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Investigation of new wood preservation formulations based on synergies between antioxidant, 2-HPNO and Propiconazole
2006 - IRG/WP 06-30401
Wood degradation by fungi is a complex phenomenon taking place in part through oxidative reactions involving many oxidizing agents like free radicals and hydroperoxide. In order to develop novel and more environmentally benign preservative systems, mixtures of Propiconazole and antioxidants with different stabilization mechanisms were investigated to detect possible synergies allowing to reduce th...
B Bakhsous, S Dumarçay, E Gelhaye, P Gérardin


Copper borate for the protection of engineered wood products
2006 - IRG/WP 06-40334
Copper borate was evaluated for use in protecting oriented strand board (OSB) from mould, decay, and termites. Aspen OSB bonded with either phenolic or isocyanate resin was treated with several formulations of copper borate at various loadings from 0.26 to 4 percent by weight. These panels were then tested to determine the impact of the preservative on mechanical properties as well as resistance ...
R Smart, W Wall


The Effect of Flavonoids on Colour and Spectral Changes of the Wood Surface Caused by Heat Treatment or Ultra-violet Irradiation
2006 - IRG/WP 06-40341
Both heat treatment and UV irradiation can cause discolouration and change in the spectral properties of wood surface. Some of the characteristic flavonols have significant role on colour and spectral changes, despite of their relative small quantities in wood. Colour changes and spectral properties of natural and extracted black locust (Robinia pseudoacacia L.) and poplar (Populus nigra L.) were...
R Csonka-Rákosa, L Molnár-Hamvas, E Börcsök, J Molnár, K Németh


Phenol oxidase activity and one-electron oxidation activity in wood degradation by soft-rot deuteromycetes
2007 - IRG/WP 07-10615
Wood degradation, one-electron oxidation activity as assayed by ethylene generation from 2-keto-4-thiomethylbutyric acid (KTBA), and phenol oxidase activity were measured in cultures of six deuteromyce fungi, with glucose or wood as the carbon source. The four fungi that degraded Japanese beech wood had higher one-electron oxidation activities in wood-containing cultures than in glucose-containing...
H Tanaka, M Yamakawa, S Itakura, A Enoki


Gypsum effects on ‘dry rot’ wood degradation as a function of environment
2007 - IRG/WP 07-10624
‘Dry rot’ fungi are a unique group of brown rot fungi that can degrade wood away from ground contact where other fungi fail to colonize. Successfully occupying this niche is partially due to efficient water and nutrient transport, but mobilizing elements, notably calcium (Ca) and iron (Fe), from adjacent building materials has also been implicated in their success. Here we report a series of t...
J Schilling, J Jellison


Effect of fungal attack on maximum load capacity of simulated wall assemblies
2007 - IRG/WP 07-20363
The effects of moisture intrusion and fungal attack on the maximum load capacity of nailed assemblies was investigated using one white and one brown rot fungus against 4 material combinations over a 20 week period. Wetting significantly reduced the maximum load capacity of all four material combinations, while wetting and autoclaving only affected the OSB sheathing/spruce stud. The white rot fung...
N Melencion, J J Morrell


Photo-degradation of modified and non-modified wood, coated with water borne acrylic coatings during artificial light exposure
2007 - IRG/WP 07-30416
A series of experiments were carried out to investigate photo-degradation of thermally modified (at 210oC and – 0.9 bars for two hours) and non-modified spruce wood (Picea abies L (Karst)), coated with transparent and semitransparent (with 3% pigment content) acrylic coatings during artificial UV light irradiation for 200 hours. Photo-degradation was evaluated in terms of colour changes througho...
M Deka, M Tomažic, M Petric


Comparative study between full cell and passive impregnation method of wood preservation for laser incised Douglas-fir lumber
2007 - IRG/WP 07-40359
Many wood species are highly resistant to conventional pressure treatment. To improve the chemical impregnation into Douglas-fir (Pseudotsuga menziesii Franco) lumber, the passive impregnation method had been developed. In this study, ability of the passive impregnation for lumber was compared with a conventional full cell method. Square Douglas-fir lumber with the incising density of 10,000 holes...
Md N Islam, K Ando, H Yamauchi, Y Kobayashi, N Hattori


