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Multilayer hot-press drying and chemical modifying of poplar wood with urea-formaldehyde prepolymer
2011 - IRG/WP 10-40539
The objective of this study was to determine the technology of chemical modifying and multilayer hot-press drying on poplar wood. The chemicals were impregnated into cell lumen space by pulse-dipping machine to improve the dimension stability and mechanical property of timber. The timbers were compressed and dried by the multilayer hot-press drying to increase the density of timber. Results indica...
Guofeng Wu, Yifei Jiang, Sheng Yao, Junwen


Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


Slice - Cut and Analyze Laser Microdissection (LMD): A method to produce sample material from modified wood for chemical quality analysis
2011 - IRG/WP 11-20478
Wood modification with its various systems is an established way to enhance a wood products’ service life in outdoor applications. Per definition, selected material properties are enhanced by means of modification without producing toxic substances or residues during service life and combustion afterwards. The systems of impregnation modification include a physical and often chemical alteration ...
K Zimmer, E Larnøy, A Treu, M Fongen


Phytosanitary standards and the potential for acceptance of chemical treatments as a phytosanitary measure
2011 - IRG/WP 11-30558
Regulations governing international trade in forest products must balance the economic and social benefits of trade with the potential risks of transporting invasive species. The International Plant Protection Convention (IPPC) is an international agreement intended to manage this process. It develops international phytosanitary standards (ISPMs) that are recognised by the World Trade Organisation...
A Uzunovic, R Stirling, J J Morrell, P I Morris, C F Schauwecker


Connecting fungal genomic variations to wood chemical composition: A way to understand the adaptation of wood decaying fungi
2012 - IRG/WP 12-10776
The development of new sequencing methods allows now exploring the detoxication systems of wood-decaying fungi. These systems, called xenome, are mainly composed of oxidative enzymes (phase I) and of conjugation enzymes (phase II). These enzymes belong to superfamilies, which are extended in the plant cell-wall interacting fungi. From different approaches coupling in particular comparative genomic...
E Gelhaye, Y Mathieu, E Meux, A Thuillier, M Mélanie


Micromorphological and chemical characteristics of waterlogged archaeological bamboos excavated from the Yellow Sea
2012 - IRG/WP 12-10785
Bamboos have widely used as documentation material in Far Eastern countries such China, Korea and Japan. In particular, bamboo slips as documentation material were extensively used even after the wide spread of paper in those countries. A large number of bamboo slips have been excavated from the shipwreck since 2009 in Korea. Understanding the cause of deterioration of ancient bamboos is crucial f...
Mi Young Cha, Yoon Soo Kim


Chemical Analysis of Hydrothermally Treated Beech Wood in Buffered Mediums
2012 - IRG/WP 12-40604
Hydrothermal treatment of beech wood in buffered mediums was carried out to study the effect of different mediums of heat treatment on crystallinity index of treated specimens due to degradation of carbohydrates. Different mediums (water, buffer5, 7 and 8) and temperatures (160 and 180 °C) were used. ATR spectra focusing on indexes of carbohydrates degradation obtained and analyzed. Results showe...
A Talaei, A Karimi


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Seed oil and defatted cake proximate composition of non timber product Annona squamosa (Annonaceae) grown in Benin
2012 - IRG/WP 12-30607
Annona squamosa L. is a small tree which grows wild in many places in the tropical regions, locally called “xwingle” in Benin. Its produces edible fruits, typically globular or heart-shaped which are highly appreciated and the seeds are not used. In the course of work about identifying new oil sources from a large number of oil bearing seeds grown in Benin, we report here on the chemical compo...
T S Djenontin, J Dangou, P Lozano, D Pioch, D C K Sohounhloue


Cell wall properties of softwood deteriorated by fungi: combined chemical analyses, FT-IR spectroscopy, nanoindentation and micromechanical modelling
2013 - IRG/WP 13-20527
Mechanical properties of wood are determined by its inherent hierarchical microstructure, starting at the nanometer scale, where the elementary components cellulose, hemicelluloses, and lignin build up the wood cell wall material. Fungi cause degradation and decomposition of these components and, thus, alter the mechanical properties of wood. The aim of this study is to gain new insight into these...
L Wagner, T K Bader, K de Borst, T Ters, K Fackler


Effect of the nature of the inert atmosphere used during thermal treatment on chemical composition, decay durability and mechanical properties of wood
2013 - IRG/WP 13-40625
Wood heat treatment is an attractive alternative to improve decay resistance of low natural durability wood species. Nowadays, several types of thermal treatments of wood exist. These treatments differ mainly by the nature of the inert atmosphere used to avoid wood combustion which may correspond to: nitrogen, vacuum, steam or oil. Decay resistances as well as mechanical properties are strongly co...
K Candelier, S Dumarçay, A Pétrissans, M Pétrissans, P Gérardin


