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Alternative technologies for wood wastes recycling - Part B: Biotreatment of PCP- and creosote-treated wood
1998 - IRG/WP 98-50101-18 b
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
S Legay, P Marchal, G Labat


Chemical analyses of IRG/COIPM INTERNATIONAL MARINE TEST (to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water) samples
1987 - IRG/WP 4114
Chemical analysis of CCA and CCB treated timber was carried out after exposure at tropical and temperate marine sites. Results indicated that losses of all elements had occurred. In particular, losses of boron were severe. Arsenic and copper were also lost. The chromium components in both formulations was the most dominant metal remaining. The results suggest that chromium modification was importa...
L E Leightley


A potential anti-sapstain chemical for sawmills
1984 - IRG/WP 3300
Several biocidal formulations were tested under laboratory conditions in order to discover an alternative antisapstain chemical to chlorophenoxides. The formulations tested were experimental water solutions containing a quaternary ammonium chloride, a commercial fungicide and/or a sodium salt of some carboxylic acids. The effect of sodium carbonate and borax decahydrate in mixture with a quaternar...
I A Linderborg


Ultrastructure of degraded, CCA-treated Pinus radiata wood from a marine pile
1990 - IRG/WP 1461
During an inspection of marine piles, 12 years after installation, severe degradation was noted on one of them in the vicinity of a corroded eye-bolt. The wood was dark brown in colour and tended to crumble easily. Wood fragments were examined by light microscopy and scanning and transmission electron microscopy and were also analysed for carbohydrates and lignin. Light microscopy showed numerous ...
A P Singh, M E Hedley


Chemical Analysis of Southern Pine Pole Stubs Thirty-Nine Months Following Treatment with Three Methylisothiocyanate-Based Fumigants
2004 - IRG/WP 04-30349
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC-based fumigants, liquid metham sodi...
R J Ziobro, J Fomenko, D J Herdman, J Guzzetta, T Pope


The chemical analysis and biological evaluation of wood extractives as potential timber preservatives
1995 - IRG/WP 95-30090
Work involved the biological performance of water and organic solvent soluble extractives of four naturally durable wood species, namely; Matumi, Tamboti, Sneezewood and the Turpentine tree. These timber species are known to be naturally durable against termites and fungi (±25 to 35 years). The extractives were evaluated against termites and fungi using impregnated pine pencil stakes in field tes...
P Turner, D Conradie


Photo-discoloration and Degradation of Wood and its Stabilisation by Modification with Benzoyl Chloride
2004 - IRG/WP 04-40274
Photo degradation of Pinus roxburghii (chir pine) and Hevea brasiliensis (rubber wood) was studied under artificial accelerated weathering conditions in a Xenon test chamber. The irradiated samples were analyzed for color changes and chemical changes. Analysis of colour changes in wood surfaces by UV-Vis. irradiation was carried out using a colour measuring (CIELAB) system and chemical changes ...
K K Pandey


Chemical, physical and biological factors affecting wood decomposition in forest soils
2003 - IRG/WP 03-20281
Organic matter (OM) decomposition is an important variable in determining the potential of forest soils to sequester atmospheric CO2. Studies using OM from a particular location gives site-specific decomposition information, but differences in OM type and quality make it difficult to compare results among soils and forest ecosystems. By using a “standard” OM in decomposition studies, OM qual...
M Jurgensen, P Laks, D Reed, A Collins, D Page-Dumroese, D Crawford


Kinetic of the wood degradation produced by wood decay fung
1993 - IRG/WP 93-20016
The degradation degree of a wooden structure has a direct influence on its loss of mechanical strength. It's necessary to deepen in non destructive techniques which permit to extrapolate the results obtained in laboratory to structural timber used in the building's construction. This work studies the relationship existing between the pulse velocity of ultrasonic waves and the wei...
M T De Troya, A M Navarrete, A Sanchez, V Bucur


Degradation of the gelatinous-layer in aspen and rubber wood by the blue stain fungus Lasiodiplodia theobromae
1996 - IRG/WP 96-10168
Studies on the degradative ability of the blue stain fungus Lasiodiplodia theobromae Pat. have shown several strains to cause significant weight losses (i.e. ca 20%) in the temperate and tropical wood species, aspen (Populus tremula) and rubber wood (Hevea brasiliensis). In addition to the consumption of soluble carbohydrates and extractives, major changes in the ultrastructure of fibre cell walls...
O Encinas, G F Daniel


Study of the degradation of retified wood through ultrasonic and gravimetric techniques
1994 - IRG/WP 94-40030
One of the non-polluting processes that increase the natural durability of wood is a thermal treatment in an atmosphere poor in oxygen, producing what is normally denominated "retified wood". In this study the validity of a non-destructive technique (ultrasound) in order to determine the biodegradation suffered by wood across time has been studied. For this reason, the behavior of a wood species (...
D T De Troya, A M Navarrete


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Identification of terminal structures in cellulose degraded by the brown-rot fungus Postia placenta
1989 - IRG/WP 1389
To gain insight into the biochemical mechanism employed by brown-rot fungi to depolymerize cellulose, we identified the end-groups of chemically pure cellulose that had been depolymerized by the brown-rot fungus, Postia placenta. The depolymerized cellulose was acid hydrolyzed and the anion fractions isolated by ion chromatography. Sugar acids were identified by gas chromatographic and mass spectr...
T K Kirk, T L Highley, R E Ibach, M D Mozuch


