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Copper Naphthenate – A Data and Capability Update
2022 - IRG/WP 22-30771
The efficacy of copper naphthenate against wood decay fungi and wood destroying organisms has been well documented from international field tests as well as decades of commercial service. The use of copper naphthenate has been dramatically expanded due to its proven performance, non-restricted use, minimal environmental impact, and superior end of life options. Extensive demand and interest has al...
J-W Kim, J D Lloyd


Comparative study of the properties of silicate coatings with different mineral pigments (titanium dioxide, iron (III) oxide, copper (II) oxide) on the surface of wood
2022 - IRG/WP 22-40936
Silicate coatings are attractive alternatives to conventional organic-based coatings for wood protection. In this work, silicate coatings were prepared with a potassium silicate binder modified with a methyl siliconate solution, and three types of mineral pigments titanium dioxide, iron (III) oxide and copper (II) oxide. The coatings were applied on beech wood and cured under ambient conditions. T...
A M Cheumani Yona, M Petrič


Glued laminated poles - Progress report after 43 years of testing
2023 - IRG/WP 23-20692
In 1979, a number of glued laminated poles treated with CCA and creosote were placed in a greenhouse in Uppsala, in the Simlångsdalen test field in south-western Sweden and in a power lane in Vuollerim in northern Sweden, in order to study their resistance against biological degradation. The test poles were treated in a two-step process. All laminations of Scots pine (Pinus sylvestris) were first...
J Jermer, M Westin, N Terziev


Virtual Reality of Wood Protection
2023 - IRG/WP 23-20698
Virtual reality (VR) is a technology that allows people to explore and interact with computer generated environments using devices that stimulate different senses (sight, sound and touch). VR is mainly used for education, training and entertainment, but it also has the potential to provide new insights into scientific phenomena. In this paper we describe the evolution of VR and its many uses, focu...
D Feng, Y Liu, M Turner, A Limaye, P D Evans


Sensitivity of copper indicators for detecting preservative penetration
2023 - IRG/WP 23-20701
Chrome azurol S (CAS), 1-(2-pyridylazo)-2-naphthol (PAN), and rubeanic acid (RA) are the three copper indicators currently used by the timber industry to assess preservative penetration. Although only the American Wood Protection Association (AWPA) standards specify indicator sensitivity, it is unclear how those limits were developed. The sensitivity of each copper indicator was determined in solu...
T Yi, J Norton, S Meldrum, J J Morrell


Outdoor performance of Tanalith® K treated timber: Dimensional stability and corrosivity towards metal fasteners
2023 - IRG/WP 23-30798
This study was carried out to investigate dimensional stability and corrosivity towards metal fasteners in radiata pine (Pinus radiata D. Don) treated with Tanalith® K to Hazard class 4 (H4) retentions in comparison with chromated copper arsenic (CCA) treated timber. For corrosion test, untreated and treated matched specimens were prepared from Australian-grown radiata pine, tested with mild stee...
G Rassam, J Hague, D Humphrey


Multi-scale Experimental Study on Self-sustained Smouldering of CCA-treated Timber Poles
2023 - IRG/WP 23-40988
While it is accepted that appropriate treatment with chromated copper arsenate (CCA) will extend the design life of wood markedly, there are concerns regarding the effect of treatment on fire performance. Smouldering combustion in CCA-treated timber infrastructure can self-sustain, destroying the timber elements, as the chromium and copper present in the CCA can act as catalysts of the smouldering...
W Wu, L Yerman, J J Morrell, F Wiesner


X-ray fluorescence microscopy of copper ion distribution in decay of copper-treated wood by Fibroporia radiculosa
2024 - IRG/WP 24-11047
Copper is an essential metal ion for eukaryotic life and must strictly be regulated as excess levels can cause oxidative damage, enzyme inhibition and denaturation, interruptions in nutrient transport and even cellular death. Copper-based wood treatments have efficacy against a wide range of biological organisms including decay fungi and are used in the majority of preservative formulations for ou...
K M Ohno, J Jakes, A B Bishell, L Li, Q Jin, E Maxey


X-ray micro-computed tomography of copper distribution in CA, ACQ and MCA treated wood and changes in microstructure of ACQ-treated southern pine following natural weathering
2024 - IRG/WP 24-20707
We hypothesized that X-ray micro-CT would be able to visualize: (a) the distribution of copper in CA-treated southern pine; and (b) microstructural changes in ACQ-treated southern pine exposed to natural weathering. Small blocks were removed from southern pine samples treated with CA and also southern pine treated with ACQ and MCA. Small blocks were also removed from ACQ-treated boards (flat and p...
D Feng, M Turner, P D Evans


