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Chemical Remediation of Beech Condensates
2004 - IRG/WP 04-50221
In the present work, The beech wood condensate are subsequently separated from the aqueous phase. Experimental results reveal the electrostatic interaction between the oppositely charged wood extracts after oxidation and Ca(OH)2. The influence of parameters such as pH, oxidation were studied. The increase in aqueous phase pH resulted in enhanced removal of wood extracts from water. The effect of p...
M Irmouli, J P Haluk


Premature failure of CCA treated vineyard posts from brown rot
1993 - IRG/WP 93-10016
A survey of CCA (AWPA Type C) treated posts used as grape vine trellis supports, to determine the extent and type of decay was carried out at a terraced vineyard in the Hawkes Bay region of the North Island of New Zealand. Of 357 posts examined out of a total of 970 in the vineyard, 47% had moderate to severe decay or had failed, 20% had established decay, 10% had a trace of decay and 23% had no s...
R N Wakeling, A P Singh


Relationship between degradation of wood, cellulose or lignin-related compounds and production of hydroxyl radical or accumulation of oxalic acid in cultures of brown-rot fungi
1994 - IRG/WP 94-10062
The degradation activities of brown rot fungi against wood, cellulose, and lignin-related compounds were measured in cultures containing glucose or wood as a carbon source. Also the activities of one-electron oxidation and hydroxyl radical production and the amount of oxalic acid present in the cultures were measured. The degradation activities of the fungi against wood, crystalline cellulose and ...
S Itakura, T Hirano, H Tanaka, A Enoki


The remaining concentration of inorganic wood preservative components in EN 252 stakes after ground contact
2000 - IRG/WP 00-50159
In order to determine the biological efficiency and the remaining concentration of different inorganic and organic active ingredients during service, EN 252 specimens were impregnated with 3 copper based wood preservatives. The stakes were installed in the test field of the DESOWAG GmbH, Rheinberg, for at least 7 years. At the end of the field test some of these stakes were divided into 10 uniform...
E Melcher, H-W Wegen


The role of oxidation in wood degradation by brown-rot fung
1992 - IRG/WP 92-1562
Brown-rot fungi are suggested to degrade cellulose by oxidation with hydrogen radicalsformed eg. in the conversion of hydrogen peroxide in the Fenton type reactions. The stuctural changes in the holocellulose in wood induced by Fenton's reaction on wood components are very similar to those caused by brown-rot fungi. In this work the effect of the Fenton reaction on wood components was stu...
A-C Ritschkoff, J Pere, J Buchert, L Viikari


A bioassay for appraising preservative protection of wood above ground
1978 - IRG/WP 2124
A bioassay, using the mold fungus Aspergillus niger, gave results that were correlated with amounts of pentachlorophenol and tributyltin oxide in pine sapwood treated with solutions ranging in strength from 0.016 or below to 5%. Limited bioassay estimates of penta in commercially treated millwork corresponded to estimates by lime ignition. The assay fungus exhibited somewhat greater tolerance of t...
T C Scheffer, L Gollob


Improvement of intrinsic properties of wood by chemical wood densification - Hydrophobic aspects and durability aspects
1999 - IRG/WP 99-40149
To improve the intrinsic properties of Scot pine wood ((1) hydrophobic surface and (2) durability), two ways of chemical modification have been tested. The first one is the chemical modification of hydroxyl groups by active substances like diisocyanate compounds with a copolymerization step. The second way is a densification by an impregnation of resins and a gamma polymerisation. This second way ...
G Labat, Q K Tran, I Le Bayon


Effect of some resin treatments on fungal degradation reactions
1999 - IRG/WP 99-10318
The effect of impregnation of wood with vegetable oil, tall oil and two water soluble on fungal degradation reactions was assessed by hydrolysis and enzyme activity measurements. The experiments were carried out by using isolated enzyme preparations and a living brown-rot fungus Poria placenta. The results indicate that the inhibitory effect of treatments was clearly directec towards the enzymatic...
A-C Ritschkoff, M Rättö, A J Nurmi, H Kokko, A O Rapp, H Militz


