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SEM-EDXA of CCA-treated Rubberwood (Hevea brasiliensis)
2009 - IRG/WP 09-20399
The microdistribution of chromated copper arsenate (CCA) preservative in rubberwood was studied using scanning electron microscope in conjunction with energy dispersive X-ray analyzer (SEM-EDXA). Bulk X-ray analysis showed that there was a high accumulation of chromium, copper, and arsenic in the vessels and lower concentration of the three preservative elements in fibres. Chromium appeared to rec...
I Jusoh, D P Kamdem


Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale


Service life prediction of wooden components – Part 1: Determination of dose-response functions for above ground decay
2010 - IRG/WP 10-20439
Scots pine sapwood (Pinus sylvestris L.) and Douglas fir heartwood (Pseudotsuga menziesii Franco) specimens were exposed in double layer field trials at 24 different European test sites under different exposure conditions (in total 28 test sets). The material climate in terms of wood moisture content (MC) and wood temperature was automatically recorded over a period of up to eight years and compar...
C Brischke, A O Rapp


Service life prediction of wooden components – Part 2: Impact of material, exposure and design details
2010 - IRG/WP 10-20440
Dose-response functions permit to estimate the moisture and temperature induced decay potential for any wooden building component and exposure, and thus the service life to be expected. In part 1 of this series dose-response functions were established as a result of double layer field trials carried out at 24 European test sites over up to eight years. Using them makes it no longer necessary to co...
C Brischke, B Lauenstein, M Bilstein, T Bornemann, A O Rapp


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Optimization of oxalic acid production for bioleaching of metal components from CCA-treated wood by an unknown Polyporales sp. KUC8959
2010 - IRG/WP 10-50266
A brown-rot fungus, an unknown Polyporales sp. KUC8959, has recently been identified and proven as a prominent fungal species for bioremediation of CCA-treated wood wastes in our Lab. The fungus produced a larger amount of oxalic acid than other fungi tested, and removed 90 % or more of chromium, copper and arsenic from CCA-treated wood sawdust through bioleaching process. The bioleaching process ...
Yong-Seok Choi, Min-Ji Kim, Jae-Jin Kim, Gyu-Hyeok Kim


Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


Service life prediction of wooden components - Part 3: Approaching a comprehensive test methodology
2011 - IRG/WP 11-20464
This paper is the third in a series on 'service life prediction' of wooden components and should be considered as a discussion paper. The authors tried to analyze the topic with a look from a distance and comment sometimes with a smile on the current controversial discussion about SLP issues. Nevertheless, the viewpoints of different groups, such as natural scientists, engineers, approva...
C Brischke, C R Welzbacher, L Meyer, T Bornemann, P Larsson Brelid, A Pilgård, E Frühwald-Hansson, M Westin, A O Rapp, S Thelandersson, J Jermer


Effects of nano-wollastonite impregnation on fire resistance and dimensional stability of Poplar wood
2012 - IRG/WP 12-40595
The fire-retardant properties of Nano-Wollastonite (NW) in poplar wood (Populus nigra) were determined in this study. Some physical properties such as water absorption, volumetric swelling and Anti-Swelling Efficiency (ASE) were also measured. Specimens were prepared according to the ISO 11925 standard for the fire-retarding properties, and ASTM D4446-2002 standard for the physical properties. Imp...
A Karimi, A Haghighi Poshtir, H Reza Taghiyari, Y Hamzeh, A Akbar Enayati


Visualization of Copper in the Voids and Cell Walls of Treated Wood using X-Ray Micro-Computed Tomography
2013 - IRG/WP 13-40640
This study extends our observations of the distribution of copper in treated wood. A small wood block was cut from a southern pine batten that had been treated with a particulate-copper preservative and similar sized block was cut from a batten that had been treated with a copper-amine preservative. Both blocks were imaged using X-ray micro-computed tomography. We obtained tomograms of each treate...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Hydrolytic stabilization of chemically modified Bambusa vulgaris Shrad ex JC Wendl
2018 - IRG/WP 18-40830
The main drawback which greatly limit the utilisation of bamboos is their high moisture intake, biodegradation and physical properties changes with environmental variations. To prevent excessive dimensional changes and improve moisture properties of bamboo, Bambusa vulgaris was chemically treated with acetic-anhydride without co-solvent. To evaluate the influence of acetylation on the moisture pro...
N A Sadiku, S M Akintayo


Thermal performance and fire safety properties of traditional circumferential log-cabin walls
2019 - IRG/WP 19-40872
The paper describes the experiment of fire resistance of a circumferential log-cabin wall fragment using various structural modification of the gap between two log members. The influence of the gap structural modification on the criterion of fire resistance E (envelop integrity) and I (insulation) is evaluated. The evaluating criteria are represented by the development of temperatures measured in ...
S Jochim, L Makovicka Osvaldova, M Zachar, Z Danihelova


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Application of an Ultrasound-based Instrument to Evaluate Condition of Drywood Termite Infested Timber Components
2022 - IRG/WP 22-11000
The characteristics of ultrasound waves propagation from non-destructive ultrasound-based instrument on drywood termite infested wooden components were investigated. Features of wave propagation such as time-of-flight, velocity, and peak energy on three orthogonal wooden plane (longitudinal, radial, and transversal) were studied. The wooden components used on this study came from a traditional woo...
S Fauziyyah, L Karlinasari, D Nandika, R Wimmer


Investigating moisture dynamics and fungal decay risk: integrating X-ray CT visualization and simulation benchmarks through a Fungal Control Unit
2024 - IRG/WP 24-11045
Wood is susceptible to fungal attack and over time the structural integrity can be compromised. This risk is of course strongly related to moisture dynamics, as moisture is needed for fungal growth. While existing methodologies, such as lab and field tests, provide valuable insights into wood decay, they often fall short in replicating real-life conditions, particularly within the intricacies of t...
J Van den Bulcke, J Van Acker, M Delbeke, A Blommaert, N Van Den Bossche, M Steeman, L De Ligne


Leaching and chemical redistribution of CCA components in refractory heartwood of E. nitens
2024 - IRG/WP 24-41011
Chromated Copper Arsenate (CCA) is a wood preservative widely used to protect against fungal and insect attack. The fixation mechanism of CCA involves complex chemical reactions, including the reduction of chromium (VI) to chromium (III) and the formation of insoluble complexes. Despite fixation efforts, a portion of CCA components tends to leach from treated wood, influenced by factors like wood ...
J R Vargas, L Yermán, K C Wood, T Singh


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