Study of UV resistance and natural weathering of coatings on chemically modified wood
2013 - IRG/WP 13-40629
In this study, UV resistance and weathering performance of rubberwood (Hevea brasiliensis) and radiata pine (Pinus radiata) modified with benzoyl chloride and acetic anhydride was studied. Performance of polyurethane based wood coatings on modified wood was also evaluated. Unmodified and chemically modified specimens were exposed to accelerated and natural weathering. Modified and unmodified woo...
K K Pandey, K Srinivas


Characterization of wood modification prepared by in situ polymerization with pre-polymer and the mechanism of modification
2013 - IRG/WP 13-40633
Chemical modification of wood is a potential way to obtain high quality wood. In this study, the fast-growing poplar was impregnated with modifier using a pulse-dipping machine by in situ polymerization. Fungal decay analysis, mechanical properties and dimension stability of the natural and modified woods were investigated. The wood samples were also characterized by X-ray diffraction (XRD) Therma...
Qian Lang, Zeng Bi, Junwen Pu


Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher


The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison


Changes in mechanical and chemical properties of wood exposed outdoors
2014 - IRG/WP 14-20550
The aim of this study was to investigate differences in certain mechanical and chemical properties of three different wood species (common beach (Fagus sylvatica), Norway spruce (Picea abies), and copper-ethanolamine (CuE) impregnated Norway spruce (Picea abies)) that were exposed in use class 3 (CEN, 2006) for periods between 4 and 30 months. The results show, that changes in the investigated me...
N Thaler, C Brischke, D Žlindra, V Vek, M Humar


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Resistance to Decay Fungi of Scots Pine Impregnated with Natural and Chemical Preservatives
2014 - IRG/WP 14-30650
In this study, heart-wood and sap-wood specimens of the Scots pine which is naturally grown in Turkey were treated with natural (valex) and some chemical preservatives such as CCA - C (Copper / Chrome / Arsenic), CBA - A (Copper / Boron / Azole). The wood protective efficacies of these preservatives were investigated by means of fungi decay test (EN 113). As a result of the study it was found t...
S Yildiz, U B Şimşek


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Chemical composition of extractives of different wood compartments of Pinus merkusii and their potential implication in wood durability
2015 - IRG/WP 15-10841
Amounts and nature of extractives differ strongly according to the compartment of wood and to the nature of the wood species. Previous studies reported that knotwood of several European Pinus sp. contains extractives contents much higher than stemwood consisting mainly of lignans which may find valuable applications in cosmetic, nutraceutic or pharmaceutic sectors. Different explanations have been...
A Wijayanto, S Dumarçay, R Kartika Sari, W Syafii, P Gérardin, C Gérardin-Charbonnier


Durability of Fence Posts of Four Wood Species After 20 Years in Field Test
2015 - IRG/WP 15-30670
In the past years, wood consumption from native forests has drastically reduced the availability of wood. Fast-growing species such as Pinus and Eucalyptus suitably impregnated with chemicals may show a service life equal or higher than hardwood with high natural durability. The field tests have been an alternative widely used to evaluate the durability of wood and the efficiency of preservatives....
A Florian da Costa, A C Salgado de Freitas, E Meneses Oliveira


How intraspecific radial variability of the European Oak’s may influence mild pyrolysis process and durability of the material
2016 - IRG/WP 16-40725
Last decades wood is promoted as building material. Unprotected wood exposed to outdoor conditions undergoes a variety of degradation induced essentially by fungi attacks. Heat treatment of wood by mild pyrolysis (180°C T 240°C under inert atmosphere) is a preservation process with a weak environmental impact, and therefore, is viewed as an interesting alternative to the chemical impregnation me...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


Optimising wood chemical modification with lactic acid oligomers by screening of processing conditions and chemical additives
2016 - IRG/WP 16-40741
Oligomer systems based on lactic acid (OLA), were impregnated in wood and polymerised in-situ by heat treatment to improve the properties of the treated wood especially regarding anti-swelling efficiency (ASE), hygroscopicity, water leaching resistance and durability. This article relates the optimisation of the heat treatment conditions and the consideration of selected chemicals for improvement ...
C Grosse, M-F Thévenon, M Noël, P Gérardin


Exterior birch plywood: potentiality of the thermo-hydro treatment
2016 - IRG/WP 16-40743
It has been found in the present study that, in laboratory fungi tests after leaching with water (EN 84), exterior birch (Betula spp.) plywood, as birch solid wood, is subjected to degradation by rot fungi. This limits the use of such plywood outdoors or in building structures in high humidity conditions. The possibility to improve the birch plywood fungal resistance was investigated in two ways: ...
B Andersons, I Andersone, A Meija-Feldmane, I Irbe, A Janberga, J Grinins


Chemical, physical-mechanical characterization and durability of thermally modified beech and ash wood by thermo-vacuum process (Termovuoto)
2016 - IRG/WP 16-40758
The paper illustrates part of the results from the CIP Eco-innovation project “Thermo-vacuum: new process for new generation of thermally modified wood”. The project is part of the 7th Framework Programme for European Research and Technological Development, and thermo-vacuum modified wood is already on the European market. The project was selected by the European Commission, EASME Agency, as "...
M Jebrane, I Cuccui, O Allegretti, N Terziev


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