Resistance of acetylated wood to biological degradation. Evaluation of field test
1997 - IRG/WP 97-30139
Acetylated wood samples were tested in ground contact (stake test) at two test fields, one in Simlångsdalen, Sweden, and one in Viikki, Finland, according to European standard EN 252. The test samples were inspected annually and their condition was compared with that of untreated controls and of samples treated with two reference CCA preservatives. The use of untreated controls and preservative t...
P Larsson Brelid, R Simonson, Ö Bergman


Cytoplasmic and extracellular localization of manganese II dependent peroxidase(s) in white rot fungi during degradation of woody materials
1989 - IRG/WP 1416
The manner by which lignin is degraded in-situ in natural substrates by white rot fungi still remains a controversial issue particularly the distribution and role(s) played by lignin degrading enzymes (i.e. manganese II peroxidase and lignin peroxidase). In the present study, use was made of anti-manganese II peroxidase and immunolabelling techniques in conjunction with transmission electron micro...
G F Daniel, B Pettersson, T Nilsson, J Volc


Antifeedant activities of flavonoids and their related compounds against the subterranean termite, Coptotermes formosanus Shiraki
1999 - IRG/WP 99-10305
Antifeedant activities of some flavonoids and their related compounds against the subterranean termite, Coptotermes formosanus Shiraki were examined with no-choice and two-choice tests. The activities of these compounds were considered in relation to their chemical structures. All flavonoids tested showed antifeedant activities whereas catechinic acid without A-ring and pyran ring in the molecule ...
W Ohmura, S Doi, M Aoyama, S Ohara


Tunnelling bacteria
1983 - IRG/WP 1186
The micromorphology of decay in wood caused by a certain group of single-cell bacteria, called tunnelling bacteria (TB), is described. TB are characterised by their tunnelling ability within the secondary cell walls of wood fibres. Pure cultures of TB have not yet been obtained although the typical decay patterns can be reproduced using mixed bacterial cultures. Some indications of lignin degradin...
T Nilsson, G F Daniel


Wood kiln drying. Simple process of material treament or soft method of preservation? (Le séchage arificiel du bois. Simple opération de traitement du metériau ou méthode douce de préservation?)
1993 - IRG/WP 93-50001-14
Among the processes enabling to extend wood durability, kiln drying can be considered as a treatment and soft preservation method. Dry woods are naturally durable provided they are not subject to important retaking of the moisture. Drying thanks to the application of temperatures from 50 to120°C enable to execute a thermic treatment which kills grubs and mushrooms to ensure a sterilization that c...
F More-Chevalier


The identification of organic compounds in wood using thermal desorption GC-MS - possibilities and limitations
2001 - IRG/WP 01-20224
There is a clear need for the analytical characterisation and identification of organic compounds and their derivatives in different phases especially in timber. In this context the paper describes a rapid and powerful gas chromatographic method for the determination of insecticides, biocides and "other" organic substances in treated and/or modified wood. The main advantage of this procedure is th...
P Jüngel, E Melcher


Differences in pH, electrical resistance, cation composition and NIR spectra of red spruce wood during early stages of brown rot degradation
2002 - IRG/WP 02-10449
Red spruce sapwood was exposed to degradation by the brown rot fungi Coniophora puteana, Postia placenta, Gloeophyllum trabeum and Serpula lacrymans for 0, 1, 2 or 3 weeks using a modified soil block assay design. Average weight losses over time ranged from 0-8.9% during this time period. Detectable changes in pH, electrical resistance and cation compostion were observed in the wood as early as 1 ...
J Jellison, S Kelley, B Goodell, D Hui, A Ostrofsky


Tebuconazole - A new triazole fungicide for wood preservation
1990 - IRG/WP 3629
The main cause of economic damage to timber and millwork worldwide are Basidiomycetes (brown and white rot). After testing a wide range of triazole derivatives for their effectiveness against decay fungi, Tebuconazole, a triazole compound, was selected. The physico-chemical, toxicological and ecotoxicological data of this substance are described. Tebuconazole is unleachable, light-stable, heat-sta...
R Gründlinger, O Exner


