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The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Leaching tests on CCA-treated wood using inorganic salt solutions
1984 - IRG/WP 3310
Pinus radiata sapwood treated to approximately 10 kg/m³ with Tanalith NCA or Tanalith C-type CCA preservatives was ground to a fine powder and samples were then leached with solutions of calcium chloride, calcium nitrate, magnesium nitrate, or a mixture of potassium di-hydrogen orthophosphate and di-potassium hydrogen orthophosphate, at 0.03M-1.00M solution concentrations. Leached wood samples we...
D V Plackett


Wood cement composites using spent CCA treated wood
1999 - IRG/WP 99-50126
The feasibility of using spent or out-of-service CCA treated wood as a component of wood/cement composites was evaluated. Cold pressed wood particle cement boards were made using CCA treated particles from a red pine (Pinus resinosa Ait.) pole removed from service and from untreated red pine wood from a new pole. Boards were manufactured using a range of wood to cement ratios and water to cement r...
Chen Huang, P A Cooper


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Use of the enzyme-linked immunoassay (ELISA) and immunocytochemistry to detect soft rot in preservative treated and untreated wood
1990 - IRG/WP 2347
A polyclonal antibody was raised against mycelial extracts from the soft rot fungus Phialophora mutabilis. In ELISA assays, the antibody showed strong reactions with its own antigen and strong to moderate cross reactions with 6 other Phialophora soft rot species. With the exception of Ceratocystis albida, the antibody gave only weak or negative reactions with 11 other mold, blue stain and rot fung...
G F Daniel, T Nilsson


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


The results of detection on CCA components of the soils contacted with CCA-treated woods - A trial study for the availability of the burial Method as a disposal CCA treated wood waste
1993 - IRG/WP 93-50005
The objecteve of this experiment is to get a knowledge that, when CCA treated wood wastes were buried in a soil as a disposal, the soil would be or not be contaminated by the components of CCA preservatives in wood wastes. The specimens used were cutting logs and chips made of the CCA treated electric pole waste. The soil was buried to the 15 cm depth and the log specimens were set in the soil for...
K Suzuki, H Sonobe


Variation in field test performance of untreated and CCA-treated lesser-known Surinamese wood species
2000 - IRG/WP 00-20213
In Suriname three different field test sites have been used to verify the biological durability of CCA-treated wood and a range of wood species including lesser-known and lesser-used wood species. In total 37 tropical wood species were tested untreated and for 17 of the less durable species CCA-treatments were included as well. Although the three sites are located in the tropical region they diffe...
J Van Acker, M Stevens, L Comvalius


A Prediction of Arsenic Groundwater Concentrations Influenced by Construction and Demolition Debris Landfills in Florida Containing CCA-Treated Wood
2006 - IRG/WP 06-50242
Groundwater fate and transport models can provide an indication of the potential impacts of arsenic from the infiltration of leachate from unlined C&D debris landfills containing CCA-treated wood. A solute transport model, Migration of Organic/Inorganic Chemicals (MYGRT), was chosen to predict groundwater contaminant concentrations at specified locations from a hypothetical source (C&D lan...
J Jambeck, T Townsend, H Solo-Gabriele


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


The use of thermal desorption and pyrolysis combined with a semiconductor VOC detector for the on-site detection of preservative-treated wood
2010 - IRG/WP 10-20456
The purpose of this study was twofold; to identify possible marker molecules released from preservative-treated wood upon heat treatment and then develop a prototype detector for this marker. Two methods for heating the samples were used: Pyrolysis combined with Gas-Chromatography with IR-detection and Thermal Desorption combined with Gas-Chromatography with mass detection. A first prototype detec...
I Svensson, A Gonzalez, L Irusta, Mª J Fernandez-Berridi, O Munné


Biological performance of wood treated with tar-oil recovered during slow pyrolysis of macadamia nut shells
2010 - IRG/WP 10-30523
This study evaluated decay and termite resistance of wood treated with tar oil obtained from a commercial pyrolysis process of macadamia nut shells. Vacuum-treated pine wood specimens were subjected to various brown and white rot fungi based on the soil-block test method specified by the American Wood Protection Association (AWPA) after leaching process. Treated specimens were also subjected to th...
S Nami Kartal, E Terzi, C Kose, J Hofmeyr, Y Imamura


Optimization of oxalic acid production for bioleaching of metal components from CCA-treated wood by an unknown Polyporales sp. KUC8959
2010 - IRG/WP 10-50266
A brown-rot fungus, an unknown Polyporales sp. KUC8959, has recently been identified and proven as a prominent fungal species for bioremediation of CCA-treated wood wastes in our Lab. The fungus produced a larger amount of oxalic acid than other fungi tested, and removed 90 % or more of chromium, copper and arsenic from CCA-treated wood sawdust through bioleaching process. The bioleaching process ...
Yong-Seok Choi, Min-Ji Kim, Jae-Jin Kim, Gyu-Hyeok Kim


Fungal biodegradation of CCA-treated wood wastes
2011 - IRG/WP 10-50276
Fungal biodegradation could be employed as a pretreatment method to alleviate problems caused by landfill disposal of CCA-treated wood wastes (e.g. a shortage of landfill space and a release of leacheate). It could be used to decrease the volume of waste and to remove metals from waste simultaneously. We have screened hundreds of decay fungi, including fungi isolated from CCA-treated wood in servi...
Gyu-Hyeok Kim, Yong-Seok Choi, Jae-Jin Kim


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