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Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Chemical composition and performances of slow pyrolysis by-product from sugarcane bagasse for wood protection
2020 - IRG/WP 20-30752
Pyrolysis distillate or bio-oil, a by-product of biomasses’ slow pyrolysis in the char-making process, has been traditionally used as bio-pesticides by Asian farmers. Due to its large composition of bio-active chemicals, bio-oil obtained from various biomass has become of interest in many applications, including wood protectants. This study aims to characterize the chemical composition of bio-oi...
F D Boer, M-F Thévenon, J-M Commandre, M Fournier


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Evaluation of chemical densification of three hardwood species through in-situ electron beam polymerization
2020 - IRG/WP 20-40893
Hardwoods are the most suitable species for wood flooring for their appearance as well as their hardness. Yet, improving hardness can provide substantial benefit for the wood flooring market. Chemical densification of wood and in-situ polymerization through electron beam technology was chosen to increase hardness of three hardwoods (Yellow birch (YB) (Betula alleghaniensis Britt.), Sugar maple (SM...
J Triquet, P Blanchet, V Landry


Comprehensive protection of timber in seawater
2020 - IRG/WP 20-10970
The hazard of wood in seawater can be divided into two areas: Below the water level, shipworm (Teredo navalis) and gribble (Limnoria lignorum) can attack non-resistant or insufficiently protected wood; above the water level, there is a risk by wood-destroying fungi and, to a lesser extent, insects. In a national project funded by the Deutsche Bundesstiftung Umwelt (DBU, German Federal Environmenta...
E Melcher, J Müller, T Huckfeldt


The influence of chemical compounds on wood cell wall to surface cracks
2020 - IRG/WP 20-40908
Degradation due to cracking and dimensional changes caused by drying, have a significantly negative impact on the preservation and durability of wood. Therefore, the prevention of surface cracking, which tends to occur during the drying process, is vital. High temperature set drying is one of the most effective methods for preventing wood surface cracking. It begins with softening the wood at a hi...
R Suzuki, Y Mori, K Yoshihiro, K Yamashita, M Kiguchi


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


Chemical composition of agarwood of Aquilaria crassna Pierre ex. Lecomte induced by Basidiomycetes from French Guiana
2022 - IRG/WP 22-10988
Aquilaria trees subjected to stress induce the formation of a transformed wood named agarwood. The formation of agarwood is a plant defense mechanism that occur in complex interactions with environmental microorganisms. Agarwood chemical compounds are mainly chromones and oxygenated sesquiterpenes such as eudesmol, agarospirol, jinkoh-eremol and valerianol, which are valued in perfumery. Its deriv...
C Zaremski, M Ducousso, C Andary, G Michaloud, C Menut, A Zaremski, N Amusant


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Surface chemical wood densification through in situ electron beam polymerization: description and dose study
2022 - IRG/WP 22-40933
Traditional wood chemical densification processes can be used to improve wood mechanical properties by increasing density of the material throughout its thickness. While mechanical surface densification has heavily been investigated, surface treatments involving impregnation of monomers remain unexplored. This study describes a new material, surface densified through lateral impregnation of acryla...
J Triquet, P Blanchet, V Landry


Chemical modification of cellulose nanofibrils for tailoring properties of composites
2022 - IRG/WP 22-40934
Due to its natural abundance, complete biodegradability and excellent properties, cellulose is one of the most promising materials for the production of bio composites, as well as one of the most promising fillers for biodegradable polymer composites. This is also true for nanocellulose. A large number of hydroxyl groups on the surface of fibers or fibrils enables a whole series of chemical reacti...
I Poljanšek, J Levanič, V Ž Bogataj, V Vek, P Oven


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


The influence of chemical and thermal modification on homogeneity between sapwood, heartwood, and transition wood of short rotation teak
2023 - IRG/WP 23-40961
Short rotation teak wood has low quality especially in durability. Heartwood presents sufficient natural durability and poor impregnability; meanwhile, most sapwood requires special treatment to increase its durability. The objective of this work was to investigate the effect of thermal or chemical treatment on homogenization between sapwood, heartwood, and transition wood for some selected proper...
R Martha, B George, W Darmawan, P Gerardin


The impact of pre-drying on treatment level variations of esterified solid wood analysed by X-ray densitometry
2023 - IRG/WP 23-40977
Wood modification requires homogenous treatment levels within the wood matrix to prevent insufficiently treated areas being subject to biodeterioration. Esterification of wood by citric acid and sorbitol can show differences in density caused by uneven chemical distribution during the curing phase and can be detected by x-ray densitometry. This study used density profiling to investigate the influ...
A Treu, S O Amiandamhem, E Larnoy


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


Studies on the treatability of selected pine species and corresponding efficacies of a new non-biocidal treatment
2024 - IRG/WP 24-20721
Wood decay caused by fungi may reduce the service life of wood in outdoor applications. Since moisture conditions in wood occur as one of the most crucial parameters for fungal decay, chemical modifications, which affect the latter, may increase the resistance of wood against such organisms. Usually, pine sapwood is easier to chemically treat than heartwood, as the former generally shows good perm...
T R da Silva Lins, L Emmerich, H Militz, P H Gonzales de Cademartoni, R J Klizke, M Pereira da Rocha


Physical, durability and chemical characterization of Gmelina arborea (Roxb.) wood treated with lactic acid
2024 - IRG/WP 24-30803
The increase in demand for durable wood has drawn attention to the use of fast-grown plantation species across the globe. Chemical modification was used to treat Gmelina arborea wood with lactic acid for property enhancement. The treated samples were obtained from two different ages of 15 and 10 years and sawn into (20 x 20 x 60) mm and (20 x 20 x 20) mm for physical, durability and chemical chara...
T O Akinwamide, J M Owoyemib, E A Iyiolac


Leaching and chemical redistribution of CCA components in refractory heartwood of E. nitens
2024 - IRG/WP 24-41011
Chromated Copper Arsenate (CCA) is a wood preservative widely used to protect against fungal and insect attack. The fixation mechanism of CCA involves complex chemical reactions, including the reduction of chromium (VI) to chromium (III) and the formation of insoluble complexes. Despite fixation efforts, a portion of CCA components tends to leach from treated wood, influenced by factors like wood ...
J R Vargas, L Yermán, K C Wood, T Singh


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