Benefits of borate dual treatment
2024 - IRG/WP 24-20710
Treatment of railroad ties with borate followed by over-treatment with creosote or copper naphthenate, called dual treatment, has become standard practice for ties being installed in higher decay hazard areas of the U.S. This paper provides an overview of why that has happened. Borate preservative presents very low human health and environmental risk. It diffuses through even hard to treat hear...
S T Smith, J D Lloyd, S McKinney


Comparison of copper leaching from alkaline copper quat and copper compound nanosol-based wood preservative treated wood
2024 - IRG/WP 24-20726
To improve the leaching resistance of copper ion-based wood preservatives, copper compound nanosol-based wood preservatives were developed and its copper leaching characteristics were evaluated. Three types of preservatives (DC1, DC2, DC3) were prepared with different crystallinity and dispersant types of copper compound nanosol, and the copper concentration was adjusted to be the same as that of ...
Y-S Choi, S-M Yoon, J O Kim, J-G Kang, J-G Park


Virtual reality of wood protection
2024 - IRG/WP 24-20727
Virtual reality (VR) is a technology that allows people to explore and interact with computer generated environments using devices that stimulate different senses (sight, sound and touch). VR is mainly used for education, training and entertainment, but it also has the potential to provide new insights into scientific phenomena. We describe our work on the use of VR as a learning tool for students...
D Feng, Y Liu, M Turner, A Limaye, P D Evans


A new wood preservative system based on basic copper compound nanosols
2024 - IRG/WP 24-20728
A bottom-up process was established to synthesize insoluble basic copper compound nanoparticles and simultaneously form a stable nanosol by dropping a neutralizing agent solution into an aqueous solution of a copper compound to which an appropriate dispersant system was added. The main ingredient of MCA (Micronized Copper Azole), the leading copper-based wood preservative in the current world mark...
J O Kim, J-G Kang, Y-S Choi, S-M Yoon, H-M Lee, J-G Park


Leaching and chemical redistribution of CCA components in refractory heartwood of E. nitens
2024 - IRG/WP 24-41011
Chromated Copper Arsenate (CCA) is a wood preservative widely used to protect against fungal and insect attack. The fixation mechanism of CCA involves complex chemical reactions, including the reduction of chromium (VI) to chromium (III) and the formation of insoluble complexes. Despite fixation efforts, a portion of CCA components tends to leach from treated wood, influenced by factors like wood ...
J R Vargas, L Yermán, K C Wood, T Singh


Keeping wood greenest: Maximizing the unique benefits of preserved wood through end-of-life planning to realize carbon sequestration and a circular economy
2024 - IRG/WP 24-50387
While competitive fuels and different energy sources are a main driver of current difficulties with using end-of-life wood products for fuel, that is a potentially smaller problem than the rapidly changing carbon footprints of competitive materials, which can potentially be smaller than wood, if the wrong decisions are made at the end of life by users and waste generators. While users have several...
J D Lloyd, B Poe


Copper migration from preservative-treated Douglas-fir decking: models vs laboratory leaching data
2024 - IRG/WP 24-50390
The ability of a model to predict copper migration from Douglas-fir treated with organic metallic substances into a freshwater slough was evaluated against data generated through simulated overhead leaching. The model predicted very high loadings of ammoniacal copper zinc arsenate, alkaline copper quaternary or copper azole that had the potential to impact water quality while data from the exper...
M J Konkler, G Presley, J J Morrell, T Singh


Quantifying metal migration from a deck constructed with copper-azole-treated lumber
2024 - IRG/WP 24-50391
Soluble copper or micronized copper wood preservatives are the most common available wood preservative systems for residential applications in the United States. Copper containing wood preservatives have been scrutinized for their potential negative impacts on the environment, across many jurisdictions. Concerns arise from the potential for preservatives to migrate out of treated wood upon water e...
G Presley, M Konkler


Quantitative assessment of wood preservative emissions to waterways
2024 - IRG/WP 24-50393
The Organisation for Economic Co-operation and Development (OECD) Emission Scenario Document (ESD) for Wood Preservatives provides methods to quantify the release of active substances from treated wood for various scenarios including sheet pilings in a flowing waterway (OECD 2013). The ESD is used for environmental risk assessment of wood preservatives according to the Biocidal Products Regulation...
K J Rader, R Carbonaro, C Mackie


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