IRG Documents Database and Compendium


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Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


Preliminary studies on cellulase production by selected Basidiomycetes and the effect of copper-chrome-arsenate on these enzymes
1980 - IRG/WP 1122
The growth of wood-destroying fungi on ligno-cellulosic materials depends on the production of many enzymes, of which probably the most important is the multi component cellulase system. Within this system, at least three different kinds of enzym are believed to be involved in crystalline cellulose decomposition. These are endo-1,4-glucanase, exo-1,4-ß glucanase and ß-glucosidase. Most of the re...
O Collett


Applications of the shower test. Part B: Results from CC and CCB treated wood: influence of fixation process
1993 - IRG/WP 93-50010
This report outlines the results of shower tests conducted on CC and CCB treated wood. The results indicate the fairly good fixation of chromium and the reasonable fixation of copper in CC and CCB formulations, as judged by the leaching limits within the Environmental Regulations. In general boron leaches to a higher extent than chromium and copper. The shower test has proven to be a useful qualit...
W J Homan, H Militz


Assessment of dehydrogenase activity, fluoride content and total chromium content of soil profiles exposed to preservative treated wood within a model system
1993 - IRG/WP 93-10015
The development and prospective use of a closed model system to facilitate study of a number of indicators of environmental impact of wood preservatives laboratory conditions has been described (IRG/WP/2395-92). Chemical analysis of leachate samples collected from drained soil profiles containing creosoted pole sections remedially treated with a chromated fluoride preservative indicated small incr...
G M Smith, D C R Sinclair, A Bruce, H J Staines


Proposal for further work on fixation of CCA-preservatives in wood
1988 - IRG/WP 3493
Many studies on the fixation and fixation-mechanism of CCA-preservatives in lignocellulose materials have been published but few on the practical consequences of this knowledge. For the wood preserving industry and the user of treated wood it is important to know what is meant by the word fixation, when fixation is complete and how fixation can be recorded in an easy way according to a non-destruc...
M-L Edlund


Appearance of PEC-treated poles in service
1985 - IRG/WP 3323
Poles treated with conventional high temperature creosote (HTC) are banned for use in Australia by the major union handling them. Pigment emulsified creosote (PEC) is an acceptable alternative because it provides much dryer and cleaner commodities than does HTC. More than 5000 poles have so far been treated with PEC and many are being installed into service. The brown pigmented PEC 30 B has given ...
H Greaves, C-W Chin, K J McCarthy, J B Watkins


Fungus cellar testing as an evaluation method for performance of treated timber in ground contact
2001 - IRG/WP 01-20227
A fungus cellar method for the accelerated evaluation of performance of treated wood in ground contact is described. The test soil comprised of sandy loam, vermiculite and Japanese horticulture soil "Kanumatsuchi" in a ratio of 6:2:2 by volume. The soil was inoculated with the dominant test fungus isolated with selective medium from decayed wood samples. Pairs of treated and untreated wood specime...
Y Nagano


Wood Preservatives Science Issues: US EPA’s Perspective
2005 - IRG/WP 05-50224-2
The USEPA Office of Pesticide Programs (OPP), Antimicrobials Division (AD), regulates the use of chemicals registered as wood preservatives in the United States. An overview of the registration and re-registration process is presented. The wood preservatives data requirements include toxicological, human exposure, ecological, and environmental fate data. A detailed discussion of wood preservati...
N Elkassabany


Serviceability of copper naphthenate-treated poles
2000 - IRG/WP 00-30214
Copper naphthenate-treated poles in service were inspected for deterioration, penetration, retention, and serviceability. The study to date has included poles in all hazard zones in the United States. Poles installed by 12 different utilities and eight different treating companies are included in the survey. Both southern pine and Douglas-fir poles and distribution and transmission poles are inclu...
H M Barnes, M H Freeman, J A Brient, C N Kerr Jr


CCA modifications and their effect on soft rot in hardwoods. Part 2
1983 - IRG/WP 3244
The work outlined in this document is a continuation of that presented in Document No: IRG/WP/3201. The findings described in the previous paper are summarised below: a double treatment of CCB followed by arsenic (CCB+A) is more effective than a double treatment of boron followed by CCA (B+CCA) or a single treatment of CCA, CCB or CCAB in controlling soft-rot due to Chaetomium globosum in birch. C...
S M Gray, D J Dickinson


Supplementary experiment to the main trial (IRG/WP/367, 384) to determine the performance of preservative treated hardwoods with particular reference to soft rot
1977 - IRG/WP 3101
The field experiment being carried out by the IRG (described in document IRG/WP/367) is designed to obtain information on the performance of a preservative in different hardwoods in ground contact. A total of 57 timber species is being examined and 36 different field sites are involved representing a complete range of climatic conditions. IRG document WP/384 describes the treatment details of the ...
F W Brooks, C R Coggins, D J Dickinson


Effect of soil parameters on biocide depletion: laboratory and field studies of water- and emulsion-borne preservatives
2000 - IRG/WP 00-30234
Two field test sites with different soils were selected. Soil analysis showed that the soil at the two sites had considerable texture, base saturation, acidity, and cation exchange capacity differences. Five sets of field stakes were treated as follows: three with water-borne CCA to about 0.4 pcf (6.4 kgm-3) retention, one with 0.75% DDAC, and one with 0.75% DDAC:0.25% chlorothalonil. The last two...
T Schultz, D D Nicholas, D E Pettry, M G Kim