Evaluation of chlorpyrifos as an insecticidal component of a wood preservative
1984 - IRG/WP 3301
After two years of laboratory and field testing, chlorpyrifos is showing excellent potential as an insecticidal treatment to wood. In laboratory termite tests, retentions as low as 1-2 parts-per-million or approximately 0.0008 kg/m³ (0.00005 lbs/ft³) are effective against the Coptotermes formosanus. Laboratory leaching tests have shown no significant effect on the concentration of the retained c...
K Rose, J Kozuma, P Sparrow


Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


The case for non-chemical termite barriers in termite control
1989 - IRG/WP 1381
A brief outline of current non-chemical barriers in subterranean termite control and their use in Australia is presented. Recent use of non-chemical barriers in Hawaii has led to their evaluation in termite control here and elsewhere. In Australia, preliminary laboratory and field experiments have shown similar results to those found against Coptotermes formosanus in Hawaii, namely, Australian Cop...
J R J French


Changed permeability and surface properties of hornbeam wood due to its degradation by erosive strain of Phanerochaete chrysosporium
2004 - IRG/WP 04-40290
Specimens of hornbeam wood were submitted to a medium-term degradations by erosive fungus Phanerochaete chrysosporium. Biodegradations of specimens resulted in their apparent structural alterations, changes in permeability and increased intensity of interactions with polar liquids. Modified physical properties of biodegraded wood may significantly influence its penetration with polar media and che...
R Solár, S Kurjatko, L Reinprecht, M Mamon, V Vacek


Microscopical analysis of formaldehyde-acid modified wood
1981 - IRG/WP 3182
Cross-linking of wood with gaseous formaldehyde improves its hygroscopic and dimensional behaviour, and its resistance against micro-organisms. However, formaldehyde cross-linking reactions take place only in the presence of an acid catalyst, which results in losses in mechanical By optimization of a formaldehyde-sulfur dioxide vapour phase process the reaction conditions were established to limit...
M Stevens, N Parameswaran


Enzyme systems of bacterial isolates from ponded logs - Potentials of pectin and/or starch degradation
2000 - IRG/WP 00-10378
This paper deals with the degradation potentials of wood constituents by the bacterial isolates from ponded logs. The potentials to degrade pectin as a constituent of pit-tori as well as starch existing in ray parenchyma cells in the areas of sap- and transition wood with the isolates were examined. The pectinase activity was investigated by means of the degradation degree of a carrot strip used a...
S Doi, S Ohta


Moisture uptake and volumetric swelling as probable factors also affecting leaching in CCA-treated wood. A preliminary study of treated Eucalyptus saligna sapwood
2003 - IRG/WP 03-30318 IRG/WP 03-30318
A number of factors affecting leaching of CCA from treated wood have been variously investigated and discussed. However, the possible effects of moisture movement in treated timbers on leaching have not received attention yet. The present study examines and compares moisture uptake and volumetric swelling in CCA-treated and untreated sapwood of Eucalyptus saligna, and tries to establish a correl...
R Venkatasamy


The chemical nature of bis(tributyltin) oxide in Pinus sylvestris sapwood
1989 - IRG/WP 3508
Tributyltin compounds have been used for many years as wood preservatives. This study has provided, for the first time, an explanation for the previously reported dealkylation and/or volatilisation of the tributyltin species in, and from, Scots pine (Pinus sylvestris) sapwood. Thus, 119 Sn nuclear magnetic resonance studies have shown that, on impregnation into this timber, bis(tributyltin) oxide ...
S J Blunden, R Hill


The effect of hemicellulose degradation on the mechanical properties of wood during brown rot decay
2001 - IRG/WP 01-20219
Incipient decay of wood by brown rot fungi causes measurable strength losses in wood before measurable weight loss occurs. Previous studies have shown that the high levels of strength loss that occur during incipient brown rot decay may be related to loss in hemicellulose. This paper investigates the effect of decay on hemicellulose composition and the relationship to the mechanical properties of ...
S F Curling, C A Clausen, J E Winandy


Improving the weather resistance of glue-laminated jarrah and karri
1994 - IRG/WP 94-40017
Surface modification and dimensional stabilisation significantly increased the dry and wet shear strength of karri and jarrah lap-shear specimens (laminates) bonded with resorcinol formaldehyde. The combination of surface modification (sanding/sodium hydroxide treatment), and furfurylation produced the highest dry and wet shear strengths. Acetylated laminates had the lowest dry bond strength, but ...
J Balfas, P D Evans


Evidence for wood cell wall degradation by the blue stain fungus Botryodiplodia theobromae Pat
1994 - IRG/WP 94-10077
Botryodiplodia theobromae Pat., a world wide ubiquitous polyfagus sapstain fungus, was found able to destroy the cell walls of birch fibres (Betula verrucosa Ehrh.) but not Caribbean (Pinus caribaea var. hondurensis Barr. and Golf.) and Scots pine (Pinus sylvestris L.) tracheids. The fungus caused characteristic erosion of fibre cell walls similar to soft rot type 2; destruction of the S1 - S2 int...
O Encinas, G F Daniel


An evaluation of chemical treatments for the protection of radiata pine logs from fungal degrade
1986 - IRG/WP 3377
Busan 30, Busan 1009, Mitrol PQ375. and sodium pentachlorophenoxide (NaPCP) plus have been evaluated as antisapstain treatments for the long-term protection of debarked radiata pine logs. After 3 months' winter-spring storage, treated debarked logs had less surface and internal sapstain than 'control' logs. After 6 months' storage all logs had internal sapstain ...
J A Drysdale, M E Hedley, J A Butcher


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