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Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali


Laboratory and above ground exposure efficacy of silicon-boron treatments
2009 - IRG/WP 09-30510
The study deals with silicon compounds, namely tetraethoxysilane (TEOS), phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) at concentrations of 23, 16 and 10% in combination with 1.2-1.5% boric acid. The aim with the study was to combine the chemical approach with the necessary biological tests of the impregnated wood. The tested silicon-boron combinations ensured mass loss less than ...
N Terziev, D Panov, A Temiz, S Palanti, E Feci, G Daniel


Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect. Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans


Modification of Wood by a Water-Repellent Compound Used in the Textile Industry: Boron Release and Termite Resistance
2009 - IRG/WP 09-40447
In the study, wood specimens were treated with disodium octoborate tetrahydrate (DOT) and a commercial water and oil repellent compound, FORGUARD M®, a weak cationic emulsion containing dipropylene glycol monomethylether, water and solids in its formulation and used in the textile industry. There were two different processes for preservative treatments: double and single treatments. The leaching ...
S N Kartal, E Terzi, B Erilkun, Y Imamura


Wettability and bonding strength of wood thermally-treated with different combinations of soy oil and chemical additives
2009 - IRG/WP 09-40454
Thermal treatment is a method which has gained wider acceptability as an alternative to the chemical treatment in wood preservation. In order to maximize the benefits of this technique several options have been adopted including the use of soy oil in transferring the heat to the wood. Available information on thermal treatment in general and the oil method in particular show that there are still n...
L Awoyemi, P A Cooper, T Ung


Investigation of chemical changes in acetylated beech wood during weathering
2009 - IRG/WP 09-40460
In this study Beech wood (Fagus orientalis) acetylated and has been subjected to a variety of artificial weathering conditions (water only, light only, water and light together)in difference times (0,50,150 and 300 h), then wood surface analyzed using Fourier Transform Infrared spectroscopy (FTIR).Results shown that weathering process affected the functional groups on the wood surface. Light and w...
M Akhtari, M Arefkhani


The effect of chemical changes on the wood-moisture relationships in thermally-modified wood
2009 - IRG/WP 09-40473
Small specimens of three wood species were thermally modified following twenty schedules in the 190-245°C temperature range for treatment times between 0.3 and 16 h. Five wood-moisture relations were subsequently determined, namely: anti-swelling efficiency (ASE), movement, hygroscopicity (adsorption and desorption), transversal swelling (radial and tangential directions), and equilibrium moistur...
M M González-Peña, M D C Hale


Chemical mediated depolymerization of cotton cellulose for the understanding of non-enzymatic fungal decay
2010 - IRG/WP 10-10731
Small, low molecular weight non-enzymatic compounds have been linked to the early stages of brown rot decay as the enzymes involved with holocellulose degradation are found to be too large to penetrate the S3 layer of intact wood cells. The most pronounced of these which were analyzed in this study are hydrogen peroxide, iron, and oxalic. The compounds related to the Fenton reaction: the combinati...
A C Steenkjær Hastrup, B Jensen, F Green III


Assessment of Boracol 200RH (FrameSaver) as a remedial treatment to control decay in pre-decayed model timber frame units
2010 - IRG/WP 10-30529
Model timber frame units constructed from untreated radiata pine were pre-wetted to approximately 40% moisture content and inoculated with Coniophora puteana and Oligoporus placenta. Units were transferred to a controlled environment room maintained at 25°C and 95% RH for 7 and 10 weeks to allow two levels of decay to become established in units. Following pre-decay, units were disassembled, clea...
Mick Hedley, Dave Page, Jackie van der Waals


Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su


Chemical protection of historic timber structures: Results and future needs
2010 - IRG/WP 10-40487
The paper concentrates on the analysis of the effectiveness of chemical protection for timber structures in the Russian State Museums “Kizhi” (Karelia) and “Vitoslavlitsy” (Novgorod). The condition of historic timber was tested at the monuments treated with PCP, borax, potassium carbonate, boric acid, Pinotex chemicals in the 1970-80. Long-term analysis revealed that in many cases the...
M Kisternaya, V Kozlov


Study on the thickness swelling of mould-resistant chemical treated bamboo strand woven outdoor flooring
2010 - IRG/WP 10-40489
To prevent bamboo strand woven flooring from mould, several preservatives were chosen to treat bamboo strand before dipping into adhesives and pressing. The thickness swelling and mould resistant effect of the finished board were studied. Results showed that different preservatives had different influences on the thickness swelling of BSWF, and in order to reduce the thickness swelling of the fini...
Fangli Sun, Binfu Bao, Shenyuan Fu, Anliang Chen


