulation was studied in laboratory and field tests. The change in moisture content of ACQ/WR treated boards under field exposure conditions is compared with that of CCA/WR treated boards. Although the water repellency of the ACQ/WR system is lower tha...
F Cui, A R Zahora


Sediment toxicity study of marine piles treated with CCA-C
1995 - IRG/WP 95-50040-35
A study was undertaken to demonstrate the effects of 10-day exposure to sediments mixed with leachate from chromated copper arsenate Type-C (CCA-C) southern pine marine piles treated to a retention of 40 kg/m³ (2.5 pcf) and untreated southern pine piles on the benthic amphipod, Ampelisca abdita. The biological endpoint used to establish effects was organism survival. Leachate obtained during a 28...
W J Baldwin, E A Pasek, P D Osborne


A possible role of unique TCA cycles in wood-rotting basidiomycetes
2003 - IRG/WP 03-10461
The copper tolerant brown-rot fungus, Fomitopsis palustris, acquires metabolic energy by use of the constitutively-occurring Kornberg’s glyoxylate cycle coordinating with oxalate biosynthesis and glucose oxidation (Erman Munir et al. Proc. Natl. Acad. Sci. USA, (2001) 98, 11126-11130). Furthermore, this fungus does not have the normal TCA cycle, lacking 2-oxoglutarate dehydrogenase which is a ke...
E Munir, T Hattori, M Shimada


Effectiveness of wood preservatives by IUFRO's method
1984 - IRG/WP 3305
Pinus elliottii and Eucalyptus saligna stakes treated with 4.9; 6.9; 9.6 and 13.5 kg/m³ of CCA-A, CCA-C and CCB and with 30-50; 60-80; 90-110 and 120-140 kg/m³ of Benzotar and CNSL (cashew-nut shell liquid) were exposed in seven test sites in Sao Paulo State, Brazil. After 4 years it was concluded that the mean useful life of untreated Pinus elliottii stakes was 8 months and of untreated Eucalyp...
G A C Lopez, E S Lepage, O B Neto


Oxidation of wood components during CCA-C fixation
1993 - IRG/WP 93-30024
Pre-extracted radial sections of southern yellow pine sapwood were treated with CCA-C and analyzed by X-ray photoelectron spectroscopy (XPS). The ratio of C1 (carbon bonded to carbon and/or hydrogen) to C2 (carbon bonded to one oxygen) in XPS Cls spectra was taken as a measure of the progress of oxidation of wood components during CCA fixation. This ratio was 0.82 before CCA treatment and increase...
M Kaldas, P A Cooper


Use of compression strength loss for measuring decay in the soil block test
1996 - IRG/WP 96-20083
The possibility of using radial direction compression strength of wood, rather than mass loss, was evaluated for both a brown-rot fungus (Gloeophyllum trabeum) and white-rot fungus (Trametes versicolor). With untreated pine wafers (5 x 19 x 19 mm³ - l x r x t) exposed to Gloeophyllum trabeum in a soil block test for five days, the compression strength loss was nearly 50% compared to a 5% mass los...
D D Nicholas, Zhongwei Jin


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 19: Report on the condition of specimens at Sekondi, Ghana after 42 months
1984 - IRG/WP 4109
The results of the first formal inspeation of CCA- and CCB- treated test panels exposed at Sekondi, Ghana, in June 1980, are presented. All untreated control panels of both reference and local species have been destroyed. Of the% CCA- treated specimens, only those of Pinus sylvestris (reference species) and Mitragyna stipulosa (local species) have not been attacked. 3% CCB-treated local species ha...
F F K Ampong


Microwave treatment to Accelerated fixation of copper-ethanolamine (Cu-EA) treated wood
2004 - IRG/WP 04-40271
This study evaluated the use of microwave post-treatment to accelerate fixation of copper-ethanolamine (Cu-EA) treated 19 mm southern yellow pine sapwood cubes. Cubes were pressure treated at 3.2 and 6.4 kg/m3 Cu retention target, after which they were microwave post treated during different duration periods. An accelerated AWPA leaching test was conducted during 300 hours to determine the amount...
Jinzhen Cao, D P Kamdem


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