Microbial decay in an extremely durable Malaysian hardwood Belian (Eusideroxylon zwageri) - an overview
1997 - IRG/WP 97-10216
The heartwood of Belian (Eusideroxylon zwageri) is highly regarded among the naturally durable Malaysian hardwoods, and is therefore a choice timber for soilcontact use in the humid tropics such as untreated telecommunication poles, fence posts and railway sleepers. The high microbial resistance of the wood is evidenced by the mere superficial degradation observed in some pole samples after 20 yea...
A H H Wong, A P Singh


Assessing the importance of degradation mechanisms on the loss of effectiveness of wood preservatives
2000 - IRG/WP 00-20193
Accelerated ageing systems developed for application to samples in the laboratory prior to biological tests, should reflect those natural deterioration processes that are likely to occur in the hazard classes defined in EN 335-1. Losses through evaporation or the effects of leaching have been recognised, however their importance, relative to other mechanisms has not been quantified. Degradation me...
E D Suttie, R J Orsler, T Dearling


The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Bacterial degradation of Pinus radiata compression wood
1996 - IRG/WP 96-10153
An inspection of twelve year old, CCA-treated Pinus radiata wood from an industrial cooling tower showed extensive surface decay of wood. Electron microscopic examination of decaying compression wood indicated that compression wood cells were attacked exclusively by bacteria, which were of erosion and tunnelling types. As compared to the normal wood, compression wood appeared to be more resistance...
A P Singh, R N Wakeling


Controlled envelope treatments of Pinus sapwood, achieved by modifications to impregnation process and carrier solvents
2003 - IRG/WP 03-40258
Specimens of slash pine or radiata pine were treated to a target retention of 0.02% m/m permethrin with conventional light organic solvent fluids or with oil-modified fluids (Tanalith® T). Best achievable envelopes from LOSP fluids were poorly controlled, penetrating not only the target outer 0-5 mm zone (mean 0.019%, RSD 28%), but also breaking through into the 5-10 mm zone (mean 0.013%, RSD 37%...
M J Kennedy, P R S Cobham


Properties of cellulose degraded by the brown rot fungus, Postia placenta
1988 - IRG/WP 1350
To gain further understanding of the nature of the cellulose depolymerizing agent or agents of brown-rot fungi, brown-rotted cellulose was chemically and physically characterized. Various culture conditions, such as low nitrogen and elevated oxygen levels, did not induce degradation of cellulose by Postia placenta in liquid cultures. Therefore, brown-rotted cellulose for analysis was prepared by a...
T L Highley, R E Ibach, T K Kirk


Targeted inhibition of wood decay fungi: degradation of cotton cellulose
1999 - IRG/WP 99-10321
Brown-rot decay is responsible for 80% of the damage and replacement of wood in service. For nearly thirty years, researchers have postulated a one-electron oxidase system combining Fe+2 oxalic acid, and H2O2 in the production of hydroxy radicals which ultimately oxidize cellulose in situ. Recently, researchers have been investigating antioxicants, in combination with biocides (Schultz, et al.,199...
F Green III, T A Kuster


IPBC - A new fungicide for wood protection
1984 - IRG/WP 3295
3-iodo-2-propynyl butyl carbamate (IPBC) is presented as a potential low toxic alternative to pentachlorophenol and the sodium chlorophenoxides. Data on its effect against basidiomycetes is shown. Tests according to both the European standard method, EN-113, and American, ASTM D-413, have shown its potential. The chemical gives protection against both the wood destroying fungi, blue stain, mould and algae. It is possible to have it formulated in both water-based and organic solvent-based products. Treatment of wood out of ground contact (vac-vac products, pretreatment products, primers, stains, etc.) and sapstain control are some of the most potential end use areas within wood protection. Besides wood protection, the IPBC is used as a fungicide in paint, adhesives, caulks and sealants, cement, leather, paper, cutting oil, ink and in different roofing materials.
J Hansen


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


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