Effect of wood polymers degradation during heat treatment on extracellular enzymatic activities involved in beech degradation by Trametes versicolor
2008 - IRG/WP 08-40392
Effect of heat treatment on extracellular enzymes involved in wood degradation by Trametes versicolor was investigated. Heat-treated and untreated beech blocks were exposed to T. versicolor on malt agar medium and extracellular enzymatic activities investigated. A strong ABTS oxidizing activity has been detected during the first stage of colonization in both cases, while cellulase activities are m...
S Lekounougou, G Nguila Inari, M Pétrissans, S Dumarçay, J P Jacquot, E Gelhaye, P Gérardin


Heat treatment, thermal treatment, thermal degradation of wood, carbon nanotubes and Damascus steel swords. What do they all have in common?
2008 - IRG/WP 08-40399
Thermal degradation of wood is a well known phenomenon. Yet heat-treatment of wood can also provide protection for wood against certain environmental hazards. This paper explores some of the aspects of thermal degradation of wood fiber at relatively low temperatures with a surprising result. Carbon nanotubes (CNTs) were produced when a specific heating regime was used to carbonize the wood fiber. ...
Xinfeng Xie, B Goodell, Yuhui Qian, G Daniel


Radial flow of Bornmullerian fir (Abies bornmulleriana Mattf.) as affected by wood tapering and the condition of end wall structure of uniseriate ray parenchyma cells
2008 - IRG/WP 08-40441
Amenability to radial permeability of Bornmullerian fir (Abies bornmulleriana Mattf.) was studied on the base of the effects of wood tapering and the structure of end walls of uniseriate ray parenchyma cells. The results showed that the most remarkable culprits of the greatest fluid uptake (as the percentage of void volume filled by the fluid in the radial flow direction, RVVF%) are the lesser woo...
I Usta, S Aslan


Degradation of polychlorinated organic biocides by the wood decaying fungi
2008 - IRG/WP 08-50253
Organochlorine biocides such as lindane, pentachlorophenol sodium salt, and polychlorinated biphenyl 153 have been widely used as wood preservatives. Due to their low degradability by soil bacteria, treated waste wood products pose a serious threat to the environment. Consequently, there is an increased need for development of new strategies for their detoxification. In this work, the bioremediati...
I Vidic, L Zupancic-Kralj, K Sepcic, F Pohleven


Comparison of permeability at different levels of moisture content in Bornmullerian fir (Abies bornmulleriana Mattf.) and Eastern spruce (Picea orientalis L.) impregnated under vacuum/pressure through full-cell method by using CCA and CCB of different concentrations
2007 - IRG/WP 07-40366
In this study, a comparison has been made in terms of the combined, longitudinal, tangential, and radial permeability of the species of Bornmullerian fir (Abies bornmulleriana Mattf.) and Eastern spruce (Picea orientalis L.) with moisture contents of 50 % and 15 %, which were impregnated under vacuum/pressure through full-cell method by using water-borne wood preservatives (impregnation materials)...
I Usta


Antinomic natural self-protection mechanism in long-lasting woods: a case study with three tropical species from French Guiana
2009 - IRG/WP 09-10696
We demonstrate in this work through 3 examples that Amazonian trees may specialize long-lasting woods by means of at least to different approaches. Wallaba impregnates its wood with large amounts of weakly antifungal compounds acting in synergy, while tatajuba and louro vermelho woods are naturally impregnated with antifungal agents. Comparison of biological activities in vitro and concentrations ...
A Rodrigues, M Royer, N Amusant, J Beauchêne, G Herbette, V Eparvier, A Thibaut, L Salmen Espíndola, B Thibaut, D Stien


The involvement of hydroxyl-radical-producing glycoprotein from the white-rot basidiomycete Ceriporiopsis subvermispora in wood decay
2009 - IRG/WP 09-10688
White-rot decay can be divided into two subtypes. One type involves the simultaneous degradation of all wood components through the formation of erosion troughs with a progressive thinning of wood cell walls. This type of decay is consistent with a model in which several polymer-degrading enzymes act on the exposed surfaces of the wood cell walls, producing progressive erosion from the lumen to th...
H Tanaka, Y Inoue, T Morikawa, S Itakura, A Enoki


SEM-EDXA of CCA-treated Rubberwood (Hevea brasiliensis)
2009 - IRG/WP 09-20399
The microdistribution of chromated copper arsenate (CCA) preservative in rubberwood was studied using scanning electron microscope in conjunction with energy dispersive X-ray analyzer (SEM-EDXA). Bulk X-ray analysis showed that there was a high accumulation of chromium, copper, and arsenic in the vessels and lower concentration of the three preservative elements in fibres. Chromium appeared to rec...
I Jusoh, D P Kamdem