Chapter 7 - Treatment processes of bamboo
2010 - IRG/WP 07-10635-07
For adequate penetration and retention of preservatives in woody bamboos at green, dry, solid and sliced conditions different possible and applied treatment processes have been described along with their classifications. The treated bamboo can be used as building materials; the sufficient treatability ensures its long-term best utilization at ground contact and indoor. All the processes descr...
A K Lahiry


Multilayer hot-press drying and chemical modifying of poplar wood with urea-formaldehyde prepolymer
2011 - IRG/WP 10-40539
The objective of this study was to determine the technology of chemical modifying and multilayer hot-press drying on poplar wood. The chemicals were impregnated into cell lumen space by pulse-dipping machine to improve the dimension stability and mechanical property of timber. The timbers were compressed and dried by the multilayer hot-press drying to increase the density of timber. Results indica...
Guofeng Wu, Yifei Jiang, Sheng Yao, Junwen


Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


Slice - Cut and Analyze Laser Microdissection (LMD): A method to produce sample material from modified wood for chemical quality analysis
2011 - IRG/WP 11-20478
Wood modification with its various systems is an established way to enhance a wood products’ service life in outdoor applications. Per definition, selected material properties are enhanced by means of modification without producing toxic substances or residues during service life and combustion afterwards. The systems of impregnation modification include a physical and often chemical alteration ...
K Zimmer, E Larnøy, A Treu, M Fongen


Novel Approaches to the Development and Testing of Anti After-glow Additives for CCA-based Treatments of Poles
2011 - IRG/WP 11-30561
In this paper, a field fire stake testing screen method is described. This method uses stake samples from matched wood sources allowing replicates from different boards to be included. The method is easy to control and can provide quick comparative fire resistance test results. The parameters measured from the tests are percentage weight loss, minimum residual circumference and residual thicknes...
L Jin, P Walcheski, A Preston


Connecting fungal genomic variations to wood chemical composition: A way to understand the adaptation of wood decaying fungi
2012 - IRG/WP 12-10776
The development of new sequencing methods allows now exploring the detoxication systems of wood-decaying fungi. These systems, called xenome, are mainly composed of oxidative enzymes (phase I) and of conjugation enzymes (phase II). These enzymes belong to superfamilies, which are extended in the plant cell-wall interacting fungi. From different approaches coupling in particular comparative genomic...
E Gelhaye, Y Mathieu, E Meux, A Thuillier, M Mélanie


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


Micromorphological and chemical characteristics of waterlogged archaeological bamboos excavated from the Yellow Sea
2012 - IRG/WP 12-10785
Bamboos have widely used as documentation material in Far Eastern countries such China, Korea and Japan. In particular, bamboo slips as documentation material were extensively used even after the wide spread of paper in those countries. A large number of bamboo slips have been excavated from the shipwreck since 2009 in Korea. Understanding the cause of deterioration of ancient bamboos is crucial f...
Mi Young Cha, Yoon Soo Kim


KERUING and APITONG: A Timely Review of the Perfect Choice Wood Species for Crossarms and Brace Arms, Including Data on Copper Naphthenate Treatments
2012 - IRG/WP 12-40603
Apitong or the wood species more commonly known as Keruing is an important tropical hardwood known for its high strength to weight ratio and its reasonable durability and preservative treatability. This wood has been exported from managed permanent forest estates in Malaysia into the United States for over 4 decades for its widespread use in wooden utility industry brace arms and crossarms, yet cu...
A Wong, M Freeman


Chemical Analysis of Hydrothermally Treated Beech Wood in Buffered Mediums
2012 - IRG/WP 12-40604
Hydrothermal treatment of beech wood in buffered mediums was carried out to study the effect of different mediums of heat treatment on crystallinity index of treated specimens due to degradation of carbohydrates. Different mediums (water, buffer5, 7 and 8) and temperatures (160 and 180 °C) were used. ATR spectra focusing on indexes of carbohydrates degradation obtained and analyzed. Results showe...
A Talaei, A Karimi


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Seed oil and defatted cake proximate composition of non timber product Annona squamosa (Annonaceae) grown in Benin
2012 - IRG/WP 12-30607
Annona squamosa L. is a small tree which grows wild in many places in the tropical regions, locally called “xwingle” in Benin. Its produces edible fruits, typically globular or heart-shaped which are highly appreciated and the seeds are not used. In the course of work about identifying new oil sources from a large number of oil bearing seeds grown in Benin, we report here on the chemical compo...
T S Djenontin, J Dangou, P Lozano, D Pioch, D C K Sohounhloue


An assessment of soft rot in preservative-treated poles in two test sites and two network areas in New South Wales
2013 - IRG/WP 13-10801
This document presents an extended summary of recent investigations into soft rot attack of preservative treated power poles from the re-inspection of samples selected from two field sites and two in-service trials located in New South Wales, Australia. The in-ground sapwood of selected poles was assessed by probing and, after core sampling, by microscopy to determine the severity and extent of s...
W D Gardner, M A Powell, C Kirton


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