Life-cycle assessement of treated wood: A view from the roa
1996 - IRG/WP 96-50078
Life Cycle Assessement (LCA) is being used increasingly as a tool to structure information on the environmental characteristics of material and processes. This paper is based on the experience gained from our LCA studies on treated wood products over the last 4 years. The comprehensive and logical examination af the information available on treated timber provided by LCA has allowed identification...
W Hillier, R J Murphy, D J Dickinson, J N B Bell


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


Environmental risk assessment of treated timber in service: The Environment Focus Group approach
2000 - IRG/WP 00-50162
In the context of the Biocidal Products Directive (98/8/EC), and of the OECD work on wood preservatives, the Environment Focus Group (EFG), comprising 8 institutes and the European Wood Preservative Manufacturers Group, has been working on the environmental risk assessment of treated timber in service. A literature review of emissions from treated timber has revealed that very little existing data...
G Deroubaix, G Labat, I Le Bayon, S Legay, P Marchal, C Yrieix, E Melcher, R-D Peek, S De Geyter, J Van Acker, W J Homan, D J Dickinson, R J Murphy, E D Suttie, A J Nurmi, A-C Ritschkoff, D Rudolph, I Stephan, D Aston, E F Baines, J B Simonin


Effectiveness of copper/chromium salts as wood preservatives against Limnoria tripunctata Menzies in laboratory tests
1977 - IRG/WP 431
During the last joint meeting of IRG and COIPM a co-operative programme of tests with copper/chromium salts as wood preservatives against marine borers was discussed and agreed. In this connection the results of a laboratory test in the BAM with Limnoria tripunctata Menzies will be of interest. But as the respective paper is written in German (H. Kühne; G. Becker: Laboratoriumsversuche über die ...
H Kühne


Safe application of copper-chrome-arsenate preservatives
1975 - IRG/WP 377
All wood preservatives contain biologically active substances and must, by design, be in some measure toxic to man. There is nothing fundamentally difficult, however, about using a wood preservative with complete safety. It depends on knowing the risks to health and/or the environment, which the preservative may present, and planning application accordingly. In this paper we examine these and othe...
I N Stalker, P B Cornwell


Initial results and observations of a model system to assess the efficacy and environmetal impact of preservative treated wood
1993 - IRG/WP 93-50001-02
The development of a closed model system for the laboratory assessment of the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles has been described (IRG/WP/2395-92). The model consists of a precipitation apparatus above a treated pole section positioned in a soil profile from which leachate was collected via a series of simulated field dra...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Experiences with penetration of copper-based wood preservatives
2001 - IRG/WP 01-20233
In the Nordic countries there is a long tradition of result type based specifications for preservative-treated wood. A common Nordic standard for treated pine (Pinus sylvestris) wood was published in 1976. After a revision in 1989 this standard, then named INSTA 140, defined four classes of treated wood: M, A, AB and B. Treaters producing according to this standard had to be affiliated to a qualit...
J Jermer, F G Evans, I Johansson


International comparison of three field methods for assessing the in-ground termite resistance of materials - highlights after two years
1999 - IRG/WP 99-20157
First-year results of a comparative study, evaluating the in-ground termite resistance of a range of materials, including CCA and ACQ-treated timbers, using the below-ground exposure, ground contact and graveyard methods against diverse termite faunas were provided in IRG/WP/98-20132. Further annual inspections have confirmed early trends and identified notable differences between sites and method...
M Lenz, J W Creffield, A F Preston, B M Kard, C Vongkaluang, Y Sornnuwat


Susceptibility of CCB treated wood to fungal colonization
2003 - IRG/WP 03-10492
CCB treated wood is generally resistant to all wood decay fungi. However, like CCA impregnated wood, susceptibility of CCB treated wood to copper tolerant fungi have been observed. The ability of various brown rot fungal hyphae to penetrate and overgrow the wood samples was investigated. Samples made of Norway spruce (Picea abies) were impregnated with 5 % CCB solution according to the EN 113 proc...
F Pohleven, U Andoljsek, P Karabegovic, C Tavzes, S A Amartey, M Humar


Chemical and biological studies of organotin treated and painted wood stakes after outdoor exposure
1987 - IRG/WP 3419
Organotin based wood preservatives containing tributyltin oxide (TBTO) or tributyltin naphthenate (TBTN) are used in Sweden mainly for double-vacuum treatments of window joinery of Pinus sylvestris. After impregnation the joinery is painted or stained in different colours. To evaluate this effect (different colours on the degree of degradation of TBTO and TBTN, effected by different temperatures i...
M-L Edlund, B Henningsson


Development of a turbidity method for the determination of water repellent in CCA treatment solutions
2000 - IRG/WP 00-40177
The use of aqueous water repellent emulsion formulations has increased significantly in the wood treatment industry. These are primarily used to enhance the weathering characteristics of wood products treated with water borne preservatives systems used in exterior above ground exposures. However, they are also used in pole treatments to improve the climbing characteristics and in low VOC millwork ...
P J Walcheski, L Jin


The mathematical study of test plot data
1987 - IRG/WP 2282
It has long been desirable to have a mathematical expression, which, by the insertion of statistically derived constants, would describe the behavior of test specimens in service. The philosophy of such expressions is briefly discussed, and the history of the concept is outlined. The modern approach to the problem dates from the graphical presentation of dosage-response and deterioration curves by...
W H Hartford


Presteaming radiata pine heartwood to improve treatability
1983 - IRG/WP 3239
Steaming and holding before preservative treatment by the Bethell process greatly improved the treatment of radiata pine heartwood. Maximum penetration of preservative for the shortest holding period was obtained by the use of steam vacuum but the difference between this and steam venting was small when compared with the standard of treatment of air dried samples. A holding period of one day was s...
A J Bergervoet


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