Degradation of wood veneers by Fenton’s reagents: effects of low molecular weight phenolic compounds on hydrogen peroxide decay and tensile strength loss
2009 - IRG/WP 09-20400
Pine wood (Pinus sylvestris) veneers strips were incubated in acetate buffer containing hydrogen peroxide and iron to mimic mechanisms of brown rot decay and assess the degradation of cellulose through analysis of the tensile properties of the decayed wood. The tensile properties of thin wood strips treated with Fenton system reagents or precursors were determined and correlated to weight loss as ...
Yanjun Xie, R Well, Zefang Xiao, B Goodell, J Jellison, H Militz, C Mai


Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale


Fungal Attack on Lignin and Cellulose: Elucidation of Brown- and White-Rot Mechanisms Comparing Biomimetic and In-Vivo Degradation Patterns
2010 - IRG/WP 10-10714
This paper examines research and hypotheses that have been developed over several years on wood degradation mechanisms. This information is combined with new data and analyses to explain why wood decay patterns caused by brown-rot fungi and specific types of white-rot fungi are different. New data, including work with both biomimetic studies on low molecular weight compounds, degradative enzymes, ...
V Arantes, B Goodell, A M F Milagres, Yuhui Qian, T Filley, J Jellison, S Kelley


Glutathione transferases as functional biomarkers of wood degradation?
2010 - IRG/WP 10-10735
The recent release of several fungal genome sequences allows the report of an overview of fungal glutathione transferases (GSTs) focused on their function in the wood-degrading basidiomycete Phanerochaete chrysosporium. A genomic and phylogenetic analysis of GST classes in various sequenced fungi –zygomycetes, ascomycetes and basidiomycetes- revealed some specificity in GSTs distribution, in com...
E Gelhaye, M Morel


Simulation and Investigation of Wood Degradation by Erosion Bacteria in Laboratory Experiments
2010 - IRG/WP 10-20431
A Microcosm experiment was successfully set up to establish, monitor and manipulate bacterial wood degradation under low oxygen conditions. Sound pine sticks were placed in waterlogged sediment from a heavily decayed pine pile foundation site in Amsterdam. The system was subject to different gassing treatment regimes in order to investigate the role of oxygen in the bacterial degradation process o...
J Gelbrich, E I Kretschmar, N Lamersdorf, H Militz


The Use of Micro-Tensile Testing to Assess Weathering Decay and Oxidative Degradation of Wooden Items
2010 - IRG/WP 10-20433
This paper presents a method to study the weathering performance of wooden items and to assess the oxidative degradation of wood via the Fenton reaction. Weathering resistance and photo-stability of wood was tested using pine wood (Pinus sylvestris) veneer strips measuring approximately 60 µm in thickness. The veneer strips were treated using a reactive chemical to impart surface protection. The ...
C Mai, Yanjun Xie, Zefang Xiao, P D Evans, H Militz


Degradation of Carbon-Based Preservatives by Black-stain Fungi
2010 - IRG/WP 10-30533
Some black-stain fungi are known to exhibit resistance to carbon-based preservatives. However, the cause of this resistance is unclear. The fungi may have mechanisms to tolerate these chemicals, or they may be able to degrade and detoxify them. Fungi capable of degrading carbon-based preservatives are of interest for possible bioremediation of carbon-based preservative-treated wood at the end of i...
R Stirling, P I Morris


Biological degradation of acetylated wood after 18 years in ground contact and 10 years in marine water
2010 - IRG/WP 10-40522
This paper addresses the resistance to biological degradation of acetylated wood. Firstly, it presents results from an EN 252 test after 18 years’ exposure. The test is still running in Nordic NWPC test fields, Simlångsdalen in Sweden and Viikki in Finland. Results from this test were presented after 5 years’ exposure ( IRG/WP 97-30139), and showed that the resistance of acetylated wood wit...
P Larsson Brelid, M Westin


Utilization of thermodesorption coupled to GC-MS to study kinetics of thermodegradation of different wood species
2011 - IRG/WP 11-40559
Thermdesorption coupled to Gas Chromatography coupled to Mass Spectroscopy (TD-GC-MS) has been investigated to identify volatile degradation products generated during wood heat treatment by mild pyrolysis. For this purpose, wood samples of different softwood and hardwood species have been heat treated under nitrogen for different temperatures comprised between 180 and 230°C during 15 min. in the ...
K Candelier, M Chaouch, S Dumarçay, A Pétrissans, M Pétrissans, P Gérardin


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