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A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Development of software to automate the quantification of checking occurring in preservative treated wood exposed to weathering
2001 - IRG/WP 01-20228
Surface checking often disfigures the appearance of wood treated with water-borne preservatives and treatments designed to reduce such checking have been receiving increasing attention. Progress in this area has however been slowed by the lack of a method of rapidly and accurately quantifying checking at treated wood surfaces. A software package has therefore been developed which identifies, measu...
A G Christy, P D Evans


Evaluation of impact of CCA-treated wood on the marine environment
1995 - IRG/WP 95-50040-15
This paper reviews the literature relating to the potential of CCA-treated wood to affect the marine environment and outlines the compounds required for a model which could be used to predict the environemental impact of maritime construction using such timber. Marine pilings require high loadings of CCA to provide protection from marine borers. Though loadings of 32-48 kg/m³ provide long-term pr...
R M Albuquerque, S M Cragg


The Disposal of CCA-Treated Wood in Simulated Landfills: Potential Impacts
2003 - IRG/WP 03-50198
Landfills are typically where CCA-treated wood is currently disposed, and will likely continue to be the primary form of management in the future. It has been shown that arsenic, copper and chromium leach from CCA-treated wood in certain situations; however, the impact of the disposal of CCA-treated wood on landfill leachate is currently unknown. The objective of this research is to examine the po...
J Jambeck, T G Townsend, H M Solo-Gabriele


Management strategies for the disposal of CCA-treated wood
2000 - IRG/WP 00-50155
A two-fold management strategy is presented for the disposal of wood treated with chromated copper arsenate (CCA). The first part focuses on the use of alternative wood treatment preservatives. The second part of the management strategy addresses short-term disposal issues (less than 25 years) by developing new methods to handle the waste. A set of seven alternative wood preservatives were evaluat...
H M Solo-Gabriele, T G Townsend


International comparison of three field methods for assessing the in-ground resistance of preservative-treated and untreated wood to termites and fungal decay – Summary of observations after five years
2003 - IRG/WP 03-20261
Results are presented from a five-year study conducted in five locations in Australia, Thailand and the USA. Three methods of exposure were assessed (below-ground, graveyard and ground contact) for evaluating the in-ground termite and decay resistance of Pinus radiata D. Don sapwood stakes that had been vacuum pressure impregnated with CCA (Type C) and ACQ (Type D) each at two nominal retentions (...
M Lenz, J W Creffield, T A Evans, B M Kard, C Vongkaluang, Y Sornnuwat, A F Preston


Surface characteristics of wood treated with various AAC, ACQ and CCA formulations after weathering
1991 - IRG/WP 2369
Wood samples treated with various alkylammonium compounds (AACs) as well as ammoniacal copper quat (ACQ) and chromated copper arsenate (CCA) have been studied in accelerated weathering experiments. Microscopic examination of the surfaces of these samples after exposure in a weatherometer revealed several different changes. Samples treated with didecyldimethyl ammonium chloride (DDAC) show consider...
L Jin, K J Archer, A F Preston


Kinetics of the dissociation of Cr, Cu, and As in fixed CCA-treated wood
2001 - IRG/WP 01-50168
The results of an experiment showing the kinetics of the dissociation of CCA compo-nents in water within treated wood samples are presented. Dry red pine (Pinus resinosa Ait.) samples were simultaneously vacuum-treated with water, then expressed to re-move the water at successive time intervals. The expressate was then analyzed for Cr, Cu, and As concentration by inductively coupled plasma (ICP). ...
L Waldron, P A Cooper


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


Tropical In-Ground Durability of Structural Sarawak Hardwoods Impregnated to High Retention with CCA-salts, CCA-oxide and FCAP after 20 Years Exposure
2005 - IRG/WP 05-30384
Statistical analysis (ANOVA) was conducted on durability (termite and decay combined) rating data collected over 20 years exposure period of over 140 species of Sarawak timbers with altogether 30,000 stake specimens, at the Forest Department’s Sibu “graveyard” stake test sites from 1977. About 20 replicated stakes were pressure-treated to refusal with 10% g/ml concentration of up to 3 CCA-sa...
Wang Choon Ling, A H H Wong


Enhanced removal of CCA from treated wood by Bacillus licheniformis in continuous culture
1997 - IRG/WP 97-50083
A gram positive, spore-forming bacterium, which was isolated from a 20-year-old Forest Service test plot of CCA-treated 2 x 4's in Madison, WI., demonstrated the ability to release copper, chromium, and arsenic from CCA-treated wood in liquid culture. CCA-treated sawdust was exposed to this organism, which has been presumptively identified as Bacillus licheniformis. Analysis of the sawdus...
C A Clausen


Treatment groups and remedies for CCA treated hardwood and softwood poles
1999 - IRG/WP 99-40142
Different hardwood and softwood species from Bangladesh and Bhutan was investigated regarding density, green fiber stress, natural durability of heartwood and CCA treated sapwood, CCA treatability grades, sapwood thickness, and kiln-drying properties for long term use as electric poles. These properties along with the past service records for nineteen years, separated ten heardwood and five softwo...
A K Lahiry


Technologies for the Management of Wood Waste Containing Metals-Based Preservatives
2005 - IRG/WP 05-50224-16
Disposal of the metals from preservative treated wood can occur through two general strategies: “removal and confinement” or “dilution”. The acceptability of each of these two choices is typically dictated through the disposal regulations of a particular region. A considerable amount of research has been conducted to develop new and innovative “removal and confinement” technologies...
H M Solo-Gabriele, T G Townsend


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


CCA-treated Wood Disposed in Landfills and Life-cycle Trade-Offs With Waste-to-Energy and MSW Landfill Disposal
2005 - IRG/WP 05-50231
CCA-treated wood as a solid waste is managed in various ways throughout the world. Although some wood is combusted for the production of energy in the U.S., more often than not, CCA-treated wood is disposed in landfills. In other countries, wood, often including CCA-treated wood, is combusted for the production of energy. This paper is presented in two parts. Part I evaluates the impact of CCA-tre...
J Jambeck, K Weitz, T G Townsend, H M Solo-Gabriele


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


Termite resistance of treated wood in an above-ground field test
1985 - IRG/WP 2241
A field test method has been developed for evaluating the susceptibility of wood products to termites in protected situations above ground. In this method fungal attack on the wood products is minimal, though decay has been observed in conjunction with termite attack in some specimens. Preliminary results from exposure of replicate wood samples treated with preservatives in Florida to Reticuliterm...
A F Preston, P A McKaig, P J Walcheski


Recycling of CCA treated wood in the US
1998 - IRG/WP 98-50101-08
The production of CCA treated wood has increased dramatically in recent years. Previous estimates of the volume of treated wood to be removed were based on the assumed service life of the material, generally 20 to 25 years. This study based on a survey of contractors installing treated decks, determined that the actual service life of these decks is much shorter than their assumed functional servi...
J McQueen, J Stevens, D P Kamdem


Termite resistance of treated wood in an above-ground field test
1986 - IRG/WP 1300
This paper provides an update on the results from an above ground field test evaluating the effectiveness of wood preservatives against subterranean termites. Results for the one and two year inspections of treated southern pine sapwood exposed in Hawaii to Coptotermes formosanus are presented. Chromated copper arsenate is providing excellent protection as is the pyrethroid deltamethrin. Borate an...
A F Preston, P A McKaig, P J Walcheski


Limnoria quadripunctata Holthuis - a threat to copper-treated wood
1983 - IRG/WP 4100
This paper presents the first reported attack by the crustacean marine wood-borer Limnoria quadripunctata Holthuis of CCA treated eucalypt piles. The attack occurred after 12 years service of the piles in the River Derwent at Hobart, Tasmania. Attack by both this borer and Limnoria tripunctata Menzies is also reported in CCA treated softwoods and hardwoods over periods ranging from 5 to 22.9 years...
J E Barnacle, L J Cookson, C N McEvoy


Depletion of preservatives from treated wood: Results from laboratory, fungus cellar and field test
1993 - IRG/WP 93-50001-07
This paper compares results of preservative component losses using a range of test procedures with several different water-borne preservatives. The data shows that laboratory leaching tests are in some cases comparable to, but in other cases significantly underestimate preservative component losses when compared with field or fungus cellar depletion tests. The results also suggest that preservativ...
L Jin, A F